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Elaeocarpus Seed Extraction and Their Impact as a Corrosion Inhibitor for Mild Steel Submerged in HCl Wash Solution: Insight from Experimental, Mathematical, and Theoretical Views

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Abstract

Herein, Elaeocarpus seed (ES) extract was studied in 3 M HCl solution as a efficacy corrosion inhibitor for the mild steel through mass loss, electrochemical Tafel diagrams, impedance spectroscopy, atomic absorption spectroscopy, scanning electron microscopy, and EDX techniques. During weight loss technique, it is observed that increasing the concentration enhances the protective role of the plant product. The Tafel diagrams showed a mixed role of the ES extract. In impedance spectroscopy, the area of depressed semicircle has a direct relationship with the plant extract concentration, which clearly demonstrating the inhibition property of ES extract. 93.370, 97.111, 89.015, and 90.528% are the maximum inhibition efficiencies obtained from the weight loss, atomic absorption spectroscopy, Tafel plot, and impedance spectroscopy techniques, respectively. Mathematical and quantum chemical studies further support the experimental results.

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References

  1. D. Nestoridia, Pletcher, The study of aluminium anodes for high power density Al/air batteries with brine electrolytes. J. Power. Sour. 178, 445–455 (2008)

    Article  Google Scholar 

  2. E.M. Sherif, S.M. Park, Effects of 1, 4-naphthoquinone on aluminum corrosion in 0.50 M sodium chloride solutions. Electrochim. Acta. 51, 1313–1321 (2006)

    Article  CAS  Google Scholar 

  3. E.J. Lee, S.J. Pyun, The effect of oxide chemistry on the passivity of aluminum surfaces. Corros. Sci. 37, 157–168 (1995)

    Article  CAS  Google Scholar 

  4. R.T. Loto, Q. Tobilola, Corrosion inhibition properties of the synergistic effect of 4-hydroxy-3-methoxybenzaldehyde and hexadecyltrimethylammoniumbromide on mild steel in dilute acid solutions. J. King Saud Univ. Eng. Sci. (2016). https://doi.org/10.1016/j.jksues.2016.10.001

    Article  Google Scholar 

  5. N. Raghavendra, J. Ishwara Bhat, Red arecanut seed extract as a sustainable corrosion inhibitor for aluminum submerged in acidic corrodent. Period. Polytech. Chem. 62, 351–6358 (2018)

    Article  CAS  Google Scholar 

  6. N. Chaubey, Y. Dk, V.K. Singh, M.A. Quraishi, A comparative study of leaves extracts for corrosion inhibition effect on aluminium alloy in alkaline medium. Ain Shams Eng. J. 8, 673–682 (2017)

    Article  Google Scholar 

  7. F.M. BinYehmed, A.M. Abdullah, Z. Zainal, Z.M. Ruzniza, Green coffee bean extract as a green corrosion inhibitor for aluminium in artificial acid rain medium. Int. J. Appl. Environ. Sci. 13, 171–183 (2018)

    Google Scholar 

  8. N. Palaniappan, L. RajuChowhan, S. Jothi, I.G. Bosco, I.S. Cole, Corrosion inhibition on mild steel by phosphonium salts in 1M HNO3 aqueous medium. Surf Interface. 6, 237–246 (2017)

    Article  CAS  Google Scholar 

  9. M.H. Othman Ahmed, A.A. Al-Amiery, Y.K. Al-Majedy, A.A.H. Kadhum, A.B. Mohamad, T.S. Gaaz, Synthesis and characterization of a novel organic corrosion inhibitor for mild steel in 1 M hydrochloric acid. Results Phys. 8, 728–733 (2018)

    Article  Google Scholar 

  10. N. Raghavendra, J. IshwaraBhat, Green approach to inhibition of corrosion of aluminum in 0.5 M HCl medium by tender arecanut seed extract. Res. Chem. Intermed. 42, 6351–6372 (2016)

    Article  CAS  Google Scholar 

  11. N. Raghavendra, J. IshwaraBhat, Natural products for material protection: an interesting and efficacious anticorrosive property of dry arecanut seed extract at electrode (aluminum)–electrolyte (hydrochloric acid) interface. J. Bio. Tribo. Corros. 2, 21 (2016)

    Article  Google Scholar 

  12. A. Saxena, D. Prasad, R. Haldhar, Use of Asparagus racemosus extract as green corrosion inhibitor for mild steel in 0.5 M H2SO4. J. Mater. Sci. 53, 8523–8535 (2018)

    Article  CAS  Google Scholar 

  13. U.F. Ekanem, S.A. Umore, I.I. Udousoro, A.P. Udoh, Inhibition of mild steel corrosion in HCl using pineapple leaves (Ananas comosus L.) extract. J. Mater. Sci. 45, 5558 (2010)

    Article  CAS  Google Scholar 

  14. M. HazwanHussin, M. JainKassim, The corrosion inhibition and adsorption behavior of Uncaria gambir extract on mild steel in 1 M HCl. Mater. Chem. Phys. 125, 461 (2011)

    Article  Google Scholar 

  15. A. Singh, I. Ahamad, V.K. Singh, M.A. Quraishi, Inhibition effect of environmentally benign Karanj (Pongamia pinnata) seed extract on corrosion of mild steel in hydrochloric acid solution. J. Solid State Electrochem. 15, 1087 (2011)

    Article  CAS  Google Scholar 

  16. G. Ji, S.K. Shukla, P. Dwivedi, S. Sundaram, R. Prakash, Inhibitive effect of argemone mexicana plant extract on acid corrosion of mild steel. Ind. Eng. Chem. Res. 50, 11954 (2011)

    Article  CAS  Google Scholar 

  17. P.K. Dixit, S. Dixit, M. Bhardwaj, B. Chauhan, K. Nagarajan, J. Sahoo, A review on traditional and ethnomedicinal uses of Elaeocarpus ganitrus(Rudraksha). Int. J. Pharm. Sci. Rev. Res. 52, 1 (2018)

    CAS  Google Scholar 

  18. G. Kumar, L. Karthik, K. Venkata, B. Rao, A review on medicinal properties of elaeocarpus ganitrus Roxbex. G.Don. (Elaeocarpaceae). Res. J. Pharm. Tech. 7, 1 (2014)

    Google Scholar 

  19. J.Y. Bao, M. Cai, G. Sun, G. Wang, H. Corke, Anthocyanins, flavonoids and free radical scavenging activity of myrialrubia extracts and their color properties and stability. J. Agric. Food Chem. 53, 2327 (2005)

    Article  CAS  Google Scholar 

  20. N. Raghavendra, Theoretical approaches on the corrosion inhibition property of some important medicinal compounds against industrial imperative metals via computational methods. Res. J. Chem. Sci. 9, 1 (2019)

    CAS  Google Scholar 

  21. N. Raghavendra, J. IshwraBhat, Application of green products for industrially important materials protection: an amusing anticorrosive behavior of tender arecanut husk (green color) extract at metal-test solution interface. Measurement. 135, 625–639 (2019)

    Article  Google Scholar 

  22. N. Raghavendra, Green compounds to attenuate aluminum corrosion in HCl activation: a necessity review. Chemistry Africa 3, 21 (2020). https://doi.org/10.1007/s42250-019-00114-6

    Article  CAS  Google Scholar 

  23. S. Boudhiba, K. Hanini, I. Selatnia, A. Saouane, M. Hioun, S. Benahmed, Experimental, theoretical and mathematical studies of Echium italicum L. extract as a corrosion inhibitor for carbon steel in acidic medium. (Res. Express, Mater, 2019) https://doi.org/10.1088/2053-1591/ab194f.2019

    Book  Google Scholar 

  24. P.M. Krishnegowda, V.T. Venkatesha, P. Kumar, M. Krishnegowda, S.B. Shivayogiraju, Acalypha torta leaf extract as green corrosion inhibitor for mild steel in hydrochloric acid solution. Ind. Eng. Chem. Res. 52, 722–728 (2013)

    Article  CAS  Google Scholar 

  25. L.R. Chauhan, G. Gunasekaran, Corrosion inhibition of mild steel by plant extract in dilute HCl medium. Corros. Sci. 49, 1143–1161 (2007)

    Article  CAS  Google Scholar 

  26. P.E. Alvarez, M.V. Fiori, A. Bimbi, A. Neske, S.A. Brandán, C.A. Gervasi, Rollinia occidentalis extract as green corrosion inhibitor for carbon steel in HCl solution. J. Ind. Eng. Chem. 58, 92–99 (2018)

    Article  CAS  Google Scholar 

  27. E. Ituen, O. Akaranta, A. James, S. Sun, Green and sustainable local biomaterials for oilfield chemicals: Griffonia simplicifolia extract as steel corrosion inhibitor in hydrochloric acid. Sustain. Mater. Technol. 11, 12 (2017)

    CAS  Google Scholar 

  28. N. Raghavendra, J.I. Bhat, Chemical components of mature areca nut husk extract as a potential corrosion inhibitor for mild steel and copper in both acid and alkali media. Chem. Eng. Commun. 205, 145–160 (2018)

    Article  CAS  Google Scholar 

  29. N. Raghavendra, J.I. Bhat, Chemical and electrochemical studies on the areca fat as a novel and sustainable corrosion inhibitor for industrially important materials in hostile fluid environments. J. Bio. Tribo. Corros. 3, 12 (2018)

    Article  Google Scholar 

  30. N. Raghavendra, Areca plant extracts as a green corrosion inhibitor of carbon steel metal in 3 M hydrochloric acid: gasometric, colorimetry and atomic absorption spectroscopy views. Mol. Eng. Mater. (2019). https://doi.org/10.1142/S2251237318500041

    Article  Google Scholar 

  31. J.C. Rocha, J.A.C.P. Gomes, E. Delia, Corrosion inhibition of carbon steel in hydrochloric acid solution by fruit peel aqueous extracts. Corros. Sci. 52, 2341 (2010)

    Article  Google Scholar 

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Raghavendra, N., Kumaraswamy, B.E. Elaeocarpus Seed Extraction and Their Impact as a Corrosion Inhibitor for Mild Steel Submerged in HCl Wash Solution: Insight from Experimental, Mathematical, and Theoretical Views. J Fail. Anal. and Preven. 21, 958–975 (2021). https://doi.org/10.1007/s11668-021-01141-7

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