Skip to main content
SpringerLink
Log in

Bi13-xMexMo5O34±δ (Me = Mg, Ca, Sr, Ba) solid solutions: synthesis and properties

  • Original Paper
  • Published:
Ionics Aims and scope Submit manuscript

Abstract

A series of complex oxides Bi13-xMexMo5O34±δ, Me = Mg, Ca, Sr, Ba were synthesized and studied. The solid solutions ranges and polymorphic modifications limits were determined. High temperature X-ray powder diffraction measurements showed the deviation of unit cell parameters dependence versus temperature from the linear function. Processes of forming of ceramic samples based on the synthesized powders were analyzed, and dense ceramic samples were obtained. Impedance spectroscopy displayed the changes of slope of Arrhenius plots which correspond with the HT-XPRD measurements. The presence of two different forms of monoclinic modification was supposed. The studied materials are promising ionic conductors, with the highest conductivity values about 6 × 10−3 S cm−1 at 973 K and 1.4 × 10−4 S cm−1 at 623 K.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. Boivin J-C (2001) Structural and electrochemical features of fast oxide ion conductors. Int J Inorg Mat 3:1261–1266. doi:10.1016/s1466-6049(01)00118-0

    Article  CAS  Google Scholar 

  2. Grasselli RKJ (1986) Selective oxidation and ammoxidation of olefins by heterogeneous catalysis. Chem Educ 63:216–221. doi:10.1021/ed063p216

    Article  CAS  Google Scholar 

  3. Keulks GW, Krenzke LD, Notermann TM (1979) Selective oxidation of propylene. Adv Catal 27:183–225. doi:10.1016/s0360-0564(08)60056-5

    Google Scholar 

  4. Libre JM, Barbaux Y, Grzybowska B, Gonflant P, Bonnelle JP (1983) Catalytic oxidation of propene: surface potential measurements and structural properties of α-Bi2Mo3O12, α-Bi2O3 and MoO3. Appl Catal 6:315–328. doi:10.1016/0166-9834(83)80104-3

    Article  CAS  Google Scholar 

  5. Egashira M, Matsuo K, Kagawa S, Seiyama T (1979) Phase diagram of the system Bi2O3 - MoO3. J Catalysis 58:409–418. doi:10.1016/0021-9517(79)90279-3

    Article  CAS  Google Scholar 

  6. Erman LY, Galperin EL, Kolchin IK (1964) The Bi2O3-MoO3-System. Russian J Inor Chem 9:1174–1176

    Google Scholar 

  7. Ono T, Utsumi K, Tsukamoto S, Tamaru H, Kataoka M, Noguchi F (2010) Roles of bulk γ(L)-Bi2MoO6 and surface β-Bi2Mo2O9 in the selective catalytic oxidation of C3H6. J Mol Catal A: Chemical 318:94–100. doi:10.1016/j.molcata.2009.11.012

    Article  CAS  Google Scholar 

  8. Snyder TP, Hill CG (1991) Stability of bismuth molybdate catalysts at elevated temperatures in air and under reaction conditions. J Catalysis 132:536–555. doi:10.1016/0021-9517(91)90169-5

    Article  CAS  Google Scholar 

  9. Crumpton TE, Francesconi MG, Greaves C (2003) The structural chemistry of Bi14 MO24 (M = Cr, Mo, W) phases: bismuth oxides containing discrete MO4 tetrahedra. J Solid State Chem 177:197–206. doi:10.1016/s0022-4596(03)00246-9

    Article  Google Scholar 

  10. Sharma N, Macquart RB, Christensen M, Avdeev M, Chen YS, Ling CD (2009) Structure and crystal chemistry of fluorite-related Bi38Mo7O78 from single crystal X-ray diffraction and ab initio calculations. J Solid State Chem 182:1312–1318. doi:10.1016/j.jssc.2009.02.030

    Article  CAS  Google Scholar 

  11. Valldor M, Esmaeilzadeh S, Pay-Gomez C, Grins J (2000) A new high-temperature cubic fluorite-type phase Mo0.16Bi0.84O1.74 with a rare three-dimensional incommensurate modulation. J Solid State Chem 152:573–576. doi:10.1006/jssc.2000.8742

    Article  CAS  Google Scholar 

  12. Vila E, Landa-Canovas RA, Galy J, Iglesias JE, Castro A (2007) Bi2n+4MonO6(n+1) with n = 3, 4, 5, 6: A new series of low-temperature stable phases in the mBi2O3– MoO3 system (1.0 ≤ m ≤ 1.7): Structural relationships and conductor properties. J Solid State Chem 180:661–669. doi:10.1016/j.jssc.2006.10.036

    Article  CAS  Google Scholar 

  13. Buttrey DJ, Vogt T, Yap GPA, Rheingold AL (1997) The structure of Bi26Mo10O69. Mater Res Bull 32:947–962. doi:10.1016/s0025-5408(97)00063-9

    Article  CAS  Google Scholar 

  14. Vannier RN, Mairesse G, Abraham F, Nowogorski G (1996) Bi26Mo10Oδ solid solution type in the Bi2O3–MoO3–V2O5 ternary diagram. J Solid State Chem 122:394–406. doi:10.1006/jssc.1996.0133

    Article  CAS  Google Scholar 

  15. Ling CD, Miiller W, Johnson MR, Richard D, Rols S, Madge J, Evans IR (2012) Local structure, dynamics, and the mechanisms of oxide ionic conduction in Bi26Mo10O69. Chem Mater 24:4607–4614. doi:10.1021/cm303202r

    Article  CAS  Google Scholar 

  16. Ayame A, Uchida K, Iwataya M, Miyamoto M (2002) X-ray photoelectron spectroscopic study on α- and γ-bismuth molybdate surfaces exposed to hydrogen, propene and oxygen. Appl Catal A: General 227:7–17. doi:10.1016/s0926-860x(01)00918-8

    Article  CAS  Google Scholar 

  17. Uchida K, Ayame (1996) A dynamic XPS measurements on bismuth molybdate surfaces. Surf Sci 357-358:170-175. doi: 0.1016/0039-6028(96)00083-0

  18. Holmes L, Peng L, Heinma I, O’Dell LA, Smith ME, Vannier RN, Grey CP (2008) Variable-temperature 17O NMR study of oxygen motion in the anionic conductor Bi26Mo10O69. Chem Mater 20:3638–3648. doi:10.1021/cm800351c

    Article  CAS  Google Scholar 

  19. Muktha B, Aarthi T, Madras G, Guru Row TN (2006) Substitution effect on the photocatalytic degradation by the series AxBi26-xMo10O68-0.5y (A = Ba, y = 0; A = Bi, La, y = 2): a kinetic study. J Phys Chem B 110:10280–10286. doi:10.1021/jp060945o

    Article  CAS  Google Scholar 

  20. Galy J, Enjalbert R, Rozier P, Millet P (2003) Lone pair stereoactivity versus anionic conductivity. Columnar structures in the Bi2O3–MoO3 system. Solid State Sci 5:165–174. doi:10.1016/s1293-2558(02)00090-0

    Article  CAS  Google Scholar 

  21. Enjalbert R, Hasselmann G, Galy J (1997) A New Mixed Oxide with (Bi12O14)n Columns: PbBi12Mo5O34. Acta Crystallgr C 53:269–272. doi:10.1107/s0108270196013698

    Article  Google Scholar 

  22. Vannier RN, Danze S, Nowogrocki G, Huve M, Mairesse G (2000) A new class of mono-dimensional bismuth-based oxide anion conductors with a structure based on [Bi12O14]∞ columns. Solid State Ionics 136–137:51–59. doi:10.1016/S0167-2738(00)00351-9

    Article  Google Scholar 

  23. Galy J, Salles P, Rozier P, Castro A (2006) Anionic conductors Ln2/3[Bi12O14](MoO4)5 with Ln = La, Nd, Gd, Ho, Yb. Synthesis–spark plasma sintering–structure–electric properties. Solid State Ionics 177:2897–2902. doi:10.1016/j.ssi.2006.07.059

    Article  CAS  Google Scholar 

  24. Bastide B, Enjalbert R, Salles P, Galy J (2003) Ionic conductivity of the oxide family Bi[Bi12O14][(Mo, M)O4]5 with M = Li, Mg, Al, Si, Ge and V. Solid State Ionics 158:351–358. doi:10.1016/s0167-2738(02)00910-4

    Article  CAS  Google Scholar 

  25. Mikhailovskaya ZA, Buyanova ES, Petrova SA, Morozova MV, Zhukovskiy VM, Zakharov RG, Tarakina NV, Berger IF (2013) Cobalt-doped Bi26Mo10O69: crystal structure and conductivity. J Solid State Chem 204:9–15. doi:10.1016/j.jssc.2013.05.006

    Article  CAS  Google Scholar 

  26. Shannon RD (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta cryst A 32:751–767. doi:10.1107/s0567739476001551

    Article  Google Scholar 

  27. Irvine JTS, Sinclair DC, West AR (1990) Electroceramics: characterization by impedance spectroscopy. Adv Mater 2:132–138. doi:10.1002/adma.19900020304

    Article  CAS  Google Scholar 

  28. Abrahams I, Krok F (2002) Defect chemistry of the BIMEVOXes. J Mater Chem 12:3351–3362. doi:10.1039/B203992N

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the Russian Fund of Basic Research (project nos. 12-03-00464 and 14-03-92605)

Author information

Authors and Affiliations

  1. Ural Federal University, Lenin Ave. 51, 620000, Ekaterinburg, Russia

    Z. A. Mikhaylovskaya, E. S. Buyanova & M. V. Morozova

  2. Institute for Metallurgy, Ural Branch of the Russian Academy of Sciences, 101 Amundsen Str., 620016, Ekaterinburg, Russia

    S. A. Petrova & R. G. Zakharov

  3. Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomayskaya Str., 620990, Ekaterinburg, Russia

    I. V. Nikolaenko

  4. Materials Research Institute, School of Biological and Chemical Sciences, Queen Mary University of London, Mile End Road, London, E1 4NS, UK

    I. Abrahams

Authors
  1. Z. A. Mikhaylovskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. S. Buyanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. V. Morozova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. A. Petrova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. R. G. Zakharov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. V. Nikolaenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. I. Abrahams
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Z. A. Mikhaylovskaya.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mikhaylovskaya, Z.A., Buyanova, E.S., Morozova, M.V. et al. Bi13-xMexMo5O34±δ (Me = Mg, Ca, Sr, Ba) solid solutions: synthesis and properties. Ionics 21, 2259–2268 (2015). https://doi.org/10.1007/s11581-015-1421-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11581-015-1421-3

Keywords

Search

Navigation