Abstract
A novel Fe-Cr-B-C-Al-Si-Mn composite coating was designed and synthesized on 2Cr13 steel substrate using laser cladding technique in this study. The microstructure evolution, microhardness and wear resistance of the composite coating were investigated. The results showed that the microstructure of the coating was mainly composed of α-(Fe,Cr,Al) martensite, retained γ-Fe, and the eutectic comprised of CrFeB, M3(C,B)2, M2(B,C) and M23(C,B)6. The average microhardness of the coating (742.1 HV0.5) was 3.95 times compared with the 2Cr13 steel substrate, and the wear resistance was enhanced by 12.5 times compared with the 2Cr13 steel substrate. The wear mechanisms were dominated by abrasive wear and oxidative wear.
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R. Cao, X.K. Zhao, Y. Ding, X.B. Zhang, X.X. Jiang, Y.J. Yan and J.H. Chen, Effects of the Rolling Temperature on the Microstructure and Mechanical properTies of 2Cr13/316L Laminated COMPOSITES Prepared by Accumulative Roll-Bonding (ARB), Mater. Charact., 2018, 139, p 153–164.
J.Q. Yang, Y. Liu, Z.Y. Ye, D.Z. Yang and S.Y. He, Microstructure and Tribological Characteristics of Nitrided Layer on 2Cr13 Steel in air and Vacuum, Surf. Coat. Technol., 2009, 204, p 705–712.
Q.L. Wu, Y.S. Sun, F. Xue and J. Zhou, Microstructure, Mechanical and Wear Properties of TiC Particulate Reinforced 2Cr13 Steel by In Situ Reaction and Electroslag Remelting, Ironmaking Steelmaking, 2008, 35, p 387–395.
P.L. Zhang, X.K. Zhao, B. Yang, X.B. Zhang and R. Cao, Effects of Rolling Temperature on the Microstructure and Properties of 2Cr13/316L/9Cr18MoV Stainless Steel Composite Plate Fabricated by Hot-Rolling Bonding Process, J. Mater. Eng. Perform., 2018, 27, p 3978–3993.
A.X. Feng, P.C. Zhou, G.F. Nie, J.W. Wang, Z.C. Han, F. Shi and B. Li, Influence of Heat Treatment and Laser Shock Processing on Impact Toughness of 2Cr13 Martensite Stainless Steel, Chin. J. Lasers, 2012, 39, p 1–4.
Z. Zhang, Y. Zhao, J. Shan, A. Wu, H. Gu and X. Tang, Influence of Heat Treatment on Microstructures and Mechanical Properties of K447A Cladding Layers Obtained by Laser Solid Forming, J. Alloys Compd., 2019, 790, p 703–715.
P.J. Kelly and R.D. Arnell, Magnetron Sputtering: A Review of Recent Developments and Applications, Vacuum, 2000, 56, p 159–172.
X.R. Liu, K.L. Wang, W. Zhang, J.Z. Zhang and J.Z. Li, Robust, Self-Cleaning, Anti-Fouling, Superamphiphobic Soy Protein Isolate Composite Films Using Spray-Coating Technique with Fluorinated HNTs/SiO2, Compos. Pt. B-Eng., 2019, 174, p 107002.
U. Demirkol, S. Pat, R. Mohammadigharehbagh, C. Musaoğlu, M. Özgür, S. Elmas, S. Özen and Ş Korkmaz, Determination of the Structural, Morphological and Optical Properties of Graphene Doped SnO Thin Films Deposited by Using Thermionic Vacuum Arc Technique, Phys. B Condens. Matter., 2019, 569, p 14–19.
X. Qian, J.J. Zhong, J.H. Zhi, F.F. Heng, X.F. Wang, Y.G. Zhang and S.L. Song, Electrochemical Surface Modification of Polyacrylonitrile-Based Ultrahigh Modulus Carbon Fibers and its Effect on the Interfacial Properties of UKMCF/EP Composites, Compos. Pt. B-Eng., 2019, 164, p 476–484.
K.M. Wang, D. Du, G. Liu, Z. Pu, B.H. Chang and J. Ju, A Study on the Additive Manufacturing of a High Chromium Nickel-Based Superalloy by Extreme High-Speed Laser Metal Deposition, Opt. Laser Technol., 2021, 133, p 106504.
K. Wang, D. Du, G. Liu, Z. Pu, B. Chang and J. Ju, Microstructure and Mechanical Properties of High Chromium Nickel-Based Superalloy Fabricated by Laser Metal Deposition, Mater. Sci. Eng. A Struct., 2020, 780, p 139185.
D.Y. Lin, N.N. Zhang, B. He, G.W. Zhang, Y. Zhang and D.Y. Li, Tribological Properties of FeCoCrNiAlBx High-Entropy Alloys Coating Prepared by Laser Cladding, J. Iron Steel Res. Int., 2017, 24, p 184–189.
P. Fan and G. Zhang, Study on Process Optimization of WC-Co50 Cermet comPosite coating by Laser Cladding, Int. J Refract. Met. H., 2020, 87, p 105133.
O. Kohmoto, K. Ohya, N. Yamaguchi et al., Amorphous FeCoNi-SiB Alloys Having Zero Magnetostriction, J. Appl. Phys., 1980, 51, p 4342–4345.
S. Li, Q.W. Hu, X.Y. Zeng and S.Q. Ji, Effect of Carbon Content on the Microstructure and the Cracking Susceptibility of Fe-Based Laser-Clad Layer, Appl. Surf. Sci., 2005, 240, p 63–70.
K. Wang, D. Du, G. Liu, B. Chang, J. Ju, S. Sun and H. Fu, Microstructure and Property of Laser Clad Fe-Based Composite Layer Containing Nb and B4C Powders, J. Alloy. Compd., 2019, 802, p 373–84.
Z.L. Li, M.M. Wei, K. Xu, Z.H. Bai, W. Xue, C.F. Dong, D. Wei and X.G. Li, Microhardness and Wear Resistance of Al2O3-TiB2-TiC Ceramic Coating on Carbon Steel Fabricated by Laser Cladding, Ceram. Int., 2019, 45, p 115–121.
H. Zhang, Y. Zou, Z.D. Zou and D.T. Wu, Microstructures and Properties of Low-Chromium High Corrosion-Resistant TiC–VC Reinforced Fe-Based Laser Cladding Layer, J. Alloys Compd., 2015, 622, p 62–68.
Y.W. Yang, H.G. Fu, Y.P. Lei, K.M. Wang, L.L. Zhu and L. Jiang, Phase Diagram Calculation and Analyze on Cast High-Boron High-Speed Steel, J. Mater. Eng. Perform., 2016, 25, p 409–420.
J. Ju, Y. Ma, H. Fu, Y. Yuan, L. Zhu and L. Jiang, Phase Diagram Calculation and Experimental Research on Fe-12Cr-B-Al-Alloys, Materialwiss Werkst, 2016, 47, p 815.
X. Cheng, J. Ju, Y. Qu, C. Li and H. Fu, Microstructure and propErties of Fe–Cr–B–Al Alloy After Heat Treatment, T Indian I Metals, 2018, 71, p 2261.
J. Ju, H. Fu and Y. Lei, Effect of Al Addition on Microstructure and Properties of an Fe-B-Al Alloy, Mater. Testing, 2016, 58, p 753–762.
J. Ju, H.G. Fu, D.M. Fu, S.Z. Wei, P. Sang, Z.W. Wu, K.Z. Tang and Y.P. Lei, Effects of Cr and V Additions on the Microstructure and Properties of High-Vanadium WEAR-Resistant Alloy Steel, Ironmaking Steelmak., 2018, 45, p 1–11.
M. Bleckmann, J. Gleinig, J. Hufenbach, H. Wendrock, L. Giebeler, J. Zeisig, U. Diekmann, J. Eckert and U. Kühn, Effect of Cooling Rate on the Microstructure and Properties of FeCrVC, J. Alloy. Compd., 2015, 634, p 200–207.
J.C. Lippold and D.J. Kotecki, Welding Metallurgy and Weld Ability of Stainless Steels, Wiley, Hoboken, 2005.
C.M. Caneda, J.B. Fogagnolo, C.S. Kiminami and C.R.M. Afonso, Ultrafine Eutectic Coatings from Fe-Nb-B Powder Using Laser Cladding, Mater. Charact., 2020, 160, p 110080.
M. Fenech, M. Grech and J.C. Betts, The In-Flight Temperature Variation and Dissolution of WC Powder Particles Producing an Fe–Cr–W–C System by Direct Laser Deposition, Surf. Coat. Technol., 2012, 207, p 211–217.
D.J. Powell, R. Pilkington and D.A. Miller, The Precipitation Characteristics of 20% Cr/25% Ni-Nb Stabilised Stainless Steel, Acta Metall., 1988, 36, p 713–724.
I.A. Sustaita-Torres, S. Haro-Rodriguez, M.P. Guerrero-Mata, M.D.L. Garza, E. Valdes, F. Deschaux-Beaume and R. Colas, Aging of a Cast 35Cr–45Ni Heat Resistant Alloy, Mater. Chem. Phys., 2012, 133, p 1018–1023.
Y.Z. Lyu, Y.F. Sun and F.Y. Jing, On the Microstructure and Wear Resistance of Fe-Based Composite Coatings Processed by Plasma Cladding with B4C Injection, Ceram. Int., 2015, 41, p 10934–10939.
S.Z. Zhao, S.F. Zhou, M. Xie, X.Q. Dai, D.C. Chen and L.C. Zhang, Phase Separation and Enhanced Wear Resistance of Cu88Fe12 Immiscible Coating Prepared by Laser Cladding, J. Mater. Res. Tech., 2019, 8, p 2001–2010.
P.L. Zhang, X.P. Liu, Y.L. Lu, H. Yan, Z.S. Yu, C.G. Li and Q.H. Lu, Microstructure and Wear Behavior of Cu–Mo–Si Coatings by Laser Cladding, Appl. Surf. Sci., 2014, 311, p 709–714.
S. Ashok Kumar and D. Karabi, The Abrasive Wear Resistance of TiC and (Ti, W)C-Reinforced Fe-17Mn Austenitic Steel Matrix Composites, Tribol. Int., 2010, 43, p 944–950.
Y.Z. Liu, Y.H. Jiang, J.D. Xing, R. Zhou and J. Feng, Mechanical Properties and Electronic Structures of M23C6 (M=Fe, Cr, Mn)-Type Multicomponent Carbides, J. Alloy. Compd., 2015, 648, p 874–880.
Y.L. Feng, C.W. Yao, C. Shen, Y.Q. Feng, K. Feng and Z.G. Li, Influence of In-Situ Synthesized Carboborides on Microstructure Evolution and the Wear Resistance of Laser Clad Fe-Base Composite Ocatings, Mater. Charact., 2020, 164, p 110326.
J. Lentz, A. Rottger and W. Theisen, Mechanism of the Fe3(B, C) and Fe23(C, B)6 Solid-State Transformation in the Hypoeutectic Region of the Fe-C-B System, Acta Mater, 2016, 119, p 80–91.
A. Rottger, J. Lentz and W. Theisen, Boron-Alloyed Fe-Cr-C-B Tool Steels-Thermodynamic Calculations and Experimental Validation, Mater. Des., 2015, 88, p 420–429.
L. Li, W. Wang, L. Hu and B. Wei, First-Principle Calculations of Structural, Elastic and Thermodynamic Properties of Fe-B Compounds, Intermetallics, 2014, 46, p 211–221.
Y. Yuan and Z. Li, Analysis of Nucleation of Carbide (Cr, Fe)7C3 in the Cr3C2/Fe-CrNiBSi Composite Coating, Surf. Coat. Technol., 2013, 228, p 41–47.
S.D. Sun, D. Fabijanic, M. Annasamy, S.C. Gallo, I. Fordyce, A. Paradowska, M. Leary, M. Easton and M. Brandt, Microstructure, Absrasive Wear and Corrosion Characterization of Laser Metal Deposited Fe-30Cr-6Mo-10Ni-2.2C Alloy, Wear, 2019, 438–439, p 203070.
F.Y. Shu, B. Yang, S.Y. Dong, H.Y. Zhao, B.S. Xu, F.J. Xu, B. Liu, P. He and J.C. Feng, Effects of Fe-to-Co Ratio on Microstructure and Mechanical Properties of Laser Cladded FeCoCrBNiSi High-Entropy Alloy Coatings, Appl. Surf. Sci., 2018, 450, p 538–544.
X.H. Tang, R. Chung, C.J. Pang, D.Y. Li, B. Hinckley and K. Dolman, Microstructure of High (45 wt.%) Chromium Cast Irons and Their Resistances to Wear and Corrosion, Wear, 2011, 271, p 1426–1431.
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Gu, J., Li, D., Liu, S. et al. Investigation on Microstructure and Dry Sliding Wear Behavior of a Novel Fe-Cr-B-C-Al-Si-Mn Composite Coatings on 2Cr13 Steel by Laser Cladding. J. of Materi Eng and Perform 31, 2381–2390 (2022). https://doi.org/10.1007/s11665-021-06325-8
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DOI: https://doi.org/10.1007/s11665-021-06325-8