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Evaluation of adsorption and inhibitive properties of Capparis spinoza leaves extract on high carbon steel corrosion in acidic media

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Abstract

Capparis spinoza leaves extract (CS) was studied in HCl (0.5 mol/L) solution as a green corrosion inhibitor for the HCS using the electrochemical measurements, as potentiodynamic polarization (PdP), and electrochemical impedance spectroscopy (Eis). The PdP plots showed a mixed role of the (CS) extract, and the Eis diagrams pointed that the charge transfer resistance (Rct) increased as the concentration of (CS) increased. Inhibition efficiency reached a maximum of ~ 97%. The corrosion inhibition of HCS in acidic medium showed a good fit to the Langmuir adsorption model. The thermodynamic parameter, as ΔGads was calculated and revealed that (CS) adsorbed onto HCS surface via both chemical and physical adsorption mode. HCS surface morphology was investigated using AFM technique, ultraviolet–visible spectrometry and confirmed that the formation of a protective thin film of (CS) on the metal surface. Quantum chemical calculations were determined and supported the experimental data.

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References

  • Abdou MM, EL-Haddad MN (2022) Synthesis of tolyl guanidine as copper corrosion inhibitor with a complementary study on electrochemical and in silico evaluation. Sci Rep 12:14893. https://doi.org/10.1038/s41598-022-18755-y

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Aliyazicioglu R, Eyupoglu OE, Sahin H, Yildiz O, Baltas N (2013) Phenolic components, antioxidant activity, and mineral analysis of Capparis spinosa L. Afr J Biotechnol 12:6643–6649. https://doi.org/10.5897/AJB2013.13241

    Article  CAS  Google Scholar 

  • Aralu CC, Chukwuemeka-Okorie HO, Akpomie KG (2021) Inhibition and adsorption potentials of mild steel corrosion using methanol extract of Gongronema latifoliuim. Appl Water Sci 11:22. https://doi.org/10.1007/s13201-020-01351-8

    Article  CAS  Google Scholar 

  • de Britto Policarpia E, Spinelli A (2020) Application of Hymenaea stigonocarpa fruit shell extract as eco-friendly corrosion inhibitor for steel in sulfuric acid. J Taiwan Inst Chem Eng 116:215–222

    Article  Google Scholar 

  • Doubi M, About S, Erramli H, Dermaj A, Chebabe D, Touir R, Hajjaji N, Biari A (2021) Performance of the novel corrosion inhibitor based on Cetamine to protect mild steel in surface water solution: electrochemical and surface studies. Chem Papers 75:71679–71690. https://doi.org/10.1007/s11696-020-01413-w

    Article  CAS  Google Scholar 

  • El-Haddad MN (2013) Chitosan as a green inhibitor for copper corrosion in acidic medium. Int J Biol Macromol 55:142–149

    Article  CAS  PubMed  Google Scholar 

  • El-Haddad MN (2016) Inhibitive action and adsorption behavior of cefotaxime drug at copper/hydrochloric acid interface: electrochemical, surface and quantum chemical studies. RSC Adv 6:57844

    Article  CAS  Google Scholar 

  • El-Haddad MN, Elattar KM (2013) Role of novel oxazocine derivative as corrosion inhibitor for 304 stainless steel in acidic chloride pickling solutions. Res Chem Intermed 39:3135–3149. https://doi.org/10.1007/s11164-012-0826-0

    Article  CAS  Google Scholar 

  • El-Haddad MN, Elattar KM (2015) Synthesis, characterization and inhibition effect of new antipyrinyl derivatives on mild steel corrosion in acidic solution. Int J Ind Chem 6:105–117. https://doi.org/10.1007/s40090-015-0037-9

    Article  CAS  Google Scholar 

  • El-Haddad MN, Fouda AS (2013) Corrosion inhibition and adsorption behavior of some azo dye derivatives on carbon steel in acidic medium: synergistic effect of halide ions. Chem Eng Comm 200:1366–1393

    Article  CAS  Google Scholar 

  • El-Haddad MN, Fouda AS (2015) Electroanalytical, quantum and surface characterization studies on imidazole derivatives as corrosion inhibitors for aluminum in acidic media. J Mol Liq 209:480–486

    Article  CAS  Google Scholar 

  • EL-Haddad MN (2014m) Hydroxyethylcellulose used as an eco-friendly inhibitor for 1018m c-steel corrosion in 3.5% NaCl solution. Carbohydr Polym 112:595–602

    Article  CAS  PubMed  Google Scholar 

  • Fouda AS, Badr GE, El-Haddad MN (2008) The inhibition of C-steel corrosion in H3PO4 solution by some furfural hydrazone derivatives. J Korean Chem Soc 52:142–132

    Article  Google Scholar 

  • Fouda AS, ElHaddad MN, Ismail MA, Abd Elgyed A (2019) Investigation of 6-[5-(4-Methoxyphenyl) furan-2-yl] Nicotinonitrile as a new corrosion inhibitor for carbon steel in acidic solution: chemical, electrochemical and quantum chemical studies. J Bio Tribo Corros 5:73

    Article  Google Scholar 

  • Guruprasad AM, Sachin HP (2021) Novel cost-effective aqueous Amorphophallus paeoniifolius leaves extract as a green corrosion inhibitor for mild steel corrosion in hydrochloric acid medium: a detailed experimental and surface characterization studies. Chem Data Collect 34:100734

    Article  CAS  Google Scholar 

  • Ismail MA, Shaban MM, Abdel-Latif E, Abdelhamed FH, Migahed MA, El-Haddad MN, Abousalem AS (2022) Novel cationic aryl bithiophene/terthiophene derivatives as corrosion inhibitors by chemical, electrochemical and surface investigations. Sci Rep 12:3192. https://doi.org/10.1038/s41598-022-06863-8

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Khadom AA, Abd AN, Ahmed NA (2018) Xanthium strumarium leaves extracts as a friendly corrosion inhibitor of low carbon steel in hydrochloric acid: Kinetics and mathematical studies. S Afr J Chem Eng 25:13–21

    Google Scholar 

  • Luo H, Sohn SS, Lu W, Li L, Li X, Soundararajan CK, Krieger W, Li Z, Raabe D (2020) A strong and ductile medium-entropy alloy resists hydrogen embrittlement and corrosion. Nat Commun 11:3081

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Prakash PMP, Kathiresan KSA (2018) Benign approach of plant-derived inhibitor: assessing their anticorrosive activity on mild steel in acidic media. J Fail Anal Prev 18:1677–1689. https://doi.org/10.1007/s11668-018-0461-1

    Article  Google Scholar 

  • Raghavendra N, IshwaraBhat J (2016) Green approach to inhibition of corrosion of aluminum in 0.5 M HCl medium by tender arecanut seed extract. Res Chem Intermed 42:6351–6372

    Article  CAS  Google Scholar 

  • Raghavendra N, Kumaraswamy BE (2021a) Elaeocarpus seed extraction and their impact as a corrosion inhibitor for mild steel submerged in HCl wash solution: insight from experimental, mathematical, and theoretical views. Fail Anal Prev 21:958–975. https://doi.org/10.1007/s11668-021-01141-7

    Article  Google Scholar 

  • Raghavendra N, Kumaraswamy BE (2021b) Elaeocarpus seed extraction and their impact as a corrosion inhibitor for mild steel submerged in HCl wash solution: insight from experimental, mathematical, and theoretical views. J Fail Anal Prev 21:958–975. https://doi.org/10.1007/s11668-021-01141-7

    Article  Google Scholar 

  • Raja PB, Sethuraman MG (2008) Natural products as corrosion inhibitor for metals in corrosive media—a review. Mater Lett 62:113–116. https://doi.org/10.1016/j.matlet.2007.04.079

    Article  CAS  Google Scholar 

  • Rathod MR, Rajappa SK, Praveen BM, Bharath DK (2021) Investigation of Dolichandra unguis-cati leaves extract as a corrosion inhibitor for mild steel in acid medium. Curr Res Green Sustain Chem 4:100113

    Article  CAS  Google Scholar 

  • Shahini MH, Keramatinia M, Ramezanzadeh M, Ramezanzadeh B, Bahlakeh G (2021a) Combined atomic-scale/DFT-theoretical simulations & electrochemical assessments of the chamomile flower extract as a green corrosion inhibitor for mild steel in HCl solution. J Mol Liq 342:117570

    Article  CAS  Google Scholar 

  • Shahini MH, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B (2021b) Superior inhibition action of the Mish Gush (MG) leaves extract toward mild steel corrosion in HCl solution: theoretical and electrochemical studies. J Mol Liq 332:115876

    Article  CAS  Google Scholar 

  • Victoria SN, Prasad R, Manivannan R (2015) Psidium guajava leaf extract as green corrosion inhibitor for mild steel in phosphoric acid. Int J Electrochem Sci 10:2220–2238

    Article  CAS  Google Scholar 

  • Yang X, Zhang R, Pu J, He Z, Xiong L (2021) 2D graphene and h-BN layers application in protective coatings. Corros Rev 39:93–107

    Article  CAS  Google Scholar 

  • Zhang M, Guo L, Zhu M, Wang K, Zhang R, He Z, Lin Y, Leng S, Anadebe VC, Zheng X (2021) Akebia trifoliate koiaz peels extract as environmentally benign corrosion inhibitor for mild steel in HCl solutions: integrated experimental and theoretical investigations. J Ind Eng Chem 101:227–236

    Article  CAS  Google Scholar 

  • Zuo X, Li W, Luo W, Zhang X, Qiang Y, Zhang J, Li H, Tan B (2021) Research of Lilium brownii leaves extract as a commendable and green inhibitor for X70 steel corrosion in hydrochloric acid. J Mol Liq 321:114914

    Article  CAS  Google Scholar 

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Acknowledgements

The author would like to thank Division of chemistry stuff, Faculty of Applied Science, SA for their excellent technical assistance during the work.

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  1. Chemistry Department, Faculty of Applied Science, Umm Al-Qura University, 21955, Makkah, Saudi Arabia

    Badreah A. Al Jahdaly

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  1. Badreah A. Al Jahdaly
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Al Jahdaly, B.A. Evaluation of adsorption and inhibitive properties of Capparis spinoza leaves extract on high carbon steel corrosion in acidic media. Chem. Pap. 77, 6605–6612 (2023). https://doi.org/10.1007/s11696-023-02961-7

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