Abstract
Corrosion behavior of new superalloy was studied in industrial environment at different temperatures by using various selected electrochemical techniques. The results revealed that the alloy is able to form protective oxide scale on its surface at higher temperatures and consequently the corrosion rate is low. The new alloy is found to degrade due to pitting corrosion at 40 and 50 °C and general corrosion at 25 °C. The scanning electron microscope results confirmed the electrochemical results. The energy-dispersive spectroscopy results confirmed the presence of oxides of nickel and alloying elements present in the superalloy. Based on the results obtained with different techniques, the alloy is recommended to fabricate different components for industrial applications with suitable protective coatings.
Similar content being viewed by others
References
I. Gurrappa, I.V.S. Yashwanth, and A.K. Gogia, The Behaviour of Superalloys in Marine Gas Turbine Engine Conditions, J. Surf. Eng. Mater. Adv. Technol., 2011, 1, p 45
K. Fulton, Gas Turbine World, June 1994, p 52–56.
M. Konter and M. Thumann, Materials and Manufacturing of Advanced Industrial Gas Turbine Components, J. Mater. Proces. Technol., 2001, 117, p 386
P. Caron and T. Khan, Evolution of Ni-Base Superalloys for Single Crystal Gas Turbine Blade Applications, Aerosp. Sci. Technol., 1999, 3, p 513
R. Hashizume, A. Yoshinari, T. Kiyono,Y. Murata, and M. Morinaga, Development of Ni-Based Single Crystal Superalloys for Power Generation Gas Turbines, Superalloys 2004, p 53–62
I.V.S. Yashwanth, I. Gurrappa, and H. Murakami, Oxidation Behavior of a Newly Developed Superalloy, J. Surf. Eng. Mater. Adv. Technol., 2011, 3, p 130
C. Gaona-Tiburcio, L.M.R. Anguilar, P.Z. Robledo, F.E. Lopez, J.A.C. Mirmonates, D. Nieves-Mendoza, E. Castillo-Gonzalez, and F. Almeraya-Calderon, Electrochemical Noise Analysis of Nickel Based Superalloys in Acid Solutions, Intl. J. Electrochem. Sci., 2014, 9, p 523
M.A. Amin, N. El-Bagoury, M. Saracoglu, and M. Ramadan, Electrochemical and Corrosion Behaviour of Cast Re-containing Inconel 718 Alloys in Sulphuric Acid Solutions and the Effect of Cl−, Int. J. Electrochem. Sci., 2014, 9, p 5352
I. Gurrappa, Hot Corrosion Behavior of CM 247 LC Alloy in Na2SO4 and NaCl Environments, Oxid. Metals, 1999, 51, p 353
I. Gurrappa, Identification of Hot Corrosion Resistant MCrAlY Based Bond Coatings for Gas Turbine Engine Applications, Surf. Coat. Technol., 2001, 139, p 272
I. Gurrappa, I.V.S. Yashwanth, and A.K. Gogia, The selection of materials for marine gas turbines, Gas Turbines ISBN:979-953-307-816-7, Volkov Konstarton (Editor), INTECH Publishers, 2012, p 51–70
I. Gurrappa and I.V.S. Yashwanth, Design and Development of Smart Coatings for Gas Turbines. “Gas Turbines”, ed. by I. Gurrappa. ISBN: 978-953-307-146-6, SCIYO Publishers, 2010, p 65–78
C.J. Wang and J.H. Lin, The Oxidation of MAR M 247 Superalloy with Na2SO4 Coating, Chem. Phys., 2002, 76, p 123
J.R. Nicholls, N.J. Simms, W.Y. Chan, and H.E. Evans, Smart coatings-Concept and Practice, Surf. Coat. Technol., 2001, 149, p 236
T. Nickechi and A. Alfantazi, Electrochemical Corrosion Behavior of Incoloy 800 in Sulphate Solutions Containing Hydrogen Peroxide, Corr. Sci., 2010, 52, p 4035
N.K. Aylikci, E. Tirabsoglu, I.H. Karahan, V. Aylikci, M. Eskil, and E. Cengiz, Alloying Effect on KX-Ray Intensity Ratios, KX-Ray Production Cross-Sections and Radiative Augur Ratios in Superalloys Constitute from Al, Ni and Mo Elements, Chem. Phys., 2010, 377, p 100
T. Chen, H. John, J. Xu, Q. Lu, J. Hawk, and X. Liu, Influence of Surface Modifications on Pitting Corrosion Behavior of Nickel Base Superalloy 718, Corr. Sci., 2013, 77, p 230
W. Batista, A.M.T. Louvisse, O.R. Mattos, and L. Sathler, The Electrochemical Behavior of INCOLOY 800 and AISI, 304 Steel in Solutions that are Similar to Those Within Occluded Corrosion Cells, Corros. Sci., 1988, 28, p 759
I. Gurrappa, I.V.S. Yashwanth, I. Mounika, H. Murakami, and S. Kuroda, “The importance of hot corrosion of Superalloys and their effective Protection for Enhanced Efficiency of Gas Turbine Engines. Gas Turbines, Materials, Modelling and Performance”, ed. by I. Gurrappa. ISBN:978-953-51-1743-8, INTECH Publishers, 2015, p 55–102
H.J. Jang, C.J. Park, and H.S. Kwon, Photoelectrochemical Analysis on the Passive Film Formed on Ni in pH 8.5 Buffer Solution, Electrochim. Acta, 2005, 50, p 3503
N. Pineau, C. Minot, V. Maurice, and P. Marcus, Density Functional Theory Study of the Interaction of Cl- with Passivated Nickel Surfaces, Electrochem. Solid-State Lett., 2003, 6, p B47
A. Bouzoubaa, B. Diawara, V. Maurice, C. Minot, and P. Marcus, Ab Initio Modelling of Localised Corrosion: Study of the Role of Surface Steps in the Interaction of Chlorides with Passivated Nickel Surfaces, Corros. Sci., 2009, 51, p 2174
F.R. Caliari, E.F. da Rosa, M.A. Silva, and D.A.P. Reis, Analysis of Pitting Corrosion on an Inconel 718 Alloy Submitted to Aging Heat Treatment, Technol. Metal Mater. Miner., 2014, 11, p 189
G.S. Frankel, Pitting Corrosion of Metals: A Review of the Critical Factors, J. Electrochem. Soc., 1998, 145, p 2186
K.V. Rybalka, L.A. Beketaeva, and A.D. Davydov, Effect of Self-Passivation on the Electrochemical and Corrosion Behavior of Alloy C-22 in NaCl Solution, Corros. Sci., 2012, 54, p 161
D.D. Macdonald, Theoretical Investigation of the Evolution of the Passive State on Alloy 22 in Acidified, Saturated Brine Under Open Circuit Conditions, Electrochim. Acta, 2011, 56, p 7411
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Yashwanth, I.V.S., Gurrappa, I. Corrosion Characteristics of New Superalloy Under Industrial Environmental Conditions. J. of Materi Eng and Perform 26, 6057–6063 (2017). https://doi.org/10.1007/s11665-017-3042-7
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-017-3042-7