Abstract
In the field of printed electronics, carbon and its allotropes are today among the most studied materials due to their unique physical and chemical properties. In this work, carbon dispersions were used for the preparation of screen-printed carbon electrodes applied as counter electrodes (CEs) for the dye-sensitized solar cells and as working electrodes for electrochemical sensing. Following the simple and quick homogenization process, carbon dispersions were subjected to thermogravimetric analysis to closely examine drying, eventually sintering processes after printing. The influence of the graphite:carbon black ratio was investigated. The structure of composite carbon layers was analyzed by scanning electron microscopy and optical microscopy. The DSSC CEs printed from the dispersion containing 100 wt% of CB exhibited the highest catalytic activity for the effective reduction of oxidized triiodide I3− back to iodide I− within the solar cell. The highest conversion efficiency achieved for the high-temperature processed CE was 3.05% with the fill factor of 0.65. The same composition of the carbon WE was used for the quantitative analysis of neurotransmitter dopamine. Based on the cyclic voltammetry measurements, the sensor showed a limit of detection of 13.3 nM for dopamine.
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References
Arumugasamy SK, Govindaraju S, Yun K (2020) Electrochemical sensor for detecting dopamine using graphene quantum dots incorporated with multiwall carbon nanotubes. Appl Surf Sci 508:145294. https://doi.org/10.1016/j.apsusc.2020.145294
Baccarin M, Santos FA, Vicentini FC, Zucolotto V, Janegitz BC, Fatibello-Filho O (2017) Electrochemical sensor based on reduced graphene oxide/carbon black/chitosan composite for the simultaneous determination of dopamine and paracetamol concentrations in urine samples. J Electroanal Chem 799:436–443. https://doi.org/10.1016/j.jelechem.2017.06.052
Barichello J, Vesce L, Matteocci F, Lamanna E, Di Carlo A (2019) The effect of water in Carbon-Perovskite Solar Cells with optimized alumina spacer. Sol Energy Mater Sol Cells 197:76–83. https://doi.org/10.1016/j.solmat.2019.03.029
Bong HK, Pestov SM, Flid VR, Karaeva AR, Peshnev BV (2017) The adsorption properties of the sorbents based on nanofibrous carbon. Open J Appl Sci 7:720–728. https://doi.org/10.4236/ojapps.2017.712051
Brown GF, Wu J (2009) Third-generation photovoltaics. Laser Photon Rev 3:394–405. https://doi.org/10.1002/lpor.200810039
Chen M, Shao LL (2016) Review on the recent progress of carbon counter electrodes for dye-sensitized solar cells. Chem Eng J 304:629–645. https://doi.org/10.1016/j.cej.2016.07.001
Couto RA, Lima JL, Quinaz MB (2016) Recent developments, characteristics and potential applications of screen-printed electrodes in pharmaceutical and biological analysis. Talanta 146:801–814. https://doi.org/10.1016/j.talanta.2015.06.011
Demuru S, Nela L, Marchack N, Holmes SJ, Farmer DB, Tulevski GS, Lin Q, Deligianni H (2018) Scalable nanostructured carbon electrode arrays for enhanced dopamine detection. ACS Sens 3:799–805. https://doi.org/10.1021/acssensors.8b00043
Domínguez Renedo O, Alonso-Lomillo MA, Arcos Martínez MJ (2007) Recent developments in the field of screen-printed electrodes and their related applications. Talanta 73:202–219. https://doi.org/10.1016/j.talanta.2007.03.050
Fujiwara N, Yamamoto H (2019) Evaluation of adsorption of organic solvents to modified hydrophobic silica adsorbents based on Hansen solubility parameter. Sep Purif Technol 210:907–912. https://doi.org/10.1016/j.seppur.2018.08.034
Gemeiner P, Kuliček J, Mikula M, Hatala M, Švorc Ľ, Hlavatá L, Mičušík M, Omastová M (2015) Polypyrrole-coated multi-walled carbon nanotubes for the simple preparation of counter electrodes in dye-sensitized solar cells. Synth Met 210:323–331. https://doi.org/10.1016/j.synthmet.2015.10.020
Gören A, Mendes J, Rodrigues HM, Sousa RE, Oliveira J, Hilliou L, Costa CM, Silva MM, Lanceros-Méndez S (2016) High performance screen-printed electrodes prepared by a green solvent approach for lithium-ion batteries. J Power Sources 334:65–77. https://doi.org/10.1016/j.jpowsour.2016.10.019
Grieshaber D, MacKenzie R, Vörös J, Reimhult E (2008) Electrochemical biosensors-sensor principles and architectures. Sensors 8(3):1400–1458. https://doi.org/10.3390/s80314000 (Basel)
Hatala M, Gemeiner P, Hvojnik M, Mikula M (2019) The effect of the ink composition on the performance of carbon-based conductive screen printing inks. J Mater Sci Mater Electron 30:1034–1044. https://doi.org/10.1007/s10854-018-0372-7
Hinsch A, Behrens S, Berginc M, Bönnemann H, Brandt H, Drewitz A, Einsele F, Faßler D, Gerhard D, Gores H, Haag R, Herzig T, Himmler S, Khelashvili G, Koch D, Nazmutdinova G, Opara-Krasovec U, Putyra P, Rau U, Sastrawan R, Schauer T, Schreiner C, Sensfuss S, Siegers C, Skupien K, Wachter P, Walter J, Wasserscheid P, Würfel U, Zistler M (2008) Material development for dye solar modules: results from an integrated approach. Prog Photovolt Res Appl 16:489–5011. https://doi.org/10.1002/pip.832
Ibáñez-Redín G, Wilson D, Gonçalves D, Oliveira ON (2018) Low-cost screen-printed electrodes based on electrochemically reduced graphene oxide-carbon black nanocomposites for dopamine, epinephrine and paracetamol detection. J Colloid Interface Sci 515:101–108. https://doi.org/10.1016/j.jcis.2017.12.085
Kay A, Grätzel M (1996) Low cost photovoltaic modules based on dye sensitized nanocrystalline titanium dioxide and carbon powder. Sol Energy Mater Sol Cells 44:99–117. https://doi.org/10.1016/0927-0248(96)00063-3
Kim JM, Rhee SW (2012) Electrochemical properties of porous carbon black layer as an electron injector into iodide redox couple. Electrochim Acta 83:264–270. https://doi.org/10.1016/j.electacta.2012.07.107
Kim DS, Kang ES, Baek S, Choo SS, Chung YH, Lee D, Min J, Kim TH (2018) Electrochemical detection of dopamine using periodic cylindrical gold nanoelectrode arrays. Sci Rep 8:14049. https://doi.org/10.1038/s41598-018-32477-0
Krueger A (2010) Carbon materials and nanotechnology. Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
Li M, Li YT, Li DW, Long YT (2012) Recent developments and applications of screen-printed electrodes in environmental assays—a review. Anal Chim Acta 734:31–44. https://doi.org/10.1016/j.aca.2012.05.018
Li CT, Lee CT, Li SR, Lee CP, Chiu IT, Vittal R, Wu NL, Sun SS, Ho KC (2016) Composite films of carbon black nanoparticles and sulfonated-polythiophene as flexible counter electrodes for dye-sensitized solar cells. J Power Sources 302:155–163. https://doi.org/10.1016/j.jpowsour.2015.10.028
Li M, Li DW, Xiu G, Long YT (2017) Applications of screen-printed electrodes in current environmental analysis. Curr Opin Electrochem 3:137–143. https://doi.org/10.1016/j.coelec.2017.08.016
Lounasvuori MM, Kelly D, Foord JS (2018) Carbon black as low-cost alternative for electrochemical sensing of phenolic compounds. Carbon 129:252–257. https://doi.org/10.1016/j.carbon.2017.12.020
Maniarasu S, Korukonda TB, Manjunath V, Ramasamy E, Ramesh M, Veerappan G (2018) Recent advancement in metal cathode and hole-conductor-free perovskite solar cells for low-cost and high stability: a route towards commercialization. Renew Sustain Energy Rev 82:845–857. https://doi.org/10.1016/j.rser.2017.09.095
Miao X, Pan K, Pan Q, Zhou W, Wang L, Liao Y, Tian G, Wang Q (2013) Highly crystalline graphene/carbon black composite counter electrodes with controllable content: Synthesis, characterization and application in dye-sensitized solar cells. Electrochim Acta 96:155–163. https://doi.org/10.1016/j.electacta.2013.02.092
Mohamed HM (2016) Screen-printed disposable electrodes: pharmaceutical applications and recent developments. Trends Anal Chem 82:1–11. https://doi.org/10.1016/j.trac.2016.02.010
Murakami TN, Grätzel M (2008) Counter electrodes for DSC: application of functional materials as catalysts. Inorg Chim Acta 361:572–580. https://doi.org/10.1016/j.ica.2007.09.025
Murakami TN, Ito S, Wang Q, Nazeeruddin MK, Bessho T, Cesar I, Liska P, Humphry-Baker R, Comte P, Péchy P, Grätzel M (2006) Highly efficient dye-sensitized solar cells based on carbon black counter electrodes. J Electrochem Soc 153:A2255–A2261. https://doi.org/10.1149/1.2358087
Park HK, Kim SM, Lee JS, Park JH, Hong YK, Hong CH, Kim KK (2015) Flexible plane heater: graphite and carbon nanotube hybrid nanocomposite. Synth Met 203:127–134. https://doi.org/10.1016/j.synthmet.2015.02.015
Tao H, Li Y, Zhang C, Wang K, Wang J, Tan B, Han L, Tao J (2018) High permeable microporous structured carbon counter electrode assisted by polystyrene sphere for fully printable perovskite solar cells. Solid State Commun 271:71–75. https://doi.org/10.1016/j.ssc.2017.12.022
Veerappan G, Bojan K, Rhee SW (2011) Sub-micrometer-sized graphite as a conducting and catalytic counter electrode for dye-sensitized solar cells. ACS Appl Mater Interfaces 3:857–862. https://doi.org/10.1021/am101204f
Vesce L, Riccitelli R, Mincuzzi G, Orabona A, Soscia G, Brown TM, Di Carlo A, Reale A (2013) Fabrication of spacer and catalytic layers in monolithic dye-sensitized solar cells. IEEE J Photovolt 3:1004–1011. https://doi.org/10.1109/JPHOTOV.2013.2262374
Vusa ChSR, Manju V, Berchmans S, Arumugam P (2016) Electrochemical amination of graphene using nanosized PAMAM dendrimers for sensing applications. RSC Adv 6:33409–33418. https://doi.org/10.1039/C5RA27862G
Wang L, Wang Y, Zhuang Q (2019) Simple self-referenced ratiometric electrochemical sensor for dopamine detection using electrochemically pretreated glassy carbon electrode modified by acid-treated multiwalled carbon nanotube. J Electroanal Chem 851:113446. https://doi.org/10.1016/j.jelechem.2019.113446
Wiench P, González Z, Menéndez R, Grzyb B, Gryglewicz G (2018) Beneficial impact of oxygen on the electrochemical performance of dopamine sensors based on N-doped reduced graphene oxides. Sens Actuators B Chem 257:143–153. https://doi.org/10.1016/j.snb.2017.10.106
Wu CS, Chang TW, Teng H, Lee YL (2016) High performance carbon black counter electrodes for dye-sensitized solar cells. Energy 115:513–518. https://doi.org/10.1016/j.energy.2016.09.052
Yamanaka K, Vestergaard MC, Tamiya E (2016) Printable electrochemical biosensors: a focus on screen-printed electrodes and their application. Sensors 16:1761. https://doi.org/10.3390/s16101761
Yuan Q, Liu Y, Ye C, Sun H, Dai D, Wei Q, Lai G, Wu T, Yu A, Fu L, Chee KWA, Lin ChT (2018) Highly stable and regenerative graphene–diamond hybrid electrochemical biosensor for fouling target dopamine detection. Biosens Bioelectron 111:117–123. https://doi.org/10.1016/j.bios.2018.04.006
Zheng S, Huang R, Ma X, Tang J, Li Z, Wang X, Wei J, Wang J (2018) A highly sensitive dopamine sensor based on graphene quantum dots modified glassy carbon electrode. Int J Electrochem Sci 13:5723–5735. https://doi.org/10.20964/2018.06.19
Acknowledgements
This work was supported by the Scientific Grant Agency, projects VEGA 1/0488/19 and VEGA 1/0403/19 and from the Slovak Research and Development Agency, projects APVV-15-0052, APVV-16-0088, APVV-17-0300 and PP-COVID-20-0019.
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Hatala, M., Gemeiner, P., Lorencová, L. et al. Screen-printed conductive carbon layers for dye-sensitized solar cells and electrochemical detection of dopamine. Chem. Pap. 75, 3817–3829 (2021). https://doi.org/10.1007/s11696-021-01601-2
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DOI: https://doi.org/10.1007/s11696-021-01601-2