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Nanocomposites of Carbon for Dye-Sensitized Solar Cell Applications

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NanoCarbon: A Wonder Material for Energy Applications

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Abstract

Efforts to make low-cost photovoltaic devices are a major part of today’s energy conversion research. The abundant, cheap, highly conductive, and easy-to-tune nature of carbon allotropes makes carbon-based nanocomposites more attractive to use in dye-sensitized solar cells (DSSC). DSSCs are photo electrocatalytic solar cells that have a device architecture involving a nanoparticular electron transport layer (ETL) which accommodates an adequate quantity of photo-active dye molecules in their mesoporous morphology where the major transport is diffusion-based. Accession of carbon-based nanocomposite materials in the ETL matrix is well-researched as they enable linear electron transport pathways. Carbon-based nanocomposites are known for their conductivity and tunability in the regimes of work function and catalytic activities. Foremost research involves nanocomposites of carbon allotropes as a replacement for the high-cost traditional Platinum counter electrode used in DSSC devices for effective regeneration. In this chapter, we will provide insight into the application of various carbonaceous nanocomposite materials both in the photo-anode and counter electrodes of a DSSC.

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References

  1. Ram, Babu, Hiroshi Mizuseki.: C568: A new two-dimensional sp2-sp3 hybridized allotrope of carbon. Carbon 158, Republic of Korea, Elsevier Ltd. (2020)

    Google Scholar 

  2. Burchfield, Larry A., Mohamed Al Fahim, Richard S. Wittman, Francesco Delodovici, Nicola Manini.: Novamene: A new class of carbon allotropes. Heliyon 3(2), USA, Elsevier Ltd. (2017)

    Google Scholar 

  3. Ding, Xian-Yong, Chao Zhang, Dong-Qi Wang, Bing-Sheng Li, Qingping Wang, Zhi Gen Yu, Kah-Wee Ang, Yong-Wei Zhang. A new carbon allotrope: T5-carbon. Scripta Materialia 189, China, Elsevier Ltd. (2020)

    Google Scholar 

  4. Janani, Murugesan, Pillalamarri Srikrishnarka, Shantikumar V. Nair, Sreekumaran Nair, A.: An in-depth review on the role of carbon nanostructures in dye-sensitized solar cells. J. Mater. Chem. A 3(35), India, RSC Publishing (2015)

    Google Scholar 

  5. Savari, Rojan, Jalal Rouhi, Omid Fakhar, Saeid Kakooei, Davoud Pourzadeh, Okhtay Jahanbakhsh, Saeid Shojaei.: Development of photo-anodes based on strontium doped zinc oxide-reduced graphene oxide nanocomposites for improving performance of dye-sensitized solar cells. Ceram. Int., 47(22), Iran, Elsevier Ltd. (2021)

    Google Scholar 

  6. Eguchi, Takuto, Shinya Kato, Naoki Kishi, Tetsuo Soga. Effect of thickness on photovoltaic properties of amorphous carbon/fullerene junction. AIMS Materials Science, 9(3), Japan, AIMS Press (2022)

    Google Scholar 

  7. Kim, Jung-Min, Shi-Woo Rhee.: Electrochemical properties of porous carbon black layer as an electron injector into iodide redox couple. Electrochimica acta 83, South Korea, Elsevier Ltd. (2012)

    Google Scholar 

  8. Kausar, Ayesha, Ishaq Ahmad, Tingkai Zhao, M.H. Eisa, Aldaghri. O.: Graphene nanofoam based nanomaterials: manufacturing and technical prospects. Nanomanufacturing 3(1), Pakistan, MDPI (2023)

    Google Scholar 

  9. Nazeeruddin, Md K., Etienne Baranoff, and Michael Grätzel. "Dye-sensitized solar cells: A brief overview. Sol. Energy, 85(6), Switzerland, Elsevier Ltd. (2011)

    Google Scholar 

  10. Bera, S., Sengupta, D., Roy, S., Mukherjee, K.: Research into dye-sensitized solar cells: a review highlighting progress in India. J. Phys.: Energy 3(3), India, IOPscience (2021)

    Google Scholar 

  11. Munukutla, L.V., Htun, A., Radhakrishanan, S., Main, L., Kannan, A.M., Tiwari, A., Boukherroub, R., Sharon, M., “Solar Cell Nanotechnology”, “Dye-Sensitized Solar Cells”,: USA. Scrivener Publishing, Wiley (2013)

    Google Scholar 

  12. Lee, Tae Young, Prashant S. Alegaonkar, Ji-Beom Yoo. Fabrication of dye sensitized solar cell using TiO2 coated carbon nanotubes. Thin solid films 515(12), Republic of Korea, Elsevier Ltd. (2007)

    Google Scholar 

  13. Kilic, Bayram, Sunay Turkdogan, Aykut Astam, Oguz Can Ozer, Mansur Asgin, Hulya Cebeci, Deniz Urk, Selin Pravadili Mucur.: Preparation of carbon nanotube/TiO2 mesoporous hybrid photoanode with iron pyrite (FeS2) thin films counter electrodes for dye-sensitized solar cell. Sci. Rep. 6(1), Turkey, Springer Nature (2016)

    Google Scholar 

  14. Ghartavol, H.M., Mohammadi, M.R. Afshar, A., Li. Y.: On the assessment of incorporation of CNT–TiO2 core–shell structures into nanoparticle TiO2 photoanodes in dye-sensitized solar cells. Photochem. Photobiol. Sci. 18, Iran, Springer Nature (2019)

    Google Scholar 

  15. Eshaghi, Akbar, Abbas Ail Aghaei.: Effect of TiO2–graphene nanocomposite photoanode on dye-sensitized solar cell performance. Bull. Mater. Sci. 38(5), Pakistan, Elsevier Ltd. (2015)

    Google Scholar 

  16. Madhavan, Asha Anish, Annapoorna Mohandas, Antonio Licciulli, K.P. Sanosh, P. Praveen, R. Jayakumar, Shantikumar V. Nair, A. Sreekumaran Nair, Avinash Balakrishnan.: Electrospun continuous nanofibers based on a TiO2–ZnO–graphene composite. RSC advances, 3(47), India, RSC Publishing (2013)

    Google Scholar 

  17. Madhavan, Asha Anish, Sujith Kalluri, Daya K. Chacko, T.A. Arun, Sivakumar Nagarajan, Kavasseri RV Subramanian, A. Sreekumaran Nair, Shantikumar V. Nair, Avinash Balakrishnan. Electrical and optical properties of electrospun TiO2-graphene composite nanofibers and its application as DSSC photo-anodes. RSC advances, 2(33), India, RSC Publishing (2012)

    Google Scholar 

  18. Pallikkara, Athira, and Kala Ramakrishnan.: Efficient charge collection of photoanodes and light absorption of photosensitizers: A review. Int. J. Energy Res. 45(2), India, Wiley (2021)

    Google Scholar 

  19. Lee, Hoik, Tomoki Nagaishi, Duy-Nam Phan, Myungwoong Kim, Ke-Qin Zhang, Kai Wei, Ick Soo Kim. Effect of graphene incorporation in carbon nanofiber decorated with TiO2 for photoanode applications. RSC advances, 7(11), Japan, RSC Publishing (2017)

    Google Scholar 

  20. Park, Hun, Woong-Rae Kim, Changduk Yang, Ho-Gi Kim, and Won-Youl Choi. "Effect of a fullerene derivative on the performance of TiO2-nanotube-based dye-sensitized solar cells. J. Nanosci. Nanotechnol. 12(2), Korea, American Scientific Publishers (2012)

    Google Scholar 

  21. Samantaray, Manas R., Abhay Kumar Mondal, Govindhasamy Murugadoss, Sudhagar Pitchaimuthu, Santanu Das, Raihana Bahru, and Mohd Ambri Mohamed. “Synergetic effects of hybrid carbon nanostructured counter electrodes for dye-sensitized solar cells: A review. Materials, 13(12), India, MDPI (2020)

    Google Scholar 

  22. Ding, Shuang, Chaoqiao Yang, Jie Yuan, Huijin Li, Xianli Yuan, Min Li.: An overview of the preparation and application of counter electrodes for DSSCs. RSC advances 13(18), China, RSC Publishing (2023)

    Google Scholar 

  23. Karim, Nayab Abdul, Umer Mehmood, Hafiza Fizza Zahid, Tahira Asif. Nanostructured photoanode and counter electrode materials for efficient Dye-Sensitized Solar Cells (DSSCs). Sol. Energy 185, Pakistan, Elsevier Ltd. (2019)

    Google Scholar 

  24. Zhang, Shihan, Jingsha Jin, Dan Li, Zhiqiang Fu, Shufang Gao, Shubo Cheng, Xiangxiang Yu, Yan Xiong.: Increased power conversion efficiency of dye-sensitized solar cells with counter electrodes based on carbon materials. RSC advances, 9(38), PR China, RSC Publishing (2019)

    Google Scholar 

  25. Cao, Xiaoyu, Qingyu Shen, Yefei Zhuang, Guoce Zhuang, Xiaobo Chen.: Atmospheric plasma reaction synthesised PtxFe1−x/graphene and TiO2 nanoparticles/graphene for efficient dye-sensitized solar cells. RSC advances, 11(12), PR China, RSC Publishing (2021)

    Google Scholar 

  26. Theerthagiri, Jayaraman, Arumugam Raja Senthil, Jagannathan Madhavan, Thandavarayan Maiyalagan.: Recent progress in non‐platinum counter electrode materials for dye‐sensitized solar cells. Chem. Electro. Chem , 2(7), India, Chemistry Europe (2015)

    Google Scholar 

  27. Rafique, Shaista, Imran Rashid, Rehana Sharif.: Cost effective dye sensitized solar cell based on novel Cu polypyrrole multiwall carbon nanotubes nanocomposites counter electrode. Scientific Reports, 11(1), Pakistan, Springer Nature (2021)

    Google Scholar 

  28. Wu, Jihuai, Zhang Lan, Jianming Lin, Miaoliang Huang, Yunfang Huang, Leqing Fan, Genggeng Luo, Yu Lin, Yimin Xie, Yuelin Wei. Counter electrodes in dye-sensitized solar cells. Chem. Soc. Rev. 46(19), China, RSC Publishing (2017)

    Google Scholar 

  29. Chen, Ming, Leng-Leng Shao. Review on the recent progress of carbon counter electrodes for dye-sensitized solar cells. Chem. Eng. J. 304, China, Elsevier Ltd. (2016)

    Google Scholar 

  30. Chen, Xin, Jing Liu, Kun Qian, and Jihui Wang.: Ternary composites of Ni–polyaniline–graphene as counter electrodes for dye-sensitized solar cells. RSC advances, 8(20), China, RSC Publishing (2018)

    Google Scholar 

  31. Saranya, K., Md Rameez, and A. Subramania.: Developments in conducting polymer based counter electrodes for dye-sensitized solar cells–An overview. Eur. Polym. J. 66, India, Elsevier Ltd. (2015)

    Google Scholar 

  32. Ahmad, Iftikhar, Joseph E. McCarthy, Mazhar Bari, and Yurii K. Gun’ko. “Carbon nanomaterial based counter electrodes for dye sensitized solar cells.” Sol. Energy 102, Ireland, Elsevier Ltd. (2014)

    Google Scholar 

  33. Shahzad, Nadia, Tahira Perveen, Diego Pugliese, Sirajul Haq, Nusrat Fatima, Syed Muhammad Salman, Alberto Tagliaferro, and Muhammad Imran Shahzad.: Counter electrode materials based on carbon nanotubes for dye-sensitized solar cells. Renew. Sustain. Energy Rev. 159, Pakistan, Elsevier Ltd. (2022)

    Google Scholar 

  34. Thomas, Sara, Deepak, T.G., Anjusree, G.S., Arun, T.A., Shantikumar Nair, V., Sreekumaran Nair, A.: A review on counter electrode materials in dye-sensitized solar cells. J. Mater. Chem. A 2, 13, India, RSC Publishing (2014)

    Google Scholar 

  35. Gnanasekar, Subashini, Pratap Kollu, Soon Kwan Jeong, Andrews Nirmala Grace.: Pt-free, low-cost and efficient counter electrode with carbon wrapped VO2 (M) nanofiber for dye-sensitized solar cells. Sci. Rep. 9(1), India, Springer Nature (2019)

    Google Scholar 

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Acknowledgements

KVR acknowledges the fellowship from Amrita Vishwa Vidyapeetham and the authors are indebted to the institute for the support.

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Correspondence to Dhamodaran Santhanagopalan .

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Ramanathan, K.V., Chary, V.V., Nair, S.V., Santhanagopalan, D. (2024). Nanocomposites of Carbon for Dye-Sensitized Solar Cell Applications. In: Gupta, R.K. (eds) NanoCarbon: A Wonder Material for Energy Applications. Engineering Materials. Springer, Singapore. https://doi.org/10.1007/978-981-99-9935-4_8

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