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Effects of dye etching on the morphology and performance of ZnO nanorod dye-sensitized solar cells

  • Environmental Engineering
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Abstract

Dye-sensitized solar cells based on electrodeposited ZnO nanorod arrays were fabricated and tested. Field-emission scanning electron microscopy (FESEM) and X-ray powder diffraction (XRD) were used to identify the characters of ZnO nanorod arrays. The effects of dye etching on the morphology and performance of ZnO nanorod dye-sensitized solar cells were studied. It was found that the surfaces of ZnO nanorods were both etched by dye solutions, no matter N3 or N719. Compared with N3, N719 had a larger damage to the structure of ZnO nanorod photoanode, and the photoelectric conversion efficiency of cells decreased quickly with the sensitizing time increasing. In a certain range, the increasing length of ZnO nanorods can clearly improve the photoelectric conversion efficiency of cells.

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References

  1. M. Gratzel, J. Photochem. Photobiol. C, 4, 145 (2003).

    Article  CAS  Google Scholar 

  2. A. Yella, H.W. Lee, H. N. Tsao, C.Y. Yi, A. K. Handiran, M. K. Nazeeruddin, E.W. Diau, C.Y. Yeh, S.M. Zakeeruddin and M. Gratzel, Science, 334, 629 (2011).

    Article  CAS  Google Scholar 

  3. J. H. Wu, S. C. Hao, Z. Lan, J.M. Lin, M. L. Huang, Y. F. Huang, P. J. Li, S. Yin and T. Sato, J. Am. Chem. Soc., 130, 11568 (2008).

    Article  CAS  Google Scholar 

  4. Z. Lan, J.H. Wu, S.C. Hao, J.M. Lin, M. L. Huang and Y. F. Huang, Energy Environ. Sci., 2, 524 (2009).

    Article  CAS  Google Scholar 

  5. J. Ya, L. An, Z. Liu, L. E, W. Zhao, D. Zhao and C. Liu, Korean J. Chem. Eng., 29, 731 (2012).

    Article  CAS  Google Scholar 

  6. Q. Zhang, C. S. Dandeneau, X. Zhou and G. Z. Cao, Adv. Mater., 21, 4087 (2009).

    Article  CAS  Google Scholar 

  7. T. Yoshida, H. Minoura, J. Zhang, D. Komatsu, S. Sawatani, T. Pauporte, D. Lincot, T. Oekermann, D. Schlettwein, H. Tada, D. Wohrle, K. Funabiki, M. Matsui, H. Miura and H. Yanagi, Adv. Funct. Mater., 19, 17 (2009).

    Article  CAS  Google Scholar 

  8. H. M. Cheng and W. F. Hsieh, Energy Environ. Sci., 3, 442 (2010).

    Article  CAS  Google Scholar 

  9. F. Xu and L. T. Sun, Energy Environ. Sci., 4, 818 (2011).

    Article  CAS  Google Scholar 

  10. Y. B. Hahn, Korean J. Chem. Eng., 28, 1797 (2011).

    Article  CAS  Google Scholar 

  11. A. Petersson, M. Ratner and H. O. Karlsson, J. Phys. Chem. B, 104, 8498 (2000).

    Article  CAS  Google Scholar 

  12. C. Bauer, G. Boschloo, E. Mukhtar and A. Hagfeldt, J. Phys. Chem. B, 105, 5585 (2001).

    Article  CAS  Google Scholar 

  13. L.M. Peter, J. Phys. Chem. Lett., 2, 1861 (2011).

    Article  CAS  Google Scholar 

  14. M. Law, L. E. Greene, J. C. Johnson, R. Saykally and P. Yang, Nat. Mater., 4, 455 (2005).

    Article  CAS  Google Scholar 

  15. E. Hosono, S. Fujihara, I. Honma and H. Zhou, Adv. Mater., 17, 2091 (2005).

    Article  CAS  Google Scholar 

  16. R. S. Mane, W. J. Lee, H. M. Pathan and S. H. Han, J. Phys. Chem. B, 109, 24254 (2005).

    Article  CAS  Google Scholar 

  17. M.H. Lai, M.W. Lee, G. J. Wang and M. F. Tai, Int. J. Electrochem. Sci., 6, 2122 (2011).

    CAS  Google Scholar 

  18. M. Guo, P. Diao, X. D. Wang and S.M. Cai, J. Solid State Chem., 178, 3210 (2005).

    Article  CAS  Google Scholar 

  19. F. P. Yan, L. H. Huang, J. S. Zheng, J. Huang, Z. Lin, F. Huang and M. D. Wei, Langmuir, 26, 7153 (2010).

    Article  CAS  Google Scholar 

  20. Y. Lin, J.Y. Yang and X.Y. Zhou, Appl. Surf. Sci., 258, 1491 (2011).

    Article  CAS  Google Scholar 

  21. K. Keis, C. Bauer, G. Boschloo, A. Hagfeldt, K. Westermark, H. Rensmo and H. Siegbahn, J. Photochem. Photobiol. A, 148, 57 (2002).

    Article  CAS  Google Scholar 

  22. J. J. Wu, G.R. Chen, H. H. Yang, C. H. Ku and J.Y. Lai, Appl. Phys. Lett., 90, 213109 (2007).

    Article  Google Scholar 

  23. M.Y. A. Rahman, A. A. Umar, R. Taslim and M. M. Salleh, Electrochim. Acta, 88, 639 (2013).

    Article  CAS  Google Scholar 

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Correspondence to Yu Lin.

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Yang, J., Lin, Y. & Meng, Y. Effects of dye etching on the morphology and performance of ZnO nanorod dye-sensitized solar cells. Korean J. Chem. Eng. 30, 2026–2029 (2013). https://doi.org/10.1007/s11814-013-0133-5

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  • DOI: https://doi.org/10.1007/s11814-013-0133-5

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