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The Ce-Ni phase diagram in [Massalski2] was adopted from [1991Nas]. [2005Oka] updated this phase diagram according to the thermodynamic evaluation by [2004Du]. Six intermetallic phases existing in this system were treated as line compounds.
[2007Xio] noticed that the CeNi5 phase has a measurable homogeneity range according to [1994Kim]. [2007Xio] confirmed this observation experimentally and calculated the Ce-Ni phase diagram, as shown in Fig. 1. (The range below 200 °C was added by this evaluator.)
Ce-Ni phase diagram
Earlier, [2004Pal] also calculated the Ce-Ni phase diagram, but the CeNi5 phase was treated as a line compound.
References
P. Nash and C.H. Tung, Ce-Ni (Cerium-Nickel), Phase Diagrams of Binary Nickel Alloys, P. Nash, Ed., ASM International, 1991, p 62-67
D.Y. Kim, M. Ohtsuka, and K. Itagaki, Shigen-to-Sozai, 1994, 110, p 95-101, as quoted in [2007Xio]
Z. Du. L. Yang, and G. Ling, Thermodynamic Assessment of the Ce-Ni System. J. Alloys Compd. 375, 186-190 (2004)
M. Palumbo, G. Borzone, S. Delsante, N. Parodi, G. Cacciamani, R. Ferro, L. Battezzati, and M. Baricco, Thermodynamic Analysis and Assessment of the Ce-Ni System. Intermetallics 12, 1367-1372 (2004)
H. Okamoto, Ce-Ni (Cerium-Nickel), J. Phase Equilib. Diffus., 2005, 397
W. Xiong, Y. Du, X. Lu, J.C. Schuster, and H. Chen, Reassessment of the Ce-Ni Binary System Supported by Key Experiments and Ab Initio Calculations. Intermetallics 15, 1401-1408 (2007)
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Okamoto, H. Ce-Ni (Cerium-Nickel). J. Phase Equilib. Diffus. 30, 407 (2009). https://doi.org/10.1007/s11669-009-9544-8
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DOI: https://doi.org/10.1007/s11669-009-9544-8