Abstract
B2O3-BaO-ZnO glass was prepared by using conventional melt quenching technology. The forming regularity and the relationship between the composition and the property of B2O3- BaO - ZnO glass were investigated. The results show that the composition range for forming B2O3 - BaO -ZnO glass is very wide, but the content of B2O3 has a limit within mole fraction of 25%–75%. When the content of B2O3 is over the limit, the melt will be divided into two phases with different compositions and structures, whereas too low content of B2O3 will result in the crystallization of the melt during the cooling process. The thermal expansion coefficient, the transition temperature and the resistivity of the glass at room temperature are (5–10) × 10−6°C−1, 480–620 °C and (1.5–3.0)×1010 Θ · m, respectively.
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References
LIN Na, LU An-xian. Current research status of glass substrates for plasma display panels(PDP)[J]. Materials Review, 2004, 18(3): 44–46. (in Chinese)
Shinoda T, Wakitani M, Nanto T, et al. Development of panel structure for a high-resolution 21-in-diagonal full-color surface-discharge plasma display panel[J]. IEEE Trans on Electron DEV, 2000, 47(1): 77–81.
QIAN Wei-zong, SUN Jian, ZHENG De-xiu. Recent advance of color plasma display panel[J]. Vacuum Electronics, 2002, 19(4): 18–22. (in Chinese)
LI Zhen-mei, DONG Chuan-dai, FANG Hua-ling. PDP display technic and application[J]. Journal of Shandong Institute of Technology, 2002, 16(4): 10–13. (in Chinese)
YU Xiang-yang, LU Zhong-xin, CHEN Wei, et al. Development of color picture tube and applied research of glass materials[J]. Glass and Enamel, 2001, 29(4): 36–40. (in Chinese)
BU Ren-an, WANG Wei-jiang, XU Wei-jun. Glass substrate for color plasma panels(PDP) [J]. Vacuum Electronics, 1999(1): 43–48. (in Chinese)
Morena R. Phosphate glasses as alternatives to Pb-based sealing frits[J]. J Non-cryst Solids, 2000, 263–264: 382–387.
Jung B H, Kim H S. Influence of Nd2O3 on the thermal and dielectric properties of Pb-based lead borosilicate glasses[J]. J Non-cryst Solids, 2004, 336(2): 96–101.
Wang C H. The microstructure and characteristics of 0.875PZT-0.125PMN ceramics with additions of Pb-based flux[J]. J Euro Ceram Soc, 2002, 22(12): 2033–2038.
Metcalfe B L, Donald I W. Development of a low temperature phosphate sealing glass [J]. Silicates Industries, 1991, 5: 99–105.
Wang T H, James P F. Hermetic glass sealing of AlN packages for high temperature applications[A]. Proceedings of the 2nd International Conference on New Materials and their Application[C]. Warwick, UK: University of Warwick Press, 1990.
Andrews A I. Porcelain enamels: the preparation, application, and properties of enamels (2nd Edn) [M]. Maryland: Garrard Champaign Press, 1991.
Filmer B. Lead free glass for electric lamps[P]. European 603933, 1992-11-26.
George L, Thomas, Edward L, et al. Glass Composition[P]. US 408694, 1978-08-05.
Masuda H, Kimura R, Ssakamoto N, et al. Properties and structure of glasses in the system BaO-B2O3-ZnO[J]. J Jpn Inst Met, 1999, 63: 284–288.
Kim D N, Lee J Y, Hus J S, et al. Thermal and electrical properties of BaO-B2O3-ZnO glasses[J]. J Non-cryst Solids, 2002, 306(1): 70–75.
Lower N P, McRae J L, Feller H A, et al. Physical properties of alkaline-earth and alkali borate glasses prepared over an extended renge of compositions[J]. J Non-cryst Solids, 2001, 293–295: 669–675.
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Lu, Ax., Li, X. & Lin, N. Forming regularity and relation between composition and property of B2O3-BaO-ZnO glass. J Cent. South Univ. Technol. 12, 521–525 (2005). https://doi.org/10.1007/s11771-005-0115-9
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DOI: https://doi.org/10.1007/s11771-005-0115-9