Skip to main content
SpringerLink
Log in

Exploration of Phase Equilibria in the Triple Molybdate System, Electrical Properties of New Rb5M1/3Zr5/3(MoO4)6 (M-Ag, Na) Phases

  • Published:
Journal of Phase Equilibria and Diffusion Aims and scope Submit manuscript

Abstract

The formation of Rb5Ag1/3Zr5/3(MoO4)6 compound during the study of Rb2MoO4-Ag2MoO4-Zr(MoO4)2 system by x-ray diffraction technique was established. Its unit cell parameters, phase transition were determined. The dimensions of trigonal unit cell Rb5Ag1/3Zr5/3(MoO4)6 are a = 10.7235 (3), c = 38.548 (1), V = 3838.9 (3). Temperature and frequency dependences of dielectric parameters for Rb5M1/3Zr5/3(MoO4)6 (M-Ag, Na) ceramics were measured by impedance spectroscopy in the temperature and the frequency range 300-773 K and 1 Hz-10 kHz, respectively. The correlation of dielectric and thermal parameters in the high-temperature region near the phase transition was revealed. Arrhenius plots of the conductivity showed anomalies at high temperatures (723-773 K), increasing several orders of magnitude to 10−3 S K/cm.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig 1
Fig 2
Fig 3
Fig 4
Fig 5
Fig 6
Fig 7

Similar content being viewed by others

References

  1. I. Jendoubi, M. Ptak, A. Pikul, J. Chmielowiec, A. Ciupa, M. Maczka, and M.F. Zid, Synthesis, Crystal Structure, Phonon, Magnetic and Electrical Properties of New Molybdate Na2Mn2(MoO4)3, J. Solid State Chem., 2019, 277, p 738–750.

    Article  ADS  Google Scholar 

  2. C. Guzman-Afonso, C. Gonzalez-Silgo, M.E. Torres, N. Sabalisck, A.D. Lozano-Gorrin, J. Gonzalez-Platas, and E. Matesanz, Crystal Structure and Non-linear Properties of A2(MoO4)3 (A = Eu, Gd, Tb, Dy and Ho), Mater. Lett., 2011, 65, p 2731–2734.

    Article  Google Scholar 

  3. C.S. Lim, A.S. Aleksandrovsky, M.S. Molokeev, A.S. Oreshonkov, and V.V. Atuchin, Microwave Synthesis and Spectroscopic Properties of Ternary Scheelite-Type Molybdate Phosphors NaSrLa(MoO4)3:Er3+, Yb3+, J. Alloys Comp., 2017, 713, p 156–163.

    Article  Google Scholar 

  4. D. Mikhailova, A. Sarapulova, A. Voss, A. Thomas, S. Oswald, W. Gruner, D.M. Trots, N.N. Bramnik, and H. Ehrenberg, Li3V(MoO4)3: A New Material for Both Li Extraction and Insertion, Chem. Mater., 2010, 22, p 3165–3173.

    Article  Google Scholar 

  5. S.G. Dorzhieva, D.O. Sofich, B.G. Bazarov, R. Yu Shendrik, and J.G. Bazarova, Optical Properties of Molybdates Containing a Combination of Rare-Earth Elements, Inorg Mater., 2021, 57, p 54–59.

    Article  Google Scholar 

  6. A. Sarapulova, T. Namsaraeva, D. Mikhailova, B. Schwarz, H. Ehrenberg, Z. Bazarova, B. Bazarov, Structure and Magnetic Properties of New Triple Molybdates CsMZr0.5(MoO4)3 (M = Al, Ga, In, Sc, Cr, V, Fe), Acta crystallogr. A, 2010, 66, S191-S191.

  7. D. Sofich, S.G. Dorzhieva, O.D. Chimitova, B.G. Bazarov, Yu.L. Tushinova, and J.G. Bazarova, Luminescence of Pr3+ and Nd3+ Ions in Double Molybdates, Phys. Solid State, 2019, 61, p 943–945.

    Article  Google Scholar 

  8. A.E. Sarapulova, B. Bazarov and T. Namsaraeva et al. Piezoelectric Materials CsMZr0.5(MoO4)3 (M = Al, Sc, V, Cr, Fe, Ga, In) and CsCrTi0.5(MoO4)3: Structure and Physical Properties, J. Phys. Chem. C, 2014, 118, 1763-1773.

  9. S.N. Savvin, A.V. Shlyakhtina, I.V. Kolbanev, A.V. Knotko, D.A. Belov, L.G. Shcherbakova, and P. Nuñez, Zr-Doped Samarium Molybdates—Potential Mixed Electron–Proton Conductors, Solid State Ionics, 2014, 262, p 713–718.

    Article  Google Scholar 

  10. B.G. Bazarov, J.G. Bazarova, Y.L. Tushinova et al., A New Double Molybdate of Erbium and Zirconium, Its Crystalline Structure and Properties, J. Alloys Comp., 2017, 701, p 750–753.

    Article  Google Scholar 

  11. A.A. Savina, S.F. Solodovnikov, D.A. Belov, Z.A. Solodovnikova, S. Yu Stefanovich, B.I. Lazoryak, and E.G. Khaikina, New Alluaudite-Related Triple Molybdates Na25Cs8R5(MoO4)24 (R = Sc, In): Synthesis, Crystal Structures and Properties, New J. Chem., 2017, 41, p 5450–5457.

    Article  Google Scholar 

  12. A.L. Buzlukov, IYu. Arapova, Y.V. Baklanova, N.I. Medvedeva, T.A. Denisova, A.A. Savina, B.I. Lazoryak, E.G. Khaikina, and M. Bardet, Coexistence of Three Types of Sodium Motion in Double Molybdate Na9Sc(MoO4)6: 23Na and 45Sc NMR Data and ab Initio Calculations, Phys. Chem. Chem. Phys., 2020, 22, p 144–154.

    Article  Google Scholar 

  13. S.G. Dorzhieva, B.G. Bazarov, A.A. Bush, K.E. Kamentsev, J.G. Bazarova Preparation, Dielectric and Thermal Characteristics of a New Series Cs-R-Ti-Molybdates (R-Al, Fe, Ga, Sc, In), Solid State Commun., 2015, 217, 25-27.

  14. J.G. Bazarova, A.V. Logvinova, B.G. Bazarov, Y.L. Tushinova, S.G. Dorzhieva, and J. Temuujin, Synthesis of New Triple Molybdates K5RZr(MoO4)6 (R = Al, Cr, Fe, In, Sc) in the K2MoO4-R2(MoO4)3-Zr(MoO4)2 Systems, Their Structure and Electrical Properties, J. Alloy. Comp., 2018, 741, p 834–839.

    Article  Google Scholar 

  15. V.G. Grossman, J.G. Bazarova, M.S. Molokeev, B.G. Bazarov, New Triple Molybdate K5ScHf(MoO4)6: Synthesis, Properties, Structure and Phase Equilibria in the M2MoO4-Sc2(MoO4)3-Hf(MoO4)2 (M = Li,K) systems, J. Solid State Chem., 2020, 283, 121143.

  16. S.G. Dorzhieva, B.G. Bazarov, A.K. Subanakov, J.G. Bazarova, Crystal Structure Modeling, Electrical and Thermal Characterization of Triple Molybdates RbCrTi0.5(MoO4)3 (R = Fe, Cr), J. Solid State Chem., 2013, 199, 21-26.

  17. T.S. Spiridonova, S.F. Solodovnikov, A.A. Savina, Y.M. Kadyrova, Z.A. Solodovnikova, V.N. Yudin, S.Y. Stefanovich, and E.G. Khaikina, New Triple Molybdate Rb2AgIn(MoO4)3: Synthesis, Framework Crystal Structure and Ion-Transport Behavior, Acta Crystallogr. C, 2018, 74, p 1603–1609.

    Article  Google Scholar 

  18. N.I. Sorokin, Ionic Conductivity of KMgCr(MoO4)3 Molybdate, Crystallogr. Rep., 2017, 62(3), p 416–418.

    Article  ADS  Google Scholar 

  19. Bruker AXS TOPAS V4, General Profile and Structure Analysis Software for Powder Diffraction Data.—User’s Manual, Bruker AXS, Karlsruhe, Germany, 2008.

  20. L. Niepel and M. Malinovsky, Triangulation of Phase Diagrams, Chem. Zvesti, 1978, 32, p 810–820.

    Google Scholar 

  21. M.V. Mokhosoev and J.G. Bazarova, Complex Oxides of Molybdenum and Tungsten with I-IV Groups Elements. Moscow, Science, 1990, 256 p. (in Russian).

  22. P.V. Klevtsov, E.S. Zolotova, L.A. Glinskaya and R.F. Klevtsova Synthesis, Thermal Stability, and Crystal Structure of Double Rubidium Molybdates with Zirconium and Hafnium. Russ. J. Inorg. Chem., 1980, 25, 1844-1850 (in Russian).

  23. E.S. Zolotova, Abstract of the Dissertation... Candidate of Chemical Sciences, Novosibirsk, 1986, 25 p (in Russian).

  24. E.T. Khobrakova, Abstract of the Dissertation... Candidate of Chemical Sciences, Moscow, 2004, 25 p (in Russian).

  25. Yu.M. Kadyrova, S.F. Solodovnikov, Z.A. Solodovnikova, O.M. Basovich, T.S. Spiridonova, and E.G. Khaikina, New Double Silver–Rubidium Molybdate, Vestnik Buryat State Univ., 2015, 3, p 21–25. , (in Russian)

    Google Scholar 

  26. S.F. Solodovnikov, L.V. Balsanova, B.G. Bazarov et al., Phase Formation in the Rb2MoO4-Li2MoO4-Hf(MoO4)2 System and the Crystal Structure of Rb5(Li1/3Hf5/3)(MoO4)6, Russ. J. Inorg. Chem., 2003, 48, p 1084–1088.

    Google Scholar 

  27. S.G. Dorzhieva, B.G. Bazarov, and J.G. Bazarova, New Molybdates in the Rb2MoO4–MI2MoO4–Zr(MoO4)2 (MI – Na, K) Systems, as a Basis for Obtaining Promising Ion-Conducting Materials, Lett. Mater., 2019, 9, p 17–21.

    Article  Google Scholar 

Download references

Acknowledgment

This study was carried out within the state assignment of Baikal Institute of Nature Management SB RAS (№ 0273-2021-0008).

Author information

Authors and Affiliations

  1. Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences (BINM SB RAS), Sakhyanovoy St., 6, Ulan-Ude 670047, Buryat Republic, Russia

    Sesegma G. Dorzhieva, Jibzema G. Bazarova & Bair G. Bazarov

Authors
  1. Sesegma G. Dorzhieva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jibzema G. Bazarova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Bair G. Bazarov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Sesegma G. Dorzhieva.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dorzhieva, S.G., Bazarova, J.G. & Bazarov, B.G. Exploration of Phase Equilibria in the Triple Molybdate System, Electrical Properties of New Rb5M1/3Zr5/3(MoO4)6 (M-Ag, Na) Phases. J. Phase Equilib. Diffus. 42, 824–830 (2021). https://doi.org/10.1007/s11669-021-00927-4

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11669-021-00927-4

Keywords

Search

Navigation