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Diffusion Bonding of TiAl to Ti6Al4V Using Nanolayers

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Abstract

Microstructural characterization of TiAl to Ti6Al4V dissimilar diffusion bonds assisted by reactive Ni/Al nanolayers was performed in this study. The nanolayers (alternated Al and Ni) were deposited onto the base material surfaces. Diffusion bonding was performed at 700 and 800 °C under pressures from 5 to 40 MPa and dwell times between 60 and 180 min. Microstructural characterization was performed using high-resolution transmission and scanning electron microscopies. The observations revealed that dissimilar TiAl to Ti6Al4V joints assisted by Ni/Al reactive nanolayers can be obtained successfully at 800 °C during 60 min using a pressure of 20 MPa. The bond interface is thin (less than 10 µm) and is mainly composed of NiAl grains. Thin layers of Al-Ni-Ti intermetallic compounds were formed adjacent to the base materials.

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References

  1. D.M. Dimiduk, Gamma Titanium Aluminide Alloys—An Assessment Within the Competition of Aerospace Structural Materials, Mater. Sci. Eng. A, 1999, 263(2), p 281–288

    Article  Google Scholar 

  2. F. Appel, U. Brossmann, U. Christoph, S. Eggert, P. Janschek, U. Lorenz, J. Mullauer, M. Oehring, and J.D.H. Paul, Recent Progress in the Development of Gamma Titanium Aluminide Alloys, Adv. Eng. Mater., 2000, 2(11), p 699–720

    Article  Google Scholar 

  3. H. Clemens and H. Kestler, Processing and Application of Intermetallic γ-TiAl-Based Alloys, Adv. Eng. Mater., 2000, 2, p 551–570

    Article  CAS  Google Scholar 

  4. F.H. Froes, C. Suryanarayana, and D. Eliezer, Synthesis, Properties and Applications of Titanium Aluminides, J. Mater. Sci., 1992, 27(19), p 5113–5140

    Article  CAS  Google Scholar 

  5. J. Cao, J. Qi, X. Song, and J. Feng, Welding and Joining of Titanium Aluminides, Materials, 2014, 7(7), p 4930–4962

    Article  Google Scholar 

  6. W. Glatz and H. Clemens, Diffusion Bonding of Intermetallic Ti-47Al-2Cr-0.2Si Sheet Material and Mechanical Properties of Joints at Room Temperature and Elevated Temperatures, Intermetallics, 1997, 5(6), p 415–423

    Article  CAS  Google Scholar 

  7. G. Çam and M. Koçak, Diffusion Bonding of Investment Cast γ-TiAl, J. Mater. Sci., 1999, 34, p 3345–3354

    Article  Google Scholar 

  8. G. Çam, H. Clemens, R. Gerling, and M. Koçak, Diffusion Bonding of γ-TiAl Sheets, Intermetallics, 1999, 7(9), p 1025–1031

    Article  Google Scholar 

  9. G. Çam, G. Ipekoglu, K.H. Bohm, and M. Koçak, Investigation into the Microstructure and Mechanical Properties of Diffusion Bonded TiAl Alloys, J. Mater. Sci., 2006, 41(16), p 5273–5282

    Article  Google Scholar 

  10. W. Glatz and H. Clemens, Diffusion Bonding of Intermetallic Ti-47Al-2Cr-0.2Si Sheet Material and Mechanical Properties of Joints at Room Temperature and Elevated Temperatures, Intermetallics, 1997, 5, p 415–423

    Article  CAS  Google Scholar 

  11. M. Holmquist, V. Recina, J. Ockborn, B. Pettersson, and E. Zumalde, Hot Isostatic Diffusion Bonding of Titanium Alloy Ti-6Al-4V to Gamma Titanium Aluminide IHI, Alloy 01A, Scr. Mater., 1998, 39, p 1101–1106

    Article  CAS  Google Scholar 

  12. G. Çam, U. Ozdemir, V. Ventzke, and M. Koçak, Microstructural and Mechanical Characterization of Diffusion Bonded Hybrid Joints, J. Mater. Sci., 2008, 43, p 3491–3499

    Article  Google Scholar 

  13. Z. Xue, Q. Yang, L. Gu, X. Hao, Y. Ren, and Y. Geng, Diffusion Bonding of TiAl Based Alloy to Ti-6Al-4V Alloy Using Amorphous Interlayer, Mater. Wiss. u Werkstofftech., 2015, 46, p 40–46

    Article  CAS  Google Scholar 

  14. L. Duarte, A.S. Ramos, M.F. Vieira, F. Viana, M.T. Vieira, and M. Koçak, Solid-State Diffusion Bonding of Gamma-TiAl Alloys Using Ti/Al Thin Films as Interlayers, Intermetallics, 2006, 14(10–11), p 1151–1156

    Article  CAS  Google Scholar 

  15. A.I. Ustinov, YuV Falchenko, A.Ya. Ishchenko, G.K. Kharchenko, Y.V. Melnichenko, and A.N. Muraveynik, Diffusion Bonding of Y-TiAl Based Alloys Through Nano-layered Foil of Ti/Al System, Intermetallics, 2008, 16, p 1043–1045

    Article  CAS  Google Scholar 

  16. J. Cao, J.C. Feng, and Z.R. Li, Microstructure and Fracture Properties of Reaction-Assisted Diffusion Bonding of TiAl Intermetallic with Al/Ni Multilayer Foils, J. Alloys Compd., 2008, 466, p 363–367

    Article  CAS  Google Scholar 

  17. S. Simões, F. Viana, M. Koçak, A.S. Ramos, M.T. Vieira, and M.F. Vieira, Diffusion Bonding of TiAl Using Reactive Ni/Al Nanolayers and Ti and Ni Foils, J. Mater. Sci., 2011, 15, p 202–207

    Google Scholar 

  18. A.S. Ramos, M.T. Vieira, S. Simões, F. Viana, and M.F. Vieira, Reaction-Assisted Diffusion Bonding of Advanced Materials, Defect Diffus. Forum., 2010, 297–301, p 972–977

    Article  Google Scholar 

  19. J. Cao, X.G. Song, L.Z. Wu, J.L. Qi, and J.C. Feng, Characterization of Al/Ni Multilayers and Their Application in Diffusion Bonding of TiAl to TiC Cermet, Thin Solid Films, 2012, 520, p 3528–3531

    Article  CAS  Google Scholar 

  20. S. Simões, F. Viana, M. Koçak, A.S. Ramos, M.T. Vieira, and M.F. Vieira, Microstructure of Reaction Zone Formed During Diffusion Bonding of TiAl with Ni/Al Multilayer, J. Mater. Eng. Perform., 2012, 21, p 678–682

    Article  Google Scholar 

  21. S. Simões, F. Viana, and M.F. Vieira, Reactive Commercial Ni/Al Nanolayers for Joining Lightweight Alloys, J. Mater. Eng. Perform., 2014, 23, p 1536–1543

    Article  Google Scholar 

  22. S. Simões, F. Viana, A.S. Ramos, M.T. Vieira, and M.F. Vieira, TEM and HRTEM Characterization of TiAl Difffusion Bonds Using Ni/Al Nanolayers, Microsc. Microanal., 2015, 21, p 132–139

    Article  Google Scholar 

  23. S. Simões, F. Viana, A.S. Ramos, M.T. Vieira, and M.F. Vieira, Reaction-Assisted Diffusion Bonding of TiAl Alloy to Steel, Mater. Chem. Phys., 2016, 171, p 73–82

    Article  Google Scholar 

  24. S. Simões, F. Viana, A.S. Ramos, M.T. Vieira, and M.F. Vieira, Microstructural Characterization of Diffusion Bonds Assisted by Ni/Ti Nanolayers, J. Mater. Eng. Perform., 2016, 25, p 3245–3251

    Article  Google Scholar 

  25. S. Simões, F. Viana, A.S. Ramos, M.T. Vieira, and M.F. Vieira, Joining of TiAl to Steel by Diffusion Bonding with Ni/Ti Reactive Multilayer, Metals, 2016, 6(5), p 96

    Article  Google Scholar 

  26. T.C. Isabel and V.P. Dravid, Resolution and Sensitivity of Electron Backscattered Diffraction in a Cold Field Emission Gun SEM, Ultramicroscopy, 1997, 67(1–4), p 59–68

    Article  Google Scholar 

  27. P. Villars, A. Prince, and H. Okamoto, Handbook of Ternary Alloy Phase Diagram, ASM International, Materials Park, 1995

    Google Scholar 

  28. P. He and D. Liu, Mechanism of Forming Interfacial Intermetallic Compounds at Interface for Solid State Diffusion Bonding of Dissimilar Materials, Mater. Sci. Eng. A, 2006, 437, p 430–435

    Article  Google Scholar 

  29. C. Herzig and S. Divinski, Bulk and grain boundary diffusion in intermetallic compounds, Diffusion Processes in Advanced Technological Materials, D. Gupta and W. Andrew, Ed., Publishing, Norwich, 2005, p 173–238

    Google Scholar 

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Acknowledgments

This research is sponsored by FEDER funds through the program COMPETE—Programa Operacional Factores de Competitividade—and by national funds through FCT—Fundação para a Ciência e a Tecnologia—, under the project UID/EMS/00285/2013. The authors are grateful to CEMUP—Centro de Materiais da Universidade do Porto for expert assistance with SEM.

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Correspondence to Sónia Simões.

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Simões, S., Viana, F., Ramos, A.S. et al. Diffusion Bonding of TiAl to Ti6Al4V Using Nanolayers. J. of Materi Eng and Perform 27, 5064–5068 (2018). https://doi.org/10.1007/s11665-018-3207-z

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  • DOI: https://doi.org/10.1007/s11665-018-3207-z

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