Abstract
Achieving an excellent combination of high strength and ductility in low-alloy magnesium (Mg) alloys is a great challenge. In this work, a new Mg-1.03Ca-0.47Mn-2.39Sn alloy was designed. The extruded sheet has a low ultimate tensile strength (UTS, ~268 MPa) and total elongation (EL, ~7.5%). However, after rolling and annealing, the strength and plasticity are greatly improved. It is noted that the UTS and EL increased simultaneously with the increase in a rolling pass and cumulative reduction. Especially, an excellent combination of UTS of 310 MPa and EL of 22% is achieved by 4-passes hot rolling and the fifth pass differential speed rolling. Microstructural results show that the high strength is mainly attributed to the uniformly fine grain size ( ~4.5 μm) and the high-density striated CaMgSn and globular Mg2Ca precipitates. In addition, the uniform grain size, weaken transverse direction-split texture and the activation of multiple slips systems all contribute to the enhanced ductility. These findings provide an effective method for manufacturing low-alloy Mg alloys with high strength and ductility by rolling.
Similar content being viewed by others
References
T. Nakata, C. Xu, R. Ajima, K. Shimizu, S. Hanaki, T.T. Sasaki, L. Ma, K. Hono and S. Kamado, Strong and Ductile Age-Hardening Mg-Al-Ca-Mn Alloy That Can be Extruded as Fast as Aluminum Alloys, Acta Mater., 2017, 130, p 261–270.
T.Z. Han, G.S. Huang, L. Huang, B. Jiang, G.G. Wang, A.T. Tang and F.S. Pan, Influence of Continuous Bending Process on Texture Evolution and Mechanical Properties of AZ31 Magnesium Alloy, Acta Metall. Sinica (English Lett.), 2018, 31, p 225–233.
J. She, F.S. Pan, W. Guo, A.T. Tang, Z.Y. Gao, S.Q. Luo, K. Song and Z.W. Yu, M, Rashad, Effect of high Mn Content on Development of Ultra-Fine Grain Extruded Magnesium Alloy, Mater. Des., 2016, 90, p 7–12.
K. Sheng, Lu. Liwei, Y. Xiang, M. Ma and Wu. Zhiqiang, Crack Behavior in Mg/Al Alloy Thin Sheet During Hot Compound Extrusion, J. Magnes. Alloys, 2019, 7, p 717–724.
G. Lu, S. Nie, J.J. Wang, Y. Zhang, T.H. Wu, Y.J. Liu and C.M. Liu, Enhancing the Bake-Hardening Responses of a Pre-Aged Al-Mg-Si Alloy by Trace Sn Additions, J. Mater. Sci. Technol., 2020, 40, p 107–112.
X.Y. Wang, Y.F. Wang, C. Wang, S. Xu, J. Rong, Z.Z. Yang, J.G. Wang and H.Y. Wang, A Simultaneous Improvement of Both Strength and Ductility by Sn Addition in as-Extruded Mg-6Al-4Zn Alloy, J. Mater. Sci. Technol., 2020, 49, p 117–125.
S. Dai, Z.Y. Bian, W.B. Wu, J.M. Tao, L. Cai, M.L. Wang, C.J. Xia and H.W. Wang, The role of Sn Element on the Deformation Mechanism and Precipitation Behavior of the Al–Cu–Mg Alloy, Mater. Sci. Eng. A, 2020, 792, p 139838.
J.K. Zou, J.H. Chen, H.G. Yan, W.J. Xia, B. Su, Y. Lei and Q. Wu, Effects of Sn Addition on Dynamic Recrystallization of Mg-5Zn-1Mn Alloy During High Strain Rate Deformation, Mater. Sci. Eng. A, 2018, 735, p 49–60.
Sh. Asqardoust, A. Zarei-Hanzaki, H.R. Abedi, T. Krajnak and P. Minárik, Enhancing the Strength and Ductility in Accumulative Back Extruded WE43 Magnesium Alloy Through Achieving Bimodal Grain Size Distribution and Texture Weakening, Mater. Sci. Eng. A, 2017, 698, p 218–229.
Q. Wang, B. Jiang, L. Liu, Q. Yang, D. Xia, D. Zhang, G. Huang and F. Pan, Reduction Per Pass Effect on Texture Traits and Mechanical Anisotropy of Mg-Al-Zn-Mn-Ca alloy Subjected to Unidirectional and Cross Rolling, J. Market. Res., 2020, 9, p 9607–9619.
Q. Xu, A. Ma, Y. Li, J. Sun, Y. Yuan, J. Jiang and C. Ni, Microstructure Evolution of AZ91 alloy Processed by a Combination Method of Equal Channel Angular Pressing and Rolling, J. Magn. Alloy., 2020, 8, p 192–198.
S.W. Bae, S.-H. Kim, J.U. Lee, W.-K. Jo, W.-H. Hong, W. Kim and S.H. Park, Improvement of Mechanical Properties and Reduction of Yield Asymmetry of Extruded Mg-Al-Zn Alloy Through Sn Addition, J. Alloy. Compd., 2018, 766, p 748–758.
H.W. Yang, I.P. Widiantara and Y.G. Ko, Effect of Deformation Path on Texture and Tension Properties of Submicrocrystalline Al-Mg-Si Alloy Fabricated by Differential Speed Rolling, Mater. Lett., 2018, 213, p 54–57.
Young Gun Ko, Kotiba Hamad, Microstructure Stability and Mechanical Properties of Ultrafine Grained 5052 Al Alloy Fabricated by Differential Speed Rolling, Mater. Sci. Eng., A, 2018, 733, p 24–27.
Y.G. Ko and K. Hamad, Structural Features and Mechanical Properties of AZ31 Mg Alloy Warm-Deformed by Differential Speed Rolling, J. Alloy. Compd., 2018, 744, p 96–103.
W. Kang, L. Lu, F. Longbiao, F. Lu, C. Gan and X. Li, Effects of Pre-Aging on Microstructure Evolution and Deformation Mechanisms of Hot Extruded Mg-6Zn-1Gd-1Er Mg Alloys, J. Magn. Alloys, 2021 https://doi.org/10.1016/j.jma.2021.05.019
H. Pan, H. Fu, Y. Ren, Q. Huang, Z. Gao, J. She, G. Qin, Q. Yang, B. Song and F. Pan, Effect of Cu/Zn on Microstructure and Mechanical Properties of Extruded Mg–Sn Alloys, Mater. Sci. Technol., 2016, 32, p 1240–1248.
Bo. Che, Lu. Liwei, W. Kang, J. Luo, M. Ma and L. Liu, Hot Deformation Behavior and Processing Map of a New Type Mg-6Zn-1Gd-1Er Alloy, J. Alloy. Compd., 2021, 862, 158700.
S.M. Fatemi and A. Zarei-Hanzaki, Microband/twin Recrystallization During Back Extrusion of AZ31 Magnesium, Mater. Sci. Eng. A, 2017, 708, p 230–236.
N. Dudamell, I. Ulacia, F. Galvez, S. Yi, J. Bohlen, D. Letzig, I. Hurtado and M.T. Perez-Prado, Influence of Texture on the Recrystallization Mechanisms in an AZ31 Mg Sheet Alloy at Dynamic Rates, Mater. Sci. Eng. A, 2012, 532, p 528–535.
Bo. Che, Lu. Liwei, Wu. Zhiqiang, H. Zhang, M. Ma, J. Luo and H. Zhao, Dynamic Recrystallization Behavior and Microstructure Evolution of a New Mg-6Zn-1Gd-1Er alloy with and Without Pre-Aging Treatment, Mater. Charact., 2021, 181, p 111506.
B.C. Suh, J.H. Kim, J.H. Bae, J.H. Hwang, M.S. Shim and N.J. Kim, Effect of Sn Addition on the Microstructure and Deformation Behavior of Mg-3Al Alloy, Acta Mater., 2017, 124, p 268–279.
W. Yuan, S.K. Panigrahi, J.Q. Su and R.S. Mishra, Influence of Grain Size and Texture on Hall-Petch Relationship for a Magnesium Alloy, Scripta Mater., 2011, 65, p 994–997.
Bo. Che, Lu. Liwei, J. Zhang, J. Zhang, M. Ma, L. Wang and F. Qi, Effects of Cryogenic Treatment on Microstructure and Mechanical Properties of AZ31 Magnesium Alloy Rolled at Different Paths, Mater. Sci. Eng. A, 2022, 832, 142475.
X. Liu, X. Qiao, Z. Li and M. Zheng, High Strength and Excellent Ductility of Dilute Mg-0.68Al-0.32Ca-0.50Mn (wt.%) Extrusion Alloy Obtained by T6 Treatment, Mater. Char., 2020, 162, 110197.
J.D. Robson, D.T. Henry and B. Davis, Particle Effects on Recrystallization in Magnesium–Manganese Alloys: Particle Pinning, Mater. Sci. Eng. A, 2011, 528, p 4239–4247.
H.J. Yang, X.H. An, X.H. Shao, X.M. Yang, S.X. Li, S.D. Wu and Z.F. Zhang, Enhancing Strength and Ductility of Mg–12Gd–3Y–0.5Zr Alloy by Forming a bi-Ultrafine Microstructure, Mater. Sci. Eng. A, 2011, 528, p 4300–4311.
Acknowledgments
The authors acknowledge support from the National Natural Science Foundation of China (U1910213), Taiyuan University of Science and Technology Scientific Research Initial Funding (Grant No. 20202039 and 20192002), Applied Basic Research Program of Shanxi Province (201901D211290).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Fan, Q., Jia, Y., Cai, Z. et al. Effect of Rolling Schedule on Microstructure and Properties of Mg-Ca-Mn-Sn Sheet. J. of Materi Eng and Perform 31, 10137–10142 (2022). https://doi.org/10.1007/s11665-022-07047-1
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-022-07047-1