Skip to main content
SpringerLink
Log in

Temperature-dependent physicochemical studies of some glycols in aqueous d-mannitol solution

  • Original Paper
  • Published:
Chemical Papers Aims and scope Submit manuscript

Abstract

The interlinkage of ethylene glycol, diethylene glycol and triethylene glycol with d-mannitol at different values of temperature has been analysed by the combination of volumetric and acoustic process. Different values of speed of sound and the density of EG, DEG and TEG in the molalities of (0.01, 0.03 and 0.05) mol kg−1 in aqueous solutions of d-mannitol at T = (293.15, 298.15, 303.15 and 308.15) K have been considered. From the values of speed of sound, the partial molar isentropic compression (Kϕ,s) and the partial molar isentropic compression of transfer \((\Delta {\rm K}_{{\phi ,{\text{s}}}}^{0}\)), have been determined. The pair and triplet interaction coefficient have also been estimated. From the density data, the apparent molar volume \((V_{\phi }^{0}\)) and standard partial molar volume of transfer \((\Delta V_{\phi }^{0} )\) for EG, DEG and TEG in aqueous d-mannitol solutions have been examined. Using the values of partial molar volume and partial molar isentropic compression of transfer, the pair and triplet coefficients are determined. These noteworthy parameters are helpful to examine the interactions between sugar alcohol + glycols + water solutions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

Abbreviations

EG:

Ethylene glycol

DEG:

Diethylene glycol

TEG:

Triethylene glycol

DSA:

Density and sound analyzer

References

  • Aminabhavi TM, Gopalakrishna B (1995) Density, viscosity, refractive-index, and speed of sound in aqueous mixtures of N,N-dimethylformamide, dimethyl-sulfoxide, N,N-dimethylacetamide, acetonitrile, ethylene-glycol, diethylene glycol, 1, 4-dioxane, tetrahydrofuran, 2-methoxyethanol, and 2-ethoxyethanol at 298.15 K. J Chem Eng Data 40:856–861. https://doi.org/10.1021/je00020a026

    Article  CAS  Google Scholar 

  • Banipal PK, Arti S, Banipal TS (2015) Influence of NH4Br on solvation behavior of polyhydroxy solutes in aqueous solutions at different temperatures and atmospheric pressure. J Chem Thermodyn 60:1023–1047. https://doi.org/10.1021/je500886a

    Article  CAS  Google Scholar 

  • Barr DB, Barr JR, Weerasekera G, Wamsley J, Kalb SR, Sjödin A, Needham LL (2007) Identification and quantification of diethylene glycol in pharmaceuticals implicated in poisoning epidemics: an historical laboratory perspective. J Anal Toxicol. https://doi.org/10.1093/jat/31.6.295

    Article  PubMed  Google Scholar 

  • Chakraborty N, Kumar H, Kaur K, Juglan KC (2018) Acoustic and thermodynamic study of D-panthenol in aqueous solutions of glycol at different temperatures. J Chem Thermodyn 126:137–146. https://doi.org/10.1016/j.jct.2018.07.006

    Article  CAS  Google Scholar 

  • Chakraborty N, Kumar H, Kaur K, Juglan KC (2020) Volumetric and ultrasonic studies on interactions of glycol in aqueous solutions of xylitol at different temperatures. J Chem Eng Data 65:1435–1446. https://doi.org/10.1021/acs.jced.9b00869

    Article  CAS  Google Scholar 

  • Deakyne CA (1986) (1986) Filling of solvent shells about ions. 2. Isomeric clusters of (H2O)n(NH3)H+. J Phys Chem 90(25):6625–6632. https://doi.org/10.1021/j100283a007

    Article  CAS  Google Scholar 

  • Franks F, Pedley M, Reid DS (1976) Solute interactions in dilute aqueous solutions. Microcalorimetric study of the hydrophobic interaction. J Chem Soc Faraday Trans 1:359–367. https://doi.org/10.1039/F19767200359

    Article  Google Scholar 

  • Hilal R, Aziz SG (2018) Solvent-assisted excited state proton transfer and photoacidity of 2-hydroxypyridine. A nonadiabatic dynamics study. Mol Simul. https://doi.org/10.1080/08927022.2018.1547821

    Article  Google Scholar 

  • Kaur K, Juglan KC (2016) Ultrasonic velocity, density and viscosity studies of the binary mixtures of ethyl acetate and hexane. J Chem Pharm Res 8:49–53

    CAS  Google Scholar 

  • Kaur K, Juglan KC, Kumar H (2004) Acoustical and volumetric investigation of polyethylene glycol 400 and polyethylene glycol 4000 in aqueous solutions of glycerol at different temperatures. J Chem Thermodyn 127:8–16. https://doi.org/10.1016/j.jct.2018.07.015

    Article  CAS  Google Scholar 

  • Kaur K, Juglan KC, Kumar H (2017) Investigation on temperature-dependent volumetric and acoustical properties of homologous series of glycols in aqueous sorbitol solutions. J Chem Eng Data 62:3769–3782. https://doi.org/10.1021/acs.jced.7b00501

    Article  CAS  Google Scholar 

  • Kaur K, Juglan KC, Kumar H, Behal I (2018) Thermodynamic interactions study of some ethylene glycols in aqueous aniline solutions at different temperatures: an acoustical and volumetric approach. J Chem Eng Data 63:3237–3251. https://doi.org/10.1021/acs.jced.8b00058

    Article  CAS  Google Scholar 

  • Kaur K, Juglan KC, Kumar H (2018) Temperature dependent physicochemical studies of polyethylene glycols (PEG-400 and PEG-4000) in aqueous sorbitol solutions. J Mol Liq 268:700–706. https://doi.org/10.1016/j.molliq.2018.07.101

    Article  CAS  Google Scholar 

  • Kaur K, Behal I, Juglan KC, Kumar H (2018) Volumetric and ultrasonic studies on interactions of ethylene glycol, diethylene glycol, triethylene glycol in aqueous solutions of glycerol at temperatures T= (293.15-308.15) K. J Chem Thermodyn 125:93–106. https://doi.org/10.1016/j.jct.2018.05.016

    Article  CAS  Google Scholar 

  • Kaur P, Chakraborty N, Juglan KC, Kumar H (2020) Volumetric and ultrasonic studies of molecular interactions of glycols in aqueous glutaraldehyde solutions at different temperatures. J Mol Liq 315:113763

    Article  CAS  Google Scholar 

  • Krishnan CV, Friedman HL (1972) Enthalpies of alkyl sulfonates in water, heavy water, and water-alcohol mixtures and the interaction of water with methylene groups. J Solution Chem 2:37–51. https://doi.org/10.1007/BF00645870

    Article  Google Scholar 

  • Kumar H, Behal I (2016a) Densities and speeds of sound of antibiotic drug chloramphenicol with L-leucine and glycyl-L-leucine in aqueous medium at T= (288.15−318.15) K: a volumetric, ultrasonic, and UV absorption study. J Chem Eng Data 61:3740–3751. https://doi.org/10.1021/acs.jced.6b00168

    Article  CAS  Google Scholar 

  • Kumar H, Behal I (2016b) Volumetric, ultrasonic and UV absorption studies on interactions of antibiotic drug chloramphenicol with glycine and its dipeptide in aqueous solutions at T = (288.15–318.15) K. J Chem Thermodyn 99:16–29. https://doi.org/10.1021/acs.jced.6b00168

    Article  CAS  Google Scholar 

  • Kumar H, Behal I (2016c) Thermodynamics of (solute + solute) and (solute + solvent) interactions of homologous series of amino acids with thiamine hydrochloride in aqueous medium at T = (305.15, 310.15, 315.15) K: a volumetric and acoustic approach. J Chem Thermodyn 102:48–62 (https://doi.org/10.1016%2Fj.jct.2016.06.026)

    Article  CAS  Google Scholar 

  • Kumar H, Kaur K, Arti S, Singla M (2016) Study of thermodynamic properties of sodium dodecyl sulphate in aqueous solutions of alkoxyalkanols at different temperatures. J Mol Liq 221:526–534 (https://doi.org/10.1016%2Fj.molliq.2016.06.027)

    Article  CAS  Google Scholar 

  • Li XX, Liu YX, Wei XH (2004) Density, viscosity, and surface tension at 293.15 K and liquid−liquid equilibria from 301.15 K to 363.15 K under atmospheric pressure for the binary mixture of diethylene glycol diethyl ether+ water. J Chem Eng Data 49:1043–1045. https://doi.org/10.1021/je500389t

    Article  CAS  Google Scholar 

  • Lomesh SK, Bala M, Kumaar D, Kumar I (2018) Investigation of molecular interactions of the drug Diclofenac sodium salt in water and aqueous sorbitol systems at different temperatures (305.15 K–315.15 K). J Chem Thermodyn. https://doi.org/10.1016/J.MOLLIQ.2018.08.034

    Article  Google Scholar 

  • Mcmillan WG, Mayer JE (1945) The statistical thermodynamics of multicomponent systems. J Chem Phys 13:276–305. https://doi.org/10.1063/1.1724036

    Article  CAS  Google Scholar 

  • Mirheydari SN, Jalali MdB, Golmohamadi B, Shekaari H, Martinez F, Jouyban A (2019) Density, speed of sound and viscosity of diethylene glycol monoethyl ether+ N, N-dimethylformamide (ethanol, water) at T=288.15-318.15 K. J Chem Eng Data 64:1425–1436. https://doi.org/10.1021/acs.jced.8b01012

    Article  CAS  Google Scholar 

  • Nain AKI (2007) Ultrasonic and viscometric study of molecular interactions in binary mixtures of aniline with 1-propanol, 2-propanol, 2-methyl-1-propanol, and 2-methyl-2-propanol at different temperatures. Fluid Ph Equilib 259:218–227. https://doi.org/10.1080/00319100500050426

    Article  CAS  Google Scholar 

  • Pal A, Kumar H, Maan R, Sharma HK (2013) Volumetric and acoustic studies of binary liquid mixtures of dipropylene glycol dimethyl ether with methyl acetate, ethyl acetate and n-butyl acetate in the temperature range T 5 (288.15, 293.15, 298.15, 303.15, and 308.15) K. J Solution Chem 42:1988–2011 (https://doi.org/10.1007%2Fs10953-013-0086-7)

    Article  CAS  Google Scholar 

  • Pauling L (1960) The nature of the chemical bond and the structure of molecules and crystals, by Linus Pauling. Cornell University Press, Ithaca. https://doi.org/10.1002/jps.3030300111

    Book  Google Scholar 

  • Pauling L, Marsh RE (1955) The structure of chlorine hydrate. Proc Natl Acad Sci 38:112–118

    Article  CAS  Google Scholar 

  • Sarkar A, Pandit B, Sinha B (2016) Volumetric and viscometric behaviour of pyridoxine hydrochloride in aqueous tetrabutylammonium hydrogen sulphate solutions at different temperatures. J Chem Thermodyn 103:36–43. https://doi.org/10.1016/j.jct.2016.08.004

    Article  CAS  Google Scholar 

  • Thakur A, Juglan KC, Kumar H, Kaur K (2019) Investigation on molecular interaction of glycols in methanol solutions of methylparaben (methyl 4-hydroxybenzonate) at different temperatures through thermo-acoustical analysis. J Molecular Liquids 288:1–11. https://doi.org/10.1016/j.molliq.2019.111014

    Article  CAS  Google Scholar 

  • Vuksanovic J, Soldatovic D, Radovic I, Višak Z, Kijevcanin M (2019) Thermodynamic characterization of binary mixtures of poly(propylene glycol) 425 with toluene and o-, m- and p-xylenes. J Chem Thermodyn 131:393–403. https://doi.org/10.1016/j.jct.2018.11.020

    Article  CAS  Google Scholar 

Download references

Funding

The authors declare that no funding is received.

Author information

Authors and Affiliations

  1. Department of Physics, Lovely Professional University, Phagwara, Punjab, 144401, India

    Diksha Chawla, Nabaparna Chakraborty & Kailash Chandra Juglan

  2. Department of Chemistry, Dr. B. R. Ambedkar NIT, Jalandhar, Punjab, 144 011, India

    Harsh Kumar

Authors
  1. Diksha Chawla
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Nabaparna Chakraborty
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kailash Chandra Juglan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Harsh Kumar
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Kailash Chandra Juglan or Harsh Kumar.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Human and animal rights

This article does not contain any studies with human participants or animals performed by any of the authors.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 34 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chawla, D., Chakraborty, N., Juglan, K.C. et al. Temperature-dependent physicochemical studies of some glycols in aqueous d-mannitol solution. Chem. Pap. 75, 1497–1506 (2021). https://doi.org/10.1007/s11696-020-01403-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11696-020-01403-y

Keywords

Search

Navigation