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The construct of a novel threefold interpenetrating uranium-organic framework as a sensor for detecting Ru3+

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Abstract

A two-dimensional threefold interpenetrated uranium-organic framework (UOF) has been synthesized by the solvothermal method with a highly luminescent response of various molecules. The structure of the compound is characterized by the single-crystal X-ray diffraction, [C27H17O11U] [C2H6N]·DMF·2H2O·(UTCPB), with a six-coordinated uranyl cation, further proved by the IR, TG and others tests. To explore the functional properties, photoluminescent, dye adsorption, and metal detecting properties have been also studied and discussed initially. The results showed that the compound exhibited some features in dye adsorption (RhB) and Ru3+ detection.

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The datasets generated during and analyzed during the current study are available from the corresponding author on reasonable request.

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Figure 1~3, Diamond. Figure 4~9, Origin.

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Funding

This work was supported by the National Natural Science Foundation of China (No.21671156).

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Contributions

LTC, Draft writing and the synthesis of the material; XLZ, Basic characteristic of the material; GFH, Data analysis; NSW, Crystal structure refinement; JSZ, Finical supporting and supervisor; CYL, Supervisor.

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Correspondence to Jian-She Zhao or Chi-Yang Liu.

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Chen, LT., Zhang, XL., Hu, GF. et al. The construct of a novel threefold interpenetrating uranium-organic framework as a sensor for detecting Ru3+. Chem. Pap. 77, 1721–1727 (2023). https://doi.org/10.1007/s11696-022-02587-1

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  • DOI: https://doi.org/10.1007/s11696-022-02587-1

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