Abstract
The suitability of certain glass compositions in the Y2O3-Al2O3-SiO2 (YAS) system as protecting coatings for silicon carbide components has been prospected. One particular YAS composition was formulated considering its glass formation ability and subsequent crystallization during service. Round-shaped and homogeneous granules of the selected composition were prepared by spray drying the corresponding homogeneous oxide powder mixture. Glassy coatings (197 µm thick) were obtained by oxyacetylene flame spraying the YAS granules over SiC substrates, previously grit blasted and coated with a Si bond layer (56 µm thick). Bulk glass of the same composition was produced by the conventional glass casting method and used as reference material for comparative evaluation of the characteristic glass transition temperatures, crystallization behavior, mechanical, and thermal coating properties. The mechanical properties and thermal conductivity of the coating were lower than those of the bulk glass owing to its lower density, higher porosity, and characteristic lamellar structure. The crystallization of both bulk glass and coating occurred during isothermal treatments in air at 1100-1350 °C. Preliminary data on ablation tests at 900 °C using the oxyacetylene gun indicated that the YAS glassy coating was a viable protective shield for the SiC substrate during 150 s.
Similar content being viewed by others
References
B. Behrens and M. Muller, Technologies for Thermal Protection Systems Applied on Re-usable Launcher, Acta Astronaut., 2004, 55, p 529-536
L. Weiming and D.D.L. Chung, Oxidation Protection of Carbon Materials by Acid Phosphate Impregnation, Carbon, 2002, 40, p 1249-1254
Y.-C. Zhu, S. Ohtani, Y. Sato, and N. Iwamoto, The Improvement in Oxidation Resistance of CVD-SiC Coated C/C Composites by Silicon Infiltration Pretreatment, Carbon, 1998, 36, p 929-935
Y.-C. Zhu, S. Ohtani, Y. Sato, and N. Iwamoto, Influence of Boron Ion Implantation on the Oxidation Behavior of CVD-SiC Coated Carbon-Carbon Composites, Carbon, 2000, 38, p 501-507
F. Smeacetto, M. Ferraris, and M. Salvo, Multilayer Coating with Self-sealing Properties for Carbon-Carbon Composites, Carbon, 2003, 41, p 2105-2111
F. Smeacetto, M. Ferraris, M. Salvo, S.D. Ellacott, A. Ahmed, R.D. Rawlings, and A.R. Boccaccini, Protective Coatings for Carbon Bonded Carbon Fibre Composites, Ceram. Int., 2008, 34, p 1297-1301
M. Guo, K. Shen, and Y. Zheng, Multilayered Coatings for Protecting Carbon-Carbon Composites from Oxidation, Carbon, 1995, 33, p 449-453
M. Aparicio and A. Durán, Yttrium Silicate Coatings for Oxidation Protection of Carbon-Cilicon Carbide Composites, J. Am. Ceram. Soc., 2000, 83, p 1351-1355
Y. Liu, L. Zhang, L. Cheng, W. Yang, W. Zhang, and Y. Xu, Preparation and Oxidation Protection of CVD SiC/a-BC/SiC Coatings for 3D C/SiC Composites, Corros. Sci., 2009, 51, p 820-826
K.N. Lee, D.S. Fox, and N.P. Bansal, Rare Earth Silicate Environmental Barrier Coatings for SiC/SiC Composites and Si3N4 Ceramics, J. Eur. Ceram. Soc., 2005, 25, p 1705-1715
K.N. Lee, D.S. Fox, J.I. Eldridge, D. Zhu, R.C. Robinson, N.P. Bansal, and R.A. Miller, Upper Temperature Limit of Environmental Barrier Coatings Based on Mullite and BSAS, J. Am. Ceram. Soc., 2003, 86, p 1299-1306
C.V. Cojocaru, D. Lévesque, C. Moreau, and R.S. Lima, Performance of Thermally Sprayed Si/Mullite/BSAS Environmental Barrier Coatings Exposed to Thermal Cycling in Water Vapor Environment, Surf. Coat. Technol., 2013, 216, p 215-223
J. Mesquita-Guimarães, E. Garcia, P. Miranzo, M.I. Osendi, C.V. Cojocaru, and R.S. Lima, Mullite-YSZ Multilayered Environmental Barrier Coatings Tested in Cycling Conditions Under Water Vapor Atmosphere, Surf. Coat. Technol., 2012, 209, p 103-109
M.A. Sainz, M.I. Osendi, and P. Miranzo, Protective Si-Al-O-Y Glass Coatings on Stainless Steel in Situ Prepared by Combustion Flame Spraying, Surf. Coat. Technol., 2008, 202, p 1712-1717
L. Wu, G. Liu, J. Li, B. He, Z. Yang, and Y. Chen, Dependence of Glass-Forming Ability on Starting Compositions in Y2O3-Al2O3-SiO2 System, Ceram. Silik, 2011, 55, p 228-231
H. Mao, M. Selleby, and O. Fabrichnaya, Thermodynamic Reassessment of the Y2O3-Al2O3-SiO2 System and its Subsystems, CALPAHD, 2008, 32, p 399-412
U. Kolitsch, H.J. Seifert, T. Ludwig, and F. Aldinger, Phase Equilbria and Crystal Chemistry in the Y2O3-Al2O3-SiO2 System, J. Mater. Res., 1999, 14(2), p 447-455
M.J. Hyatt and D.E. Day, Glass Properties in the Yttria-Aluminas-Silica System, J. Am. Ceram. Soc., 1987, 70, p C283-C287
J.E. Shelby, S.M. Minton, C.E. Lord, and M.R. Tuzzolo, Formation and Properties of Yttrium Aluminosilicate Glasses, Phys. Chem. Glasses, 1992, 33, p 93-98
K. Morita, A. Umezawa, S. Yamato, and A. Makishima, Surface-Roughness of Yttria-Containing Aluminosilicate Glass-Ceramics as Indicative of Their Machinability, J. Am. Ceram. Soc., 1993, 76, p 1861-1864
E. Garcia, P. Miranzo, and M.I. Osendi, The Prospect of Y2SiO5-Based Materials as Protective Layer in Environmental Barrier Coatings, J. Therm. Spray Technol., 2013, 22, p 680-689
H.L. Schick, A Thermodynamic Analysis of the High-Temperature Vaporization Properties of Silica, Chem. Rev., 1960, 60, p 331-362
E. García, J. Mesquita-Guimarães, P. Miranzo, and M.I. Osendi, Porous Mullite and Mullite-ZrO2 Granules for Thermal Spraying Applications, Surf. Coat. Technol., 2011, 205, p 4304-4311
H. Scholze, Influence of the Viscosity and Surface Tension on Hot-Stage Microscopy Measurements on Glasses, Ver. Dtsch. Keram. Ges., 1962, 391, p 63-68
H. Vogel, Temperature Dependence of Viscosity of Melts, Physik Z, 1921, 22, p 645-646
G.S. Fulcher, Analysis of Recent Measurements of the Viscosity of Glasses, J. Am. Ceram. Soc., 1925, 8, p 339-355
G. Tammann and W. Hesse, Temperature Dependence of Viscosity of Melted Supercooled Liquids, Z. Anorg. Chem., 1926, 156, p 245-247
W.C. Oliver and G.M. Pharr, Improved Technique for Determining Hardness and Elastic Modulus Using Load and Displacement Sensing Indentation Experiments, J. Mater. Res., 1992, 7, p 1564-1580
A. Roine, Outokumpu HSC Chemistry for Windows V. 5.11. Outokumpu Research, Pori 2002
J. Mesquita-Guimarães, E. García, M.I. Osendi, O. Sevecek, and R. Bermejo, Effect of Aging on the Onset of Cracks due to Redistribution of Residual Stresses in Functionally Graded Environmental Barrier Coatings of Mullite/ZrO2, Composites B, 2014, 61, p 199-205
M.A. Sainz, P. Miranzo, and M.I. Osendi, Sintering Behaviour and Properties of YAlSiO and YAlSiON Glass-Ceramics, Ceram. Int., 2011, 37, p 1485-1492
K. Liddell and D.P. Thompson, X-ray Diffraction Data for Yttrium Silicates, Br. Ceram Trans. J., 1986, 85, p 17-22
J. Ito and H. Johnson, Synthesis and Study of Yttrialite, Am. Mineral., 1968, 53, p 1940-1952
J. Gröbner, “Constitution Calculations in the System Y-Al-Si-C-O,” Ph.D. Thesis, University of Stuttgart, 1994
H.B. Guo, R. Vassen, and D. Stöver, Atmospheric Plasma Sprayed Thick Thermal Barrier Coatings with High Segmentation Crack Density, Surf. Coat. Technol., 2004, 186, p 353-363
L. Bianchi, A.C. Leger, M. Vardelle, A. Vardelle, and P. Fauchais, Splat Formation and Cooling of Plasma-Sprayed Zirconia, Thin Solid Films, 1997, 305, p 35-47
A.A. El-Kheshen, F.A. Khaliafa, E.A. Saad, and R.L. Elwan, Effect of Al2O3 Addition on Bioactivity, Thermal and Mechanical Properties of Some Bioactive Glasses, Ceram. Int., 2008, 34, p 1667-1673
C. Maxwell, A Treatise on Electricity and Magnetism, Clarendon, Oxford, 1904
E. Garcia, P. Miranzo, R. Soltani, and T.W. Coyle, Microstructure and Thermal Behavior of Thermal Barrier Coatings, J. Therm Spray Technol., 2008, 17, p 478-485
E. Garcia, J. Mesquita-Guimarães, M.I. Osendi, and P. Miranzo, Thermal Conductivity in Mullite/ZrO2 Composite Coatings, Ceram. Int., 2010, 36, p 1609-1614
D. Zhu, N.P. Bansal, K.N. Lee, and R.A. Miller, Thermal Conductivity of Ceramic Thermal Barrier and Environmental Barrier Coating Materials. NASA TM-2001-211122, NASA Lewis Research Center, Cleveland, OH, 2001
Z.Q. Sun, Y.C. Zhou, and M.S. Li, Thermal Properties of Single-Phase Y2SiO5, J. Eur. Ceram. Soc., 2009, 29, p 551-557
Acknowledgments
This work was supported by the Spanish Ministry of Economy and Competitiveness (MINECO) under project IPT-2012-0800-420000. Dr. E. Garcia acknowledges the financial support of the Ramon y Cajal Program of the MINECO.
Author information
Authors and Affiliations
Corresponding author
Additional information
This article is an invited paper selected from presentations at the 2014 International Thermal Spray Conference, held on May 21-23, 2014, in Barcelona, Spain, and has been expanded from the original presentation.
Rights and permissions
About this article
Cite this article
García, E., Nistal, A., Martín de la Escalera, F. et al. Thermally Sprayed Y2O3-Al2O3-SiO2 Coatings for High-Temperature Protection of SiC Ceramics. J Therm Spray Tech 24, 185–193 (2015). https://doi.org/10.1007/s11666-014-0178-y
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11666-014-0178-y