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An Investigation on Room and High Temperature Wear Performance of Fe-45%WC Hardfaced Coating Applied on Ductile Cast Iron

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Abstract

In this study, Fe-45%WC hardfacing coating was applied using flux core welding wire on ductile cast iron substrate by the GTAW process. Microstructural characterization and wear performance measurements were performed at room and 400 °C. The matrix phase of the hardfaced coating contained dendrites that chemically contained Fe and other elements such as Ni and Cr, diffused from the buffer layer. In the inter-dendritic spaces, tungsten-rich Eta carbides (Fe3W3C) with fish-bone morphology as well as chromium-rich carbides (Cr7C3) with leaf-shaped morphology were observed. The formation of eta-carbide was due to the dissolution of WC particles during the thermal effect of the hardfacing process, and the formation of Chromium carbide was caused by dilution of the chromium element from the buffer layer. For the room temperature wear test, a protective tribolayer was formed on the wear track due to the presence of graphite in ductile cast iron, which acted as a lubricant. However, this tribolayer was unable to protect the cast iron, and it was removed during the wear test at room temperature because of its low adhesion, leading to severe wear of the base metal. On the other hand, for the Fe-45% WC hardfaced coating, despite the lack of formation of the lubricant at room temperature, much better wear resistance was observed as compared to the base metal, mainly due to its higher hardness and also presence of WC reinforcing particles in its structure. For the high temperature wear test at 400 °C, due to the formation of a continuous tribolayer, with good adhesion on the wear track of base metal and hardfaced coating, higher hardness, and trapping of WC debris in the tribolayer for the Fe-45%WC hardfaced cast iron, much better wear resistance in comparison to the room temperature wear test was observed.

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Notes

  1. In this regard, WC powder was first extracted from industrial scrabs and chips and purified by chemical methods. Then the powder was sandwiched in an iron shell, to produce a wire welding with specific thickness and chemical (Fe-45% WC) composition, fabricating. The welding wire with desired diameter were produced through deep drawing in several steps. The chemical composition of WC powder and Fe shell of the composite wires is presented in Table1.

References

  1. J.M. Amado, M.J. Tobar, J.C. Alvarez, J. Lamas, and A. Yanez, Laser Cladding of Tungsten Carbides (Spherotene1) Hardfacing Alloys for the Mining and Mineral Industry, Appl. Surf. Sci., 2009, 255, p 5553–5556.

    Article  CAS  ADS  Google Scholar 

  2. K.H. Lo, F.T. Cheng, and H.C. Man, Cavitation Erosion Mechanism of S31600 Stainless Steel Laser Surface Modified with Unclad WC, Mater. Sci. Eng. A, 2003, 357, p 168–180.

    Article  Google Scholar 

  3. M.C. Carvalho, Y. Wang, J.A.S. Souza, E.M. Braga, and L. Li, Characterization of Phases and Defects in Chromium Carbide Overlays Deposited by SAW Process, Eng. Fail. Anal., 2006, 60, p 374–382.

    Article  Google Scholar 

  4. P.F. Mendez, N. Barnes, K. Bell, S.D. Borle, S.S. Gajapathi, S.D. Guest, H. Izadi, A. KamyabiGol, and G. Wood, Welding Processes for Wear Resistant Overlays, Manuf. Process., 2014, 16, p 4–25.

    Article  Google Scholar 

  5. C.M. Chang, Y.C. Chen, and W. Wu, Microstructural and Abrasive Characteristics of High Carbon Fe–Cr–C Hardfacing Alloy, Tribol. Int., 2010, 43, p 929–934.

    Article  CAS  Google Scholar 

  6. O.M. Alzouma, M.A. Azman, D.L. Yung, V. Fridrici, and P. Kapsa, Influence of Different Reinforcing Particles on the Scratch Resistance and Microstructure of Different WC–Ni Composites, Wear, 2016, 352–353, p 130–135.

    Article  Google Scholar 

  7. R. Zahiri, R. Sundaramoorthy, P. Lysz, and C. Subramanian, Hardfacing Using Ferro-Alloy Powdermixtures by Submerged Arc Welding, Surf. Coat. Technol., 2014, 260, p 220–229.

    Article  CAS  Google Scholar 

  8. Z. Weng, A. Wang, X. Wu, Y. Wang, and Z. Yang, Wear Resistance of Diode Laser Clad Ni/WC Composite Coatings at Different Temperatures, Surf. Coat. Technol., 2016, 304, p 283–292.

    Article  CAS  Google Scholar 

  9. H. Xu, T. He, N. Zhong, B. Zhao, and Z. Liu, Transient Thermomechanical Analysis of Micro Cylindrical Asperity Sliding Contact of SnSbCu alloy, Tribology Int, 2022, 167, p 107362.

    Article  CAS  Google Scholar 

  10. G. Portu, S. Guicciardi, C. Melandri, and F. Monteverde, Wear Behaviour of Al2O3_Mo and Al2O3_Nb Composites, Wear, 2007, 262, p 1346–1352.

    Article  Google Scholar 

  11. Z. Zhang, F. Yang, H. Zhang, T. Zhang, H. Wang, Y. Xu, and Q. Ma, Influence of CeO2 Addition on Forming Quality and Microstructure of TiCx-Reinforced CrTi4-Based Laser Cladding Composite Coating, Mater. Charact., 2020, 171, p 110732.

    Article  Google Scholar 

  12. P. Pereira, L.M. Vilhena, J. Sacramentos, A.M. Senos, L.F. Malheiros, and A. Ramallo, Tribological Behaviour of Different Formulation of WC Composites, Wear, 2022, 506, p 204415.

    Article  Google Scholar 

  13. P.C. Huang, K.H. Hou, J.J. Hong, M.H. Lin, and G.L. Wang, Study of Fabrication and Wear Properties of Ni_SiC Composite Coating on A356 Aluminum Alloy, Wear, 2021, 477, p 203772.

    Article  CAS  Google Scholar 

  14. V. Jankauskas, M. Antonov, V. Varnauskas, R. Skirkus, and D. Goljandin, Effect of WC Grain Size and Content on Low Stress Abrasive Wear of Manual Arc Welded Hardfacings With Low-Carbon or Stainless Steel Matrix, Wear, 2015, 328–329, p 378–390.

    Article  Google Scholar 

  15. S. Gao, H. Nakashin, M. Yamamoto, K. Shinozaki, K. Kadoi, H. Watanabe, T. Kanazawa, and A.P. Gerlich, Development of WC Hardfacing Welding Process Using Pulse Heated Hot-Wire Gas Tungsten Arc Welding System, Quart. J. Japan Weld. Soc., 2013, 31, p 57–60.

    Article  Google Scholar 

  16. S. Buytoz, M. Ulutan, and M.M. Yildirim, Dry Sliding Wear Behavior of TIG Welding Clad WC Composite Coatings, Appl. Surf. Sci., 2005, 252, p 1313–1323.

    Article  CAS  ADS  Google Scholar 

  17. S.W. Huanga, M. Samandi, and M. Brandt, Abrasive Wear Performance and Microstructure of Laser Clad WC/Ni Layers, Wear, 2004, 256, p 1095–1105.

    Article  Google Scholar 

  18. G. Fisher, T. Wolfe, and K. Meszaros, The Effects of Carbide Characteristics on the Performance of Tungsten Carbide-Based Composite Overlays, Deposited by Plasma-Transferred Arc Welding, Therm. Spray Technol., 2013, 22(5), p 764–771.

    Article  CAS  ADS  Google Scholar 

  19. Ch. Just, E. Badisch, and J. Wosik, Influence of Welding Current on Carbide/Matrix Interface Properties in MMCs, Mater. Process. Technol., 2010, 210, p 408–414.

    Article  CAS  Google Scholar 

  20. L. Zhong, C. Deng, X. Zhang, H. Bai, J. Zhu, Z. Lu, and Y. Xu, WC-Fe Layer with High Volume Fraction and Fracture Toughness on Cast Iron Fabricated by In Situ Solid-Phase Diffusion, Vacuum, 2019, 84, p 456–468.

    Google Scholar 

  21. L. Niu, Y. Xu, and X. Wang, Fabrication of WC/Fe Composite Coating by Centrifugal Casting Plus In-Situ Synthesis Techniques, Surf. Coat. Technol., 2010, 205, p 551–556.

    Article  CAS  Google Scholar 

  22. N. Nordin, F.M. Yussof, S. Kasolang, Z. Salleh, and M. Ali Ahmad, Wear Rate of Natural Fibre: Long Kenaf Composite, Proc. Eng., 2013, 68, p 145–151.

    Article  CAS  Google Scholar 

  23. B. Cheniti, D. Miroud, P. Hvizdo, J. Balko, R. Sedlak, T. Csanadi, B. Belkessa, and M. Fides, Investigation of WC Decarburization Effect on the Microstructure and Wear Behavior of WC-Ni Hardfacing Under Dry and Alkaline Wet Conditions, Mater. Chem. Phys., 2018, 208, p 237–247.

    Article  CAS  Google Scholar 

  24. D.V. Sueti, L.R. Shein, and A.L. Ivanovskii, Structural, Electronic and Magnetic Properties of η Carbides (Fe3W3C, Fe6W6C, Co3W3C and Co6W6C) from First Principles Calculations, Phys. B Condens. Matter., 2009, 404, p 3544–3549.

    Article  ADS  Google Scholar 

  25. M.F. Buchely, J.C. Gutierrez, L.M. Leon, and A. Toro, The Effect of Microstructure on Abrasive Wear of Hardfacing Alloys, Wear, 2005, 259, p 52–61.

    Article  CAS  Google Scholar 

  26. Y. Birol, High Temperature Sliding Wear Behaviour of Inconel 617 and Stellite 6 Alloys, Wear, 2010, 269, p 664–671.

    Article  CAS  Google Scholar 

  27. R. ArabiJashvaghani, M. Jaberzadeh, H. Zohdi, and M. Shamanian, Microstructural Study and Wear Behavior of Ductile Iron Surface Alloyed by Inconel 617, Mater. Des., 2014, 54, p 491–497.

    Article  Google Scholar 

  28. X. Li, X. Yang, D. Yi, B. Liu, J. Zhu, J. Li, C. Gao, and L. Wang, Effects of NbC Content on Microstructural Evolution and Mechanical Properties of Laser Cladded Fe50Mn30Co10Cr10-xNbC Composite Coatings, Intermetallics, 2021, 138, p P107309.

    Article  Google Scholar 

  29. F. Fernandes, T. Polcar, A. Loureiro, and A. Cavaleiro, Effect of the Substrate Dilution on the Room and High Temperature Tribological Behaviour of Ni-Based Coatings Deposited by PTA on Grey Cast Iron, Surf. Coat. Technol., 2015, 281, p 11–19.

    Article  CAS  Google Scholar 

  30. Z. Shigen and F. Jinhui, Rolling Contact Fatigue Performance of Ductile Iron Improved by Electric Contact Surface Strengthening, Tribol. Int., 2013, 60, p 58–63.

    Article  Google Scholar 

  31. X. Qi, S. Zhu, and J. Fan, Rolling Contact Fatigue Performance of Ductile Iron Improved by Electric Contact Surface Strengthening, Tribol. Int., 2013, 60, p 58–63.

    Article  CAS  Google Scholar 

  32. C. Just, E. Badisch, and J. Wosik, Influence of Welding Current on Carbide/Matrix Interface Properties in MMCs, Mater. Process. Technol., 2010, 210(2), p 408–414.

    Article  CAS  Google Scholar 

  33. T.B. Torgerson, M.B. Harris, S.A. Alidokht, T.W. Scharf, S.M. Aouadi, R.R. Chromik, J.S. Zabinski, and A.A. Voevodin, Room and Elevated Temperature Sliding Wear Behavior of Cold Sprayed Ni-WC Composite Coatings, Surf. Coat. Technol., 2018, 350, p 136–145.

    Article  CAS  Google Scholar 

  34. Y.K. Singla, N. Arora, and D.H. Dwivedi, Dry Sliding Adhesive Wear Characteristics of Fe-Based Hardfacing Alloys with Different CeO2 Additives—A Statistical Analysis, Tribol. Int., 2017, 105, p 229–240.

    Article  CAS  Google Scholar 

  35. M. Shamanian, S.M.R. Mousavi, and S.R. MousaviPour, Effects of Surface Alloying on Microstructure and Wear Behavior of Ductile Iron, Mater. Des., 2010, 31, p 2760–2766.

    Article  CAS  Google Scholar 

  36. R. Jia, S. Liu, Z. Luo, J. Ning, H. Wang, T. Luo, Y. Zhu, X. Yuan, and Z. Wang, Microstructure and Wear Resistance of WC and High Chromium Cast Iron Hardfacing Layers, Coatings, 2020, 852, p 1–9.

    Google Scholar 

  37. M. Erfanmanesh, R. Razavi, H. AbdollahPour, H. Mohammadian, M. Barekat, and H. Hashemi, Friction and Wear Behavior of Laser Cladded WC-Co and Ni/WC-Co Deposits at High Temperature, Int. J. Refract. Met. Hard Mater., 2019, 81, p 137–148.

    Article  CAS  Google Scholar 

  38. Q. Xiao, W.L. Sun, K.X. Yang, X.F. Xing, Z.H. Chen, H.N. Zhou, and J. Lu, Wear Mechanisms and Micro-Evaluation on WC Particles Investigation of WC-Fe Composite Coatings Fabricated by Laser Cladding, Surf. Coat. Technol., 2021, 420, p 127341.

    Article  CAS  Google Scholar 

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Acknowledgments

The authors would like to thank the Isfahan University of Technology and CSROLL and MIRCO Companies for their support.

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Correspondence to Abdoulmajid Eslami.

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Mohammadi, J., Eslami, A., Ashrafizadeh, F. et al. An Investigation on Room and High Temperature Wear Performance of Fe-45%WC Hardfaced Coating Applied on Ductile Cast Iron. J. of Materi Eng and Perform 33, 1358–1368 (2024). https://doi.org/10.1007/s11665-023-08077-z

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