Skip to main content
Log in

Changes of hydrochemical composition and heavy metals concentration in shallow groundwater from karst hilly areas in Guiyang region, China

  • Published:
Journal of Central South University of Technology Aims and scope Submit manuscript

Abstract

The quality changes of shallow groundwater from karst hilly areas in Guiyang region of China impacted by the urbanization were investigated. The results show that the major ions in shallow groundwater from the karst hilly areas are mainly composed of HCO3 , SO4 2−, Ca2+ and Mg2+, and the concentrations scopes of NO3 , Cl, K+ and Na+ of the groundwater in agricultural, residential and industrial areas are 4.5–9.6, 2.8–7.1, 3.9–6.3 and 2.5–4.9 times higher than those in the forest areas, respectively. The concentrations of As, Pb and Cd of shallow groundwater in the industrial areas are also significantly enhanced, followed by those in the residential areas and the agricultural areas. The concentrations of NO3 , SO4 2−, As, Pb and Cd of the groundwater in the industrial areas and those of NO3 , SO4 2−, As and Cd of shallow groundwater in the residential areas reach grade III of the Groundwater Quality Standard of China (GB/T 14848-93), while the concentration of NO3 in the groundwater from the industrial areas exceeds grade V. With the process of urbanization, NO3 is the key factor to influence the groundwater quality in karst hilly areas, followed by SO4 2−, As, Pb and Cd.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. WANG S J, LIU Q M, ZHANG D F. Karst rocky desertification in southwestern China: Concept, formation background and rehabilitation [J]. Land Degradation and Development, 2004a, 15(2): 115–121.

    Article  Google Scholar 

  2. ANDREO B T, GOLDSCHEIDER N C, VADILLO I K. Karst groundwater protection: First application of a Pan-European approach to vulnerability, hazard and risk mapping in the Sierra de Líbar (Southern Spain) [J]. Science of the Total Environment, 2006, 357(1): 54–73.

    Article  Google Scholar 

  3. LI S L, LIU C Q, TAO F X, HAN G L. δ 13CDIC as a tracer to monitor pollution and ecological changes in ground water [J]. Ground Water, 2005, 43(2): 494–499.

    Article  Google Scholar 

  4. LANG Y C, LIU C Q, ZHAO Z Q, LI S L, HAN G L. Geochemistry of surface and ground water in Guiyang, China: Water/rock interaction and pollution in a karst hydrological system [J]. Applied Geochemistry, 2006, 21(6): 887–903.

    Article  Google Scholar 

  5. LAURA T, KATHLEEN G, YOUA Y. Effects of restricted recharge in an urban karst system [J]. Environmental Geology, 2009, 58(1): 131–139.

    Article  Google Scholar 

  6. PLAGNES V L, BAKALOWICZ M C. The protection of a karst water resource from the example of the Larzac karst plateau (south of France): A matter of regulations or a matter of process knowledge? [J]. Engineering Geology, 2002, 65(2): 107–116.

    Article  Google Scholar 

  7. ZEMECKIS R M, LAZAUSKAS S G, GORTON M T. The Europeanisation of agri-environmental policy: A case study of water quality in the Lithuanian karst zone [J]. Land Use Policy, 2005, 22(3): 255–264.

    Article  Google Scholar 

  8. MARFIA A M, KRISHNAMURTHY R V, ATEKWANA E A. Isotopic and geochemical evolution of ground and surface waters in a karst dominated geological setting: A case study from Belize, Central America [J]. Applied Geochemistry, 2004, 19(6): 937–946.

    Article  Google Scholar 

  9. GUO H M, WANG Y X. Geochemical characteristics of shallow groundwater in Datong basin, northwestern China [J]. Journal of Geochemical Exploration, 2005, 87(3): 109–120.

    Article  Google Scholar 

  10. JEONG C H. Effect of land use and urbanization on hydrochemistry and contamination of groundwater from Taejon area, Korea [J]. Journal of Hydrology, 2001, 253(1): 194–210.

    Article  Google Scholar 

  11. HAN G L, LIU C Q. Water geochemistry controlled by carbonate dissolution: A study of the river waters draining karst-dominated terrain, Guizhou Province, China [J]. Chemical Geology, 2004, 204(1): 1–21.

    Article  Google Scholar 

  12. HAN G L, LIU C Q. Strontium isotope and major ion chemistry of the rainwater from Guiyang, Guizhou Province, China [J]. Science of the Total Environment, 2006, 364(1): 165–174.

    Article  Google Scholar 

  13. MARKOVIC T M, MIKO S B, KAPELJ S N. Behavior of metals and nutrients in soils and groundwater of a karst pole [J]. Journal of Geochemical Exploration, 2006, 88(1): 124–129.

    Article  Google Scholar 

  14. JIANG Y, YUAN D, ZHANG C, ZHANG G, HE R. Impact of land use change on groundwater quality in a typical karst watershed of southwest China [J]. Hydrogeology Journal, 2008, 16(4): 727–735.

    Article  Google Scholar 

  15. WANG J Y, DA L J, SONG K, LI B L. Temporal variations of surface water quality in urban, suburban and rural areas during rapid urbanization in Shanghai, China [J]. Environmental Pollution, 2008, 152(2): 387–393.

    Article  Google Scholar 

  16. WANG S J, LI R L, SUN C X, LIU X M. How types of carbonate rock assemblages constrain the distribution of karst rocky desertification land in Guizhou Province, PR China: phenomena and mechanisms [J]. Land Degradation and Development, 2004, 15(2): 123–131.

    Article  Google Scholar 

  17. YU Li-fei, ZHU Shou-qian, YE Jing-zhong, WEI Ru-ming. Evaluation on degradation of karst forest community and human disturbance [J]. Journal of Applied Ecology, 2002, 13(5): 529–532. (in Chinese)

    Google Scholar 

  18. OENEMA O N, LIERE L V, SCHOUMANS O C. Effects of lowering nitrogen and phosphorus surpluses in agriculture on the quality of groundwater and surface water in the Netherlands [J]. Journal of Hydrology, 2005, 304(2): 289–301.

    Article  Google Scholar 

  19. PANNO S V, KELLY W R. Nitrate and herbicide loading in two groundwater basins of Illinois’ sinkhole plain [J]. Journal of Hydrology, 2004, 290(3): 229–242.

    Article  Google Scholar 

  20. PETERSON E W, DAVIS R K, BRAHANA J V, ORNDORFF H A. Movement of nitrate through regolith covered karst terrain, northwest Arkansas [J]. Journal of Hydrology, 2002, 278(1): 35–47.

    Article  Google Scholar 

  21. Council of the European Communities. Council Directive of 12th December 2006 on the pollution of groundwater against pollution and deterioration (2006/118/EC), No. L 372/19 [R]. London: Official Journal of the European Community, 2006: 1–9.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Fang Liu  (刘方).

Additional information

Foundation item: Project(2006CB403205) supported by the National Key Basic Research Program of China; Project(40961030) supported by the National Natural Science Foundation of China

Rights and permissions

Reprints and permissions

About this article

Cite this article

Liu, F., Liu, Cq., Zhao, Y. et al. Changes of hydrochemical composition and heavy metals concentration in shallow groundwater from karst hilly areas in Guiyang region, China. J. Cent. South Univ. Technol. 17, 1216–1222 (2010). https://doi.org/10.1007/s11771-010-0622-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11771-010-0622-1

Key words

Navigation