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Corrosion Investigation of Zinc–Aluminum Alloy (ZA-27) Matrix Reinforced with In Situ Synthesized Titanium Carbide Particle Composites

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Abstract

ZA-27 alloy matrix composites comprised of different volume fractions of TiC particles as reinforcement phase were synthesized by in situ technique. Microstructural, hardness and electrochemical analysis were performed on these samples along with the base ZA-27 alloy to assess any beneficial effect of making the composites over the base alloy. It was observed that hardness increases in composites as compared to the base alloy. However, hardness of the composite reduces on increasing the reinforcement percentage. Corrosion behavior was investigated by using Tafel and EIS plots in 3.5 wt.% NaCl solution at room temperature for all the samples. The results showed increase in corrosion resistance for composites than that of base alloy. However, ZA27 + 5%TiC composite showed better results as compared to that of ZA27 + 10%TiC composite. The decreased property of ZA27 + 10%TiC composite is because of the agglomeration of particles and also by the formation of galvanic cell.

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References

  1. E.J. Kubel, Expanding Horizons for ZA alloys, Adv. Mater. Processes, 1987, 132, p 51–57

    Google Scholar 

  2. E. Gervais, R.J. Barnhurst, and C.A. Loong, An Analysis of Selected Properties of ZA Alloys, J. Met., 1985, 11, p 43–47

    Google Scholar 

  3. P.A. Schweitzer, Fundamentals of Corrosion, CRC Press, New York, 2010, p 112

    Google Scholar 

  4. ASM Handbook, vol. 15, Casting, Materials Park, Ohio, ASM International, 2008, p 1734–1753.

  5. C.S. Ramesh, S. Pramod, and R. Keshavamurthy, A Study on Microstructure and Mechanical Properties of Al6061-TiB2 In-Situ Composites, Mater. Sci. Eng., A, 2011, 528, p 4125–4132

    Article  Google Scholar 

  6. B. Bobic, S. Mitrovic, M. Babic, and I. Bobic, Corrosion of Aluminum and Zinc Aluminum Alloy Based Metal Matrix Composite, Tribol. Ind., 2009, 31(3–4), p 44–53

    Google Scholar 

  7. R. Lyon, High Strength Zinc Alloys for Engineering Applications in the Motor Car, Met. Mater., 1985, 1, p 55–57

    Google Scholar 

  8. S. Sharma, M. Krishna, and D. Bhattacharyya, Dry Sliding Wear Behaviour of Fly Ash Reinforced ZA-27 Alloy Based MMC, Int. J. Mod. Phys. B, 2006, 20, p 4703–4708

    Article  Google Scholar 

  9. O.P. Modi, S.K. Rathod, B.K. Prasad, A.K. Jha, and G. Dixit, The Influence of Alumina Particle Dispersion and Test Parameters on Dry Sliding Wear Behavior of Zinc-Based Alloy, Tribol. Int., 2007, 40, p 1137–1146

    Article  Google Scholar 

  10. M. Babic, S. Mitrovic, and B. Jeremic, The Influence of Heat Treatment on the Sliding Wear Behavior of a ZA-27 Alloy, Tribol. Int., 2010, 43(1), p 16–21

    Article  Google Scholar 

  11. B.K. Prasad, Investigation Into Sliding Wear Performance of Zinc-Based Alloy Reinforced with SiC Particles in Dry and Lubricated Conditions, Wear, 2007, 262, p 262–272

    Article  Google Scholar 

  12. O.P. Modi, B.K. Prasad, and A.K. Jha, Influence of Alumina Dispersoid and Test Parameters on Erosive Wear Behavior of a Cast Zinc–Aluminum Alloy, Wear, 2006, 260, p 895–902

    Article  Google Scholar 

  13. K.H.W. Seah, S.C. Sharma, and B.M. Girish, Corrosion Characteristics of ZA-27 Graphite Particulate Composites, Corros. Sci., 1997, 39, p 1–7

    Article  Google Scholar 

  14. G. Ranganath, S. Sharma, and M. Krishna, Dry Sliding Wear of Garnet Reinforced Zinc/Aluminum Metal Matrix Composites, Wear, 2001, 251, p 1408–1413

    Article  Google Scholar 

  15. S. Sharma, D. Somashekar, and B. Satish, A Note on the Corrosion Characterisation of ZA-27/Zircon Particulates Composites in Acidic Medium, J. Mater. Process. Technol., 2001, 118(1–3), p 62–64

    Article  Google Scholar 

  16. M. Almomani, M.T. Hayajneh, and M. Draidi, Corrosion Investigation of Zinc–Aluminum Alloy Matrix (ZA-27) Reinforced with Alumina (Al2O3) and Fly Ash, Part. Sci. Technol., 2017, 35(4), p 439–447

    Article  Google Scholar 

  17. B. Bobic, A. Vencl, M. Babic, S. Mitrovic, and I. Bobic, The influence of corrosion on the microstructure of thermally treated ZA 27/SiCP composites, in 13th International Conference on Tribology, 2013, p 106–112.

  18. B. Yang, G. Chen, and J. Zhang, Effect of Ti/C Additions on the Formation of Al3Ti of In Situ TiC/Al Composites, Mater. Des., 2001, 22, p 645–650

    Article  Google Scholar 

  19. Q.C. Jiang, X.L. Li, and H.Y. Wang, Fabrication of TiC Particulate Reinforced Magnesium Matrix Composites, Scr. Mater., 2003, 48, p 713–717

    Article  Google Scholar 

  20. G.S.P. Kumar, R. Keshavamurthy, C.S. Ramesh, and B.H. Channabasappa, Tribological Characteristics of Al6061-TiC Composite Synthesized by In-situ Technique, Appl. Mech. Mater., 2015, 787, p 653–657

    Article  Google Scholar 

  21. R.N. Rai, A.K.P. Rao, G.L. Dutta, and M. Chakraborty, Forming Behaviour of Al-TiC In-Situ Composites, Mater. Sci. Forum, 2013, 765, p 418–422

    Article  Google Scholar 

  22. G.S.P. Kumar, P.G. Koppad, R. Keshavamurthy, and M. Alipour, Microstructure and Mechanical Behaviour of In Situ Fabricated AA6061-TiC Metal Matrix Composites, Arch. Civ. Mech. Eng., 2017, 17, p 535–544

    Article  Google Scholar 

  23. S.A. Sajjadi, H.R. Ezatpour, and M.T. Parizi, Comparison of Microstructure and Mechanical Properties of A356 Aluminum Alloy/Al2O3 Composites Fabricated by Stir and Compo-Casting Processes, Mater. Des., 2012, 34, p 106–111

    Article  Google Scholar 

  24. T.P.D. Rajan, R.M. Pillai, B.C. Pai, K.G. Satyanarayana, and P.K. Rohatgi, Fabrication and Characterisation of Al-7Si-0.35 Mg/Fly Ash Metal Matrix Composites Processed by Different Stir Casting Routes, Compos. Sci. Technol., 2007, 67, p 3369–3377

    Article  Google Scholar 

  25. V. Shrivastava, A. Singh, and I.B. Singh, Effect of Sol–Gel Prepared Nanoalumina Reinforcement Content on the Corrosion Resistances of Al 6061-Al2O3 Nanocomposite in 3.5% NaCl Solution, Mater. Corros., 2017, 68, p 1099–1106

    Article  Google Scholar 

  26. I.B. Singh, D.P. Mandal, M. Singh, and S. Das, Influence of SiC Particles Addition on the Corrosion Behavior of 2014 Al-Cu Alloy in 3.5% NaCl Solution, Corros. Sci., 2009, 51, p 234–341

    Article  Google Scholar 

  27. V. Shrivastava, S. Dubey, G.K. Gupta, and I.B. Singh, Influence of Alpha Nanoalumina Reinforcement Content on the Microstructure, Mechanical and Corrosion Properties of Al6061-Al2O3 Composite, J. Mater. Eng. Perform., 2017, 26, p 4424–4433

    Article  Google Scholar 

  28. B. Bobic, J. Bajat, Z. Acimovic-pavlovic, I. Bobic, and B. Jegdic, Corrosion Behaviour of Thixoformed And Heat-Treated ZA27 Alloys in NaCl Solution, Trans. Nonferrous Met. Soc. China, 2013, 23, p 931–941

    Article  Google Scholar 

  29. E. Palma, J.M. Puente, and M. Morcillo, The Atmospheric Corrosion Mechanism of 55%Al-Zn Coating on Steel, Corros. Sci., 1998, 40, p 61–68

    Article  Google Scholar 

  30. D. Persson, D. Thierry, and N. Lebozec, Corrosion Product Formation on Zn55Al Coated Steel Upon Exposure in a Marine Atmosphere, Corros. Sci., 2011, 53, p 720–726

    Article  Google Scholar 

  31. B. Bobic, J. Bajat, Z. Acimovic-pavlovic, M. Rakin, and I. Bobic, The Effect of T4 Heat Treatment on the Microstructure and Corrosion Behaviour of Zn27Al1.5Cu0.02 Mg Alloy, Corros. Sci., 2011, 53, p 409–417

    Article  Google Scholar 

  32. M. Mouanga, L. Ricq, J. Douglade, and P. Berçot, Corrosion Behaviour of Zinc Deposits Obtained Under Pulse Current Electrodeposition: Effects of Coumarin as Additive, Corros. Sci., 2009, 51, p 690–698

    Article  Google Scholar 

  33. H.H. Hassan, Perchlorate and Oxygen Reduction During Zn Corrosion in a Neutral Medium, Electrochim. Acta, 2006, 51, p 5966–5972

    Article  Google Scholar 

  34. X.G. Zhang, Corrosion and Electrochemistry of Zinc, Plenum Press, New York, 1996

    Book  Google Scholar 

  35. A. El-Feki and G.W. Walter, Corrosion Rate Measurements Under Conditions of Mixed Charge Transfer Plus Diffusion Control Including the Cathodic Metal Ion Deposition Partial Reaction, Corros. Sci., 2000, 42, p 1055–1070

    Article  Google Scholar 

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Acknowledgments

The authors are thankful to the Director CSIR-AMPRI, Bhopal, India, for providing necessary means to carry out the present work. Two authors (RD and VS) also acknowledge CSIR-HRDG, India, for providing financial support.

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The authors declare that they have no conflict of interest.

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Correspondence to Vikas Shrivastava.

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David, R., Shrivastava, V., Dasgupta, R. et al. Corrosion Investigation of Zinc–Aluminum Alloy (ZA-27) Matrix Reinforced with In Situ Synthesized Titanium Carbide Particle Composites. J. of Materi Eng and Perform 28, 2356–2364 (2019). https://doi.org/10.1007/s11665-019-03992-6

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  • DOI: https://doi.org/10.1007/s11665-019-03992-6

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