Skip to main content
Log in

Thermochemical material removal of diamond by solid iron and mischmetal

  • Production Process
  • Published:
Production Engineering Aims and scope Submit manuscript

Abstract

Solid iron and mischmetal (Ce, La, Fe, etc. alloy) were used to remove material from single crystal diamond. Contact experiments with diamond and mischmetal were carried out at 600°C and 750°C with hold times from 3 to 24 h. Contact experiments with diamond and iron were performed at 850°C with hold times of 3, 4 and 5 h. In the case of mischmetal, material removal was only observed for temperatures of 750°C with hold times of 16 h or more. In these experiments it was found that material was removed only at certain areas of the contact surface whereas for the iron experiments material was removed over the entire contact surface.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Karlsson M, Nikolajeff F (2003) Diamond micro-optics: microlenses and antireflection structured surfaces for the infrared spectral region. Opt Exp 11:502–507

    Article  Google Scholar 

  2. Jin S, Graebner J, Kammlott G, Tiefel T, Kosinski S, Chen L (1992) Massive thinning of diamond films by diffusion process. Appl Phys Lett 60(16):1948–1950

    Article  Google Scholar 

  3. Brinksmeier E, Gläbe R, Osmer J (2006) Ultra-precision diamond cutting of steel molds. Ann CIRP 55(1):551–554

    Article  Google Scholar 

  4. Paul E, Evans C, Mangamelli A, McGlauflin M, Polvani R (1996) Chemical aspects of tool wear in single point diamond turning. Prec Eng 18:4–19

    Article  Google Scholar 

  5. Jin S, Chen L, Graebner J, McCormack M, Reiss M (1993) Thermal conductivity in molten-metal-etched diamond films. Appl Phys Lett 63(5):622–624

    Article  Google Scholar 

  6. Jin S, Graebner J, McCormack M, Tiefel T, Katz A, Dautremont-Smith W (1993) Shaping of diamond films by etching with molten rare-earth metals. Nature 362:822–824

    Article  Google Scholar 

  7. Sun Y, Wang S, Tian S, Wang Y (2006) Polishing of diamond thick films by Ce at lower temperatures. Diam Relat Mater 15:1412–1417

    Article  Google Scholar 

  8. Madelung O (ed) (1992) Landolt–Börnstein—Group IV physical chemistry numerical data and functional relationships in science and technology, vol 5b. Springer, Heidelberg

  9. Jin S, Mavoori H (1998) Processing and properties of CVD diamond for thermal management. J Electron Mater 27(11):1148–1153

    Article  Google Scholar 

  10. Jin S, Graebner J, Tiefel T, Kammlott G, Zydzik G (1992) Polishing of CVD diamond by diffusional reaction with manganese powder. Diam Relat Mater 1(9):949–953

    Article  Google Scholar 

  11. Shimada S, Tanaka H, Higuchi M, Yamaguchi T, Honda S, Obata K (2004) Thermo-chemical wear mechanism of diamond tool in machining of ferrous metals. Ann CIRP 53(1):57–60

    Article  Google Scholar 

  12. Ralchenko V, Konoenko T, Pimenov S, Chernenko N, Loubnin E, Armeyev VY, Zlobin A (1993) Catalytic interaction of Fe, Ni and Pt with diamond films: patterning applications. Diam Relat Mater 2:904–909

    Article  Google Scholar 

  13. Takeuchi M, Hiramoto M, Kumagi N, Yamazaki N, Kodaira A, Sugiyama K (1993) Material properties of concrete and steel bars at elevated temperatures. In: Kussmaul K (ed) Proceedings of SMiRT 12 structural mechanics in reactor technology. Elsevier, Amsterdam, pp 133–138

Download references

Acknowledgments

The authors gratefully acknowledge the support of the German Research Foundation (DFG) through the Collaborative Research Center 747—Micro Cold Forming.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. J. Klopfstein.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Brinksmeier, E., Klopfstein, M.J. Thermochemical material removal of diamond by solid iron and mischmetal. Prod. Eng. Res. Devel. 3, 225–229 (2009). https://doi.org/10.1007/s11740-009-0159-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11740-009-0159-z

Keywords

Navigation