Skip to main content
Log in

WC-Co/Al Multilayer Coatings by Warm Spray Deposition

  • Peer Reviewed
  • Published:
Journal of Thermal Spray Technology Aims and scope Submit manuscript

Abstract

WC-Co/aluminum multilayer coatings have been developed by using warm spray deposition to improve fracture toughness and damage tolerance of conventional WC-Co coatings and to investigate the effects of ductile layer addition on their fracture properties. Prior to depositing the multilayer coatings, the mechanical properties of three metal coatings of aluminum, copper, and titanium, which were deposited by warm spraying, were evaluated. The aluminum coating showed excellent ductility among them and was selected for use as ductile layers for the multilayer coatings. The fracture behavior of WC-Co/Al coatings was examined by the four-point bending test. The multilayer coatings did not break in a brittle manner after reaching maximum load, but exhibited a plateau as a result of the ductility of the aluminum layers. The fracture behavior was compared with the finite element analysis results, and they showed good agreement in a general trend. It has been concluded that ductile metal reinforcements, by advanced thermal spray techniques such as warm spray deposition, are very effective to enhance the toughness and damage tolerance of sprayed cermet coatings.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16

Similar content being viewed by others

References

  1. G. Barbezat, A.R. Nicoll, and A. Sickinger, Abrasion, Erosion and Scuffing Resistance of Carbide and Oxide Ceramic Thermal Sprayed Coatings for Different Applications, Wear, 1993, 162, p 529-537

    Article  Google Scholar 

  2. C. Verdon, A. Karimi, and J.L. Martin, A Study of High Velocity Oxy-fuel Thermally Sprayed Tungsten Carbide Based Coatings. Part 1: Microstructures, Mater. Sci. Eng. A, 1998, 246(1-2), p 11-24

    Article  Google Scholar 

  3. D.A. Stewart, P.H. Shipway, and D.G. McCartney, Abrasive Wear Behaviour of Conventional and Nanocomposite HVOF-Sprayed WC-Co Coatings, Wear, 1999, 225, p 789-798

    Article  Google Scholar 

  4. H.J. Kim, C.H. Lee, and S.Y. Hwang, Superhard Nano WC-12%Co Coating by Cold Spray Deposition, Mater. Sci. Eng. A, 2005, 391(1-2), p 243-248

    Article  Google Scholar 

  5. S. Kuroda, J. Kawakita, M. Watanabe, and H. Katanoda, Warm Spraying—A Novel Coating Process Based on High-Velocity Impact of Solid Particles, Sci. Technol. Adv. Mater., 2008, 9(3), p 033002

    Article  Google Scholar 

  6. M. Watanabe, C. Pornthep, S. Kuroda, J. Kawakita, J. Kitamura, and K. Sato, Development of WC-Co Coatings by Warm Spray Deposition for Resource Savings of Tungsten, J. Jpn. Inst. Met., 2007, 71, p 853-859

    Article  CAS  Google Scholar 

  7. P. Chivavibul, M. Watanabe, S. Kuroda, J. Kawakita, M. Komatsu, K. Sato, and J. Kitamura, Development of WC-Co Coatings Deposited by Warm Spray Process, J. Therm. Spray Technol., 2008, 17(5-6), p 750-756

    Article  CAS  Google Scholar 

  8. P. Chivavibul, M. Watanabe, S. Kuroda, J. Kawakita, M. Komatsu, K. Sato, and J. Kitamura, Effect of Powder Characteristics on Properties of Warm-Sprayed WC-Co Coatings, J. Therm. Spray Technol., 2010, 19(1), p 81-88

    Article  CAS  Google Scholar 

  9. F. Zok and C.L. Hom, Large Scale Bridging in Brittle Matrix Composites, Acta Metall. Mater., 1990, 38(10), p 1895-1904

    Article  CAS  Google Scholar 

  10. H.C. Cao and A.G. Evans, On Crack Extension in Ductile/Brittle Laminates, Acta Metall. Mater., 1991, 39(12), p 2997-3005

    Article  CAS  Google Scholar 

  11. A.G. Evans and B.J. Dalgleish, The Fracture-Resistance of Metal Ceramic Interfaces, Acta Metall. Mater., 1992, 4, p S295-S306

    Google Scholar 

  12. M. Hadad, M. Hockauf, L.W. Meyer, G. Marot, J. Lesage, R. Hitzek, and S. Siegmann, Adhesion Evaluation of Multilayered Based WC-Co-Cr Thermally Sprayed Coatings, Surf. Coat. Technol., 2008, 202(18), p 4399-4405

    Article  CAS  Google Scholar 

  13. K.S. Ravichandran, K. An, R.E. Dutton, and S.L. Semiatin, Thermal Conductivity of Plasma-Sprayed Monolithic and Multilayer Coatings of Alumina and Yttria-Stabilized Zirconia, J. Am. Ceram. Soc., 1999, 82(3), p 673-682

    Article  CAS  Google Scholar 

  14. M. Watanabe, M. Komatsu, and S. Kuroda, Multilayered WC-Co/Cu Coatings by Warm Spray Deposition, Surf. Coat. Technol., 2011, 205(23-24), p 5358-5368

    Article  CAS  Google Scholar 

  15. S. Kuroda, M. Watanabe, K. Kim, and H. Katanoda, Current Status and Future Prospects of Warm Spray Technology, J. Therm. Spray Technol., 2011, 20(4), p 653-676

    Article  Google Scholar 

  16. S.P. Timoshenko and J.N. Goodier, Theory of Elasticity, 2nd ed., McGraw-Hill Book Co., 1951

  17. Y. Zhang, J. Li, J. Huang, and C. Ding, Mechanical and Tribological Properties of Plasma-Sprayed Cr3C2-NiCr, WC-Co, and Cr2O3 Coatings, J. Therm. Spray Technol., 1998, 7(2), p 242-246

    Article  Google Scholar 

  18. Y. Itoh, S. Suyama, and T. Fuse, Mechanical Properties of Aluminum Coatings Produced by Cold Spraying, J. Soc. Mater. Sci. Jpn., 2007, 56(6), p 550-555

    Article  CAS  Google Scholar 

  19. C.A. Folsom, F.W. Zok, and F.F. Lange, Flexural Properties of Brittle Multilayer Materials. 1. Modeling, J. Am. Ceram. Soc., 1994, 77(3), p 689-696

    Article  Google Scholar 

  20. A.J. Phillipps, W.J. Clegg, and T.W. Clyne, Fracture Behaviour of Ceramic Laminates in Bending. I. Modelling of Crack Propagation, Acta Metall. Mater., 1993, 41(3), p 805-817

    Article  CAS  Google Scholar 

  21. K.H. Kim and S. Kuroda, Amorphous Oxide Film Formed by Dynamic Oxidation During Kinetic Spraying of Titanium at High Temperature and Its Role in Subsequent Coating Formation, Scripta Mater., 2010, 63(2), p 215-218

    Article  CAS  Google Scholar 

  22. F. Gartner, T. Stoltenhoff, J. Voyer, H. Kreye, S. Riekehr, and M. Kocak, Mechanical Properties of Cold-Sprayed and Thermally Sprayed Copper Coatings, Surf. Coat. Technol., 2006, 200(24), p 6770-6782

    Article  Google Scholar 

Download references

Acknowledgments

Authors greatly acknowledge Fujimi Incorporated (Japan) for providing WC-Co feedstock powder. This work was supported as a part of Fail-Safe Hybrid Materials project (2006-2010) in National Institute for Materials Science Japan.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Makoto Watanabe.

Additional information

This article is an invited paper selected from presentations at the 2011 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Thermal Spray 2011: Proceedings of the International Thermal Spray Conference , Hamburg, Germany, September 27-29, 2011, Basil R. Marple, Arvind Agarwal, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and André McDonald, Ed., ASM International, Materials Park, OH, 2011.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Watanabe, M., Komatsu, M. & Kuroda, S. WC-Co/Al Multilayer Coatings by Warm Spray Deposition. J Therm Spray Tech 21, 597–608 (2012). https://doi.org/10.1007/s11666-012-9773-y

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11666-012-9773-y

Keywords

Navigation