Skip to main content
SpringerLink
Log in

High Temperature Oxidation Behavior of HfH2-CoCrAlYSi Coating Fabricated by Laser Cladding

  • Technical Article
  • Published:
Journal of Materials Engineering and Performance Aims and scope Submit manuscript

Abstract

CoCrAlYSi coating has been widely used in aero-engine for its high temperature oxidation resistance. As an additive element, Hf has been studied for improving the performance of CoCrAlYSi coating. However, there is a lack of study about the influence of Hf on the high temperature oxidation behavior of CoCrAlYSi coating. In this study, we prepared customized CoCrAlYSi coatings with various HfH2 contents by laser cladding. The microstructure evolution of CoCrAlYSi coating and formation characteristics of γ-Co solution phases were discussed. The isothermal oxidation products and oxide films of CoCrAlYSi coating at 1100 °C were analyzed. Results showed that due to the addition of HfH2, the grain of CoCrAlYSi coatings was refined, together with the micro-cracks decreased. The addition of HfH2 postponed the formation of CoO during isothermal oxidation test at 1100 °C in synthetic air. The lack of CoO further postponed the formation of CoCr2O4, which may cause the failure of CoCrAlYSi coating. Meanwihle, the growth rate of Cr2O3 oxide film was decreased due to the addition of Hf, which led to the improvement of stability of CoCrAlYSi coating.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

Availability of Data and Material

All data in this paper are original and publishable.

References

  1. D.R. Clarke, M. Oechsner, and N.P. Padture, Thermal-Barrier Coatings for More Efficient Gas-Turbine Engines, MRS Bull., 2012, 37, p 891–898.

    Article  CAS  Google Scholar 

  2. R. Darolia, Thermal Barrier Coatings Technology, Critical Review, Progress Update, Remaining Challenges and Prospects, Int. Mater. Rev., 2013, 58, p 315–348.

    Article  CAS  Google Scholar 

  3. M.J. Stiger, N.M. Yanar, M.G. Topping, F.S. Pettit, and G.H. Meier, Thermal Barrier Coatings for the 21st Century, Zeitschrift Fur Met., 1999, 90, p 1069–1078.

    CAS  Google Scholar 

  4. M. Peters, C. Leyens, U. Schulz, and W.A. Kaysser, EB-PVD Thermal Barrier Coatings for Aeroengines and Gas Turbines, Adv. Eng. Mater., 2001, 3, p 193–204.

    Article  CAS  Google Scholar 

  5. C.G. Levi, Emerging Materials and Processes for Thermal Barrier Systems, Curr. Opin. Solid State Mater. Sci., 2004, 8, p 77–91.

    Article  CAS  Google Scholar 

  6. İB. Nilüfer, H. Gökçe, F. Muhaffel, M.L. Öveçoğlu, and H. Çimenoğlu, The Effect of La2O3 on the Microstructure and Room Temperature Mechanical Properties of t-ZrO2, Ceram. Int., 2016, 42(8), p 9443–9447.

    Article  Google Scholar 

  7. K. Yuan, C. Feng, X. Gan, Yu. Zhichao, X. Wang, L. Zhu, G. Zhang, and Xu. Dong, Fabrication of La2Zr2O7 Ceramic Fibers Via Electrospinning Method Using Different La2O3 Precursors, Ceram. Int., 2016, 15, p 16633–16639.

    Article  Google Scholar 

  8. K.M. Doleker, Y. Ozgurluk, and A.C. Karaoglanli, Isothermal Oxidation and Thermal Cyclic Behaviors of YSZ and Double-Layered YSZ/La2Zr2O7 Thermal Barrier Coatings (TBCs), Surf. Coat. Technol., 2018, 351, p 78–88.

    Article  CAS  Google Scholar 

  9. M. Shinozaki and T.W. Clyne, The Effect of Vermiculite on the Degradation and Spallation of Plasma Sprayed Thermal Barrier Coatings, Surf. Coat. Technol., 2013, 216, p 172–177.

    Article  CAS  Google Scholar 

  10. K.M. Doleker, Y. Ozgurluk, H. Ahlatci, and A.C. Karaoglanli, Evaluation of Oxidation and Thermal Cyclic Behavior of YSZ, Gd2Zr2O7 and YSZ/Gd2Zr2O7 TBCs, Surf. Coat. Technol., 2018, 371, p 262–275.

    Article  Google Scholar 

  11. D. Pwi, M. Allam, and J. Stringer, The Oxidation Behavior of CoCrAI Systems Containing Active Element Additions, Oxid. Met., 1978, 12, p 35–66.

    Article  Google Scholar 

  12. T. Dpwi, M. Allam, and J. Stringer, Improvements in Oxidation Resistance by Dispersed Oxide Addition, Al203-Forming Alloys, Oxid. Met., 1979, 13, p 381–401.

    Article  Google Scholar 

  13. M. Aadpw and J. Stringer, The High Temperature Containing Oxidation of CoCrAl Allows Yttrium or Hafnium Additions, Thin Solid Films, 1977, 45, p 377–384.

    Article  Google Scholar 

  14. R. Pa and J. Stringer, The Influence of Alloy Microstructure on the Oxide Peg Morphologies in a Co-10% Cr% AI Alloy With and Without Reactive Element Additions, Oxid. Met., 1985, 23, p 1–16.

    Article  Google Scholar 

  15. C. Wa and S. Khanna, Addition of Yttrium, Cerium and Hafnium to Combat the Deleterious Effect of Sulphur Impurity during Oxidation of an Ni-Cr-AI Alloy, Mater. Sci. Eng., 1989, 120, p 185–191.

    Google Scholar 

  16. B.A. Pint, J.A. Haynes, and T.M. Besmann, Effect of Hf and Y alloy additions on aluminide coating performance, Surf. Coat. Technol., 2010, 204, p 3287–3293.

    Article  CAS  Google Scholar 

  17. Y. Wang, M. Suneson, and G. Sayre, Synthesis of Hf-Modified Aluminide Coatings on Ni-Base Superalloys, Surf. Coat. Technol., 2011, 206, p 1218–1228.

    Article  CAS  Google Scholar 

  18. Y. Wang and M. Suneson, Oxidation Behavior of Hf-Modified Aluminide Coatings on Haynes-188 at 1050 °C, Surf. Coat. Technol., 2013, 215, p 7–15.

    Article  CAS  Google Scholar 

  19. A.U. Munawar, U. Schulz, and M. Shahid, Microstructure and Lifetime of EB-PVD TBCs with Hf-Doped Bond Coat and Gd-Zirconate Ceramic Top Coat on CMSX-4 Substrates, Surf. Coat. Technol., 2016, 299, p 104–112.

    Article  CAS  Google Scholar 

  20. V. Kumar and B. Kandasubramanian, Processing and Design Methodologies for Advanced and Novel Thermal Barrier Coatings for Engineering Applications, Particuology, 2016, 27, p 1–28.

    Article  CAS  Google Scholar 

  21. C. Li, H. Guo, L. Gao, L. Wei, S. Gong, and H. Xu, Microstructures of Yttria-Stabilized Zirconia Coatings by Plasma Spray-Physical Vapor Deposition, J. Therm. Spray Technol., 2014, 24, p 534–541.

    Article  Google Scholar 

  22. J.C. Pereira, J.C. Zambrano, M.J. Tobar, A. Yañez, and V. Amigó, High Temperature Oxidation Behavior of Laser Cladding MCrAlY Coatings on Austenitic Stainless Steel, Surf. Coat. Technol., 2015, 270, p 243–248.

    Article  CAS  Google Scholar 

  23. J.D. Majumdar and I. Manna, Laser-Surface Alloying of Nimonic 80 with Silicon and Aluminum and its Oxidation Behavior, Metall. and Mater. Trans. A., 2012, 43, p 3786–3796.

    Article  CAS  Google Scholar 

  24. M. Barekat, R. Shoja Razavi, and A. Ghasemi, High Temperature Oxidation Behavior of Laser Clad Co–Cr–Mo Coating on γ-TiAl Substrate, J. Laser Appl., 2016, 28, p 042005.

    Article  Google Scholar 

  25. C. Cui, Z. Guo, Y. Liu, Q. Xie, Z. Wang, J. Hu, and Y. Yao, Characteristics of Cobalt-Based Alloy Coating on Tool Steel Prepared by Powder Feeding Laser Cladding, Opt. Laser Technol., 2007, 39, p 1544–1550.

    Article  CAS  Google Scholar 

  26. F. Weng, H. Yu, C. Chen, J. Liu, and L. Zhao, Microstructures and Properties of TiN Reinforced Co-Based Composite Coatings Modified with Y2O3 by Laser Cladding on Ti–6Al–4V Alloy, J. Alloy. Compd., 2015, 650, p 178–184.

    Article  CAS  Google Scholar 

  27. F. Weng, H. Yu, J. Liu, C. Chen, J. Dai, and Z. Zhao, Micro-Structure and Wear Property of the Ti5Si3/TiC Reinforced Co-Based Coatings Fabricated by Laser Cladding on Ti-6Al-4V, Opt. Laser Technol., 2017, 92, p 156–162.

    Article  CAS  Google Scholar 

  28. L. Zhang, C. Wang, L. Han, and C. Dong, Influence of Laser Power on Microstructure and Properties of Laser Clad Co-Based Amorphous Composite Coatings, Surf. Interfaces, 2017, 6, p 18–23.

    Article  CAS  Google Scholar 

  29. X. Zhang, X. Jie, L. Zhang, S. Luo, and Q. Zheng, Improving the High-Temperature Oxidation Resistance of H13 Steel by Laser Cladding with a WC/Co-Cr Alloy Coating, Anti-Corros. Methods Mater., 2016, 63, p 171–176.

    Article  CAS  Google Scholar 

  30. Q.Y. Hou, J.S. Gao, and F. Zhou, Microstructure and Wear Characteristics of Cobalt-Based Alloy Deposited by Plasma Transferred Arc Weld Surfacing, Surf. Coat. Technol., 2005, 194(2–3), p 238–243.

    Article  CAS  Google Scholar 

  31. S. Mohammed, P. Balu, A. Ahmed et al., Improvement of Wear Resistance of the Nickel Based Alloy Mixed with Rare Earth Elements by High Power Direct Diode Laser Cladding, Lasers Manuf. Mater. Process., 2019, 6, p 173–188.

    Article  Google Scholar 

  32. Z.Y. Zhang, X.C. Lu, and B.L. Han, Rare Earth Effect on Microstructure, Mechanical and Tribological Properties of CoCrW Coatings, Mater. Sci. Eng. A., 2006, 444, p 92–98.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nanjing University of Aeronautics and Astronautics, Nanjing, 210016, China

    Zhao Yong, Yang Liu, Shichun Jiang, Lili Chang, Lida Shen & Zongjun Tian

  2. College of Energy and Power Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing, 210016, China

    Deqiao Xie

Authors
  1. Zhao Yong
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Deqiao Xie
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yang Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Shichun Jiang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Lili Chang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Lida Shen
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Zongjun Tian
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Zongjun Tian.

Ethics declarations

Conflict of interest

Publication of this paper has no conflict of interest with any other organizations.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yong, Z., Xie, D., Liu, Y. et al. High Temperature Oxidation Behavior of HfH2-CoCrAlYSi Coating Fabricated by Laser Cladding. J. of Materi Eng and Perform 33, 3077–3086 (2024). https://doi.org/10.1007/s11665-023-08203-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11665-023-08203-x

Keywords

Search

Navigation