Skip to main content
Log in

Failure Analysis of Yellowness Issue in Automotive Headlamp and its Remedies

  • Technical Article---Peer-Reviewed
  • Published:
Journal of Failure Analysis and Prevention Aims and scope Submit manuscript

Abstract

Automotive headlamps, constructed using different components are likely affected by haziness, dirtiness, fogginess, cloudiness, or white patches caused by oxidation, chemical attack, water vapors, flying debris, and dirt. In the present work, we have identified the root causes of outer lens yellowness issue in a headlamp and provided possible remedies. For this attempt, two headlamps were analyzed for the yellowness root cause analysis and their failure prevention. Several parts of the headlamp assembly, such as outer lens, dust caps and housing assembly, were characterized for the thermal, structural, and morphological analysis. Yellowness is mostly caused by the liberation of lower temperature volatile organic compounds due to thermal decomposition and oxidation of lower molecular weight additives present in the polymers. Thermal properties of clear transparent headlamp parts (OK) and yellow colored headlamp parts (NOT-OK) were analyzed using differential scanning calorimetry, thermogravimetric analysis. The chemical structure similarity of the NOT-OK and OK headlamps parts was characterized by the fourier transform infrared spectroscopy analysis. The liberation of lower temperature volatile organic components and their deposition onto the inside layer of the outer lens resulted in the yellowness issue in the headlamp. The headlamp component that contributed to the liberation of lower temperature volatile organic components was identified and remedies have been implemented for the failure prevention in future headlamp parts.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. J.A. Sanguesa, V. Torres-Sanz, P. Garrido, F.J. Martinez, J.M. Marquez-Barja, A review on electric vehicles: technologies and challenges. Smart Cities. 4(1), 372–404 (2021)

    Article  Google Scholar 

  2. Y. Miao, P. Hynan, A. Von Jouanne, A. Yokochi, Current li-ion battery technologies in electric vehicles and opportunities for advancements. Energies. 12(6), 1074 (2019)

    Article  CAS  Google Scholar 

  3. S.A.Q. Mohammed, J.W. Jung, A comprehensive state-of-the-art review of wired/wireless charging technologies for battery electric vehicles: classification/common topologies/future research issues. IEEE Access. 9, 19572–19585 (2021)

    Article  Google Scholar 

  4. D.W. Eby, L.J. Molnar, L. Zhang, R.MSt. Louis, N. Zanier, L.P. Kostyniuk, S. Stanciu, Use, perceptions, and benefits of automotive technologies among aging drivers. Inj. Epidemiol. 3(1), 28 (2016)

    Article  Google Scholar 

  5. C.D. May, R.J. Watling, The development of analytical and interpretational protocols to facilitate the provenance establishment of polycarbonate headlamp lens material. J. Forensic Sci. 56, s47–s57 (2011)

    Article  Google Scholar 

  6. B.T. Anthony, Lexan polycarbonate for automotive forward lighting. Mater. Des. 6, 293–302 (1985)

    Article  CAS  Google Scholar 

  7. C. Seubert, K. Nietering, M. Nichols, R. Wykoff, S. Bollin, An overview of the scratch resistance of automotive coatings: exterior clearcoats and polycarbonate hardcoats. Coatings. 2(4), 221–234 (2012)

    Article  CAS  Google Scholar 

  8. K.L. Camera, B. Wenning, A. Lal, C.K. Ober, Transient materials from thermally-sensitive polycarbonates and polycarbonate. Polymer (Guildf). 101, 59–66 (2016)

    Article  CAS  Google Scholar 

  9. U. Ali, K.J.B.A. Karim, N.A. Buang, A review of the properties and applications of poly (Methyl Methacrylate) (PMMA). Polym. Rev. 55(4), 678–705 (2015)

    Article  CAS  Google Scholar 

  10. A.M. Omer, Energy use and environmental impacts: a general review. J. Renew. Sustain. Energy. 1, 053101 (2009)

    Article  Google Scholar 

  11. M.E. Nichols, C.A. Peters, The effect of weathering on the fracture energy of hardcoats over polycarbonate. Polym. Degrad. Stab. 75(3), 439–446 (2002)

    Article  CAS  Google Scholar 

  12. C. Yan, J. Zhang, J. Han, X. Wang, Z. Guan, L. Zhang, C. Liu, C. Shen, Improvement of environmental stress cracking resistance of polycarbonate by silicone coating. Polym. Test. 60, 6–11 (2017)

    Article  CAS  Google Scholar 

  13. M.M. Ferreira, V. de Freitas Cunha Lins, Failure in automotive headlight lenses. Eng. Fail. Anal. 104, 844–855 (2019)

    Article  CAS  Google Scholar 

  14. D. Kyriacos, Polycarbonates, in Brydson’s Plastics Materials. (Elsevier, 2017), p. 457–485

    Chapter  Google Scholar 

  15. M.D. Pustode, C.S. Singh, R. Verma, T. Kochi, H. Barge, S. Gouda, A. Dutta, Root cause analysis and mitigation of white patch formation in automotive headlmap. J. Fail. Anal. Prev. 21(2), 387–397 (2021)

    Article  Google Scholar 

  16. T. Schmauder, K.D. Nauenburg, K. Kruse, G. Ickes, Hard coatings by plasma CVD on polycarbonate for automotive and optical applications. Thin Solid Films. 502(1), 270–274 (2006)

    Article  CAS  Google Scholar 

  17. M. Barletta, M. Puopolo, G. Rubino, V. Tagliaferri, S. Vesco, Hard transparent coatings on thermoplastic polycarboate. Prog. Org. Coatings. 90, 178–186 (2016)

    Article  CAS  Google Scholar 

  18. P. Sarkar, A.K. Bhowmick, Sustainable rubbers and rubber additives. J. Appl. Polym. Sci. 135(24), 1–33 (2018)

    Article  Google Scholar 

  19. M.J. Samide, G.D. Smith, J. Chromatogr, Analysis and quantitation of volatile organic compounds emitted from plastics used in museum construction by evolved gas analysis-gas chromatography-mass spectrometry. J. Chromatogr. 1426, 201–208 (2015)

    Article  CAS  Google Scholar 

  20. V. Ambrogi, C. Carfagna, P. Cerruti, V. Marturano, Additives in polymers. Modifications of polymer properties (Elsevier, 2017), p. 87–108

    Book  Google Scholar 

  21. H. Yahyaei, M. Mohseni, S. Bastani, Using Taguchi experimental design to reveal the impact of parameters affecting the abrasion resistance of sol–gel based UV curable nanocomposite films on polycarbonate. J. Sol-Gel Sci. Technol. 59, 95–105 (2011)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors would like to thank Minda-Rinder plant for cooperation throughout the characterization and analysis process. The authors also thankful to the CREAT management team of UNO Minda Limited for the motivation.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Ikhlas Chandkoti or Manoj Mali.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chandkoti, I., Naikwadi, A.T., Mali, M. et al. Failure Analysis of Yellowness Issue in Automotive Headlamp and its Remedies. J Fail. Anal. and Preven. 22, 1590–1603 (2022). https://doi.org/10.1007/s11668-022-01451-4

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11668-022-01451-4

Keywords

Navigation