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Orientation effect on sign and magnitude of excess thermodynamic functions of non electrolyte solutions at different temperatures (303.15 K, 308.15 K, and 313.15K)

  • Separation Technology, Thermodynamics
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Abstract

Experimental values of the density and viscosity have been measured for binary mixtures of N-ethylaniline with isomeric butanols (1-butanol, 2-butanol, 2-methyl-1-propanol and 2-methyl-2-propanol) at 303.15, 308.15 and 313.15 K over the entire mole fraction range. These data, the excess molar volumes, and deviation viscosity for the binary systems at the above-mentioned temperatures were calculated and fitted to Redlich-Kister equation to determine the fitting parameters and the root-mean-square deviations. The excess molar volumes, deviation viscosity and excess Gibbs energy of activation of viscous flow have been analyzed in terms of acid-base interactions, hydrogen bond, and dipole-dipole interaction between unlike molecules. The results obtained for dynamic viscosity of binary mixtures were used to test the semi-empirical relations of Grunberg-Nissan, Katti-Chaudhri, and Hind et al. equations.

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Authors and Affiliations

  1. Department of Chemistry, Acharya Nagarjuna University, Guntur, 522510, AP, India

    Jareena Shaik, Dittakavi Ramachandran & Chintala Rambabu

  2. Department of Chemistry, J.K.C. College, Acharya Nagarjuna University, Guntur, 522006, India

    Manukonda Gowri Sankar

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  1. Jareena Shaik
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  2. Manukonda Gowri Sankar
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  3. Dittakavi Ramachandran
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  4. Chintala Rambabu
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Correspondence to Chintala Rambabu.

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Shaik, J., Sankar, M.G., Ramachandran, D. et al. Orientation effect on sign and magnitude of excess thermodynamic functions of non electrolyte solutions at different temperatures (303.15 K, 308.15 K, and 313.15K). Korean J. Chem. Eng. 31, 1460–1469 (2014). https://doi.org/10.1007/s11814-014-0088-1

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  • DOI: https://doi.org/10.1007/s11814-014-0088-1

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