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Corrosion Characteristics of New Superalloy Under Industrial Environmental Conditions

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Abstract

Corrosion behavior of new superalloy was studied in industrial environment at different temperatures by using various selected electrochemical techniques. The results revealed that the alloy is able to form protective oxide scale on its surface at higher temperatures and consequently the corrosion rate is low. The new alloy is found to degrade due to pitting corrosion at 40 and 50 °C and general corrosion at 25 °C. The scanning electron microscope results confirmed the electrochemical results. The energy-dispersive spectroscopy results confirmed the presence of oxides of nickel and alloying elements present in the superalloy. Based on the results obtained with different techniques, the alloy is recommended to fabricate different components for industrial applications with suitable protective coatings.

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References

  1. I. Gurrappa, I.V.S. Yashwanth, and A.K. Gogia, The Behaviour of Superalloys in Marine Gas Turbine Engine Conditions, J. Surf. Eng. Mater. Adv. Technol., 2011, 1, p 45

    Google Scholar 

  2. K. Fulton, Gas Turbine World, June 1994, p 52–56.

  3. M. Konter and M. Thumann, Materials and Manufacturing of Advanced Industrial Gas Turbine Components, J. Mater. Proces. Technol., 2001, 117, p 386

    Article  Google Scholar 

  4. P. Caron and T. Khan, Evolution of Ni-Base Superalloys for Single Crystal Gas Turbine Blade Applications, Aerosp. Sci. Technol., 1999, 3, p 513

    Article  Google Scholar 

  5. R. Hashizume, A. Yoshinari, T. Kiyono,Y. Murata, and M. Morinaga, Development of Ni-Based Single Crystal Superalloys for Power Generation Gas Turbines, Superalloys 2004, p 53–62

  6. I.V.S. Yashwanth, I. Gurrappa, and H. Murakami, Oxidation Behavior of a Newly Developed Superalloy, J. Surf. Eng. Mater. Adv. Technol., 2011, 3, p 130

    Google Scholar 

  7. C. Gaona-Tiburcio, L.M.R. Anguilar, P.Z. Robledo, F.E. Lopez, J.A.C. Mirmonates, D. Nieves-Mendoza, E. Castillo-Gonzalez, and F. Almeraya-Calderon, Electrochemical Noise Analysis of Nickel Based Superalloys in Acid Solutions, Intl. J. Electrochem. Sci., 2014, 9, p 523

    Google Scholar 

  8. M.A. Amin, N. El-Bagoury, M. Saracoglu, and M. Ramadan, Electrochemical and Corrosion Behaviour of Cast Re-containing Inconel 718 Alloys in Sulphuric Acid Solutions and the Effect of Cl, Int. J. Electrochem. Sci., 2014, 9, p 5352

    Google Scholar 

  9. I. Gurrappa, Hot Corrosion Behavior of CM 247 LC Alloy in Na2SO4 and NaCl Environments, Oxid. Metals, 1999, 51, p 353

    Article  Google Scholar 

  10. I. Gurrappa, Identification of Hot Corrosion Resistant MCrAlY Based Bond Coatings for Gas Turbine Engine Applications, Surf. Coat. Technol., 2001, 139, p 272

    Article  Google Scholar 

  11. I. Gurrappa, I.V.S. Yashwanth, and A.K. Gogia, The selection of materials for marine gas turbines, Gas Turbines ISBN:979-953-307-816-7, Volkov Konstarton (Editor), INTECH Publishers, 2012, p 51–70

  12. I. Gurrappa and I.V.S. Yashwanth, Design and Development of Smart Coatings for Gas Turbines. “Gas Turbines”, ed. by I. Gurrappa. ISBN: 978-953-307-146-6, SCIYO Publishers, 2010, p 65–78

  13. C.J. Wang and J.H. Lin, The Oxidation of MAR M 247 Superalloy with Na2SO4 Coating, Chem. Phys., 2002, 76, p 123

    Google Scholar 

  14. J.R. Nicholls, N.J. Simms, W.Y. Chan, and H.E. Evans, Smart coatings-Concept and Practice, Surf. Coat. Technol., 2001, 149, p 236

    Article  Google Scholar 

  15. T. Nickechi and A. Alfantazi, Electrochemical Corrosion Behavior of Incoloy 800 in Sulphate Solutions Containing Hydrogen Peroxide, Corr. Sci., 2010, 52, p 4035

    Article  Google Scholar 

  16. N.K. Aylikci, E. Tirabsoglu, I.H. Karahan, V. Aylikci, M. Eskil, and E. Cengiz, Alloying Effect on KX-Ray Intensity Ratios, KX-Ray Production Cross-Sections and Radiative Augur Ratios in Superalloys Constitute from Al, Ni and Mo Elements, Chem. Phys., 2010, 377, p 100

    Article  Google Scholar 

  17. T. Chen, H. John, J. Xu, Q. Lu, J. Hawk, and X. Liu, Influence of Surface Modifications on Pitting Corrosion Behavior of Nickel Base Superalloy 718, Corr. Sci., 2013, 77, p 230

    Article  Google Scholar 

  18. W. Batista, A.M.T. Louvisse, O.R. Mattos, and L. Sathler, The Electrochemical Behavior of INCOLOY 800 and AISI, 304 Steel in Solutions that are Similar to Those Within Occluded Corrosion Cells, Corros. Sci., 1988, 28, p 759

    Article  Google Scholar 

  19. I. Gurrappa, I.V.S. Yashwanth, I. Mounika, H. Murakami, and S. Kuroda, “The importance of hot corrosion of Superalloys and their effective Protection for Enhanced Efficiency of Gas Turbine Engines. Gas Turbines, Materials, Modelling and Performance”, ed. by I. Gurrappa. ISBN:978-953-51-1743-8, INTECH Publishers, 2015, p 55–102

  20. H.J. Jang, C.J. Park, and H.S. Kwon, Photoelectrochemical Analysis on the Passive Film Formed on Ni in pH 8.5 Buffer Solution, Electrochim. Acta, 2005, 50, p 3503

    Article  Google Scholar 

  21. N. Pineau, C. Minot, V. Maurice, and P. Marcus, Density Functional Theory Study of the Interaction of Cl- with Passivated Nickel Surfaces, Electrochem. Solid-State Lett., 2003, 6, p B47

    Article  Google Scholar 

  22. A. Bouzoubaa, B. Diawara, V. Maurice, C. Minot, and P. Marcus, Ab Initio Modelling of Localised Corrosion: Study of the Role of Surface Steps in the Interaction of Chlorides with Passivated Nickel Surfaces, Corros. Sci., 2009, 51, p 2174

    Article  Google Scholar 

  23. F.R. Caliari, E.F. da Rosa, M.A. Silva, and D.A.P. Reis, Analysis of Pitting Corrosion on an Inconel 718 Alloy Submitted to Aging Heat Treatment, Technol. Metal Mater. Miner., 2014, 11, p 189

    Article  Google Scholar 

  24. G.S. Frankel, Pitting Corrosion of Metals: A Review of the Critical Factors, J. Electrochem. Soc., 1998, 145, p 2186

    Article  Google Scholar 

  25. K.V. Rybalka, L.A. Beketaeva, and A.D. Davydov, Effect of Self-Passivation on the Electrochemical and Corrosion Behavior of Alloy C-22 in NaCl Solution, Corros. Sci., 2012, 54, p 161

    Article  Google Scholar 

  26. D.D. Macdonald, Theoretical Investigation of the Evolution of the Passive State on Alloy 22 in Acidified, Saturated Brine Under Open Circuit Conditions, Electrochim. Acta, 2011, 56, p 7411

    Article  Google Scholar 

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Yashwanth, I.V.S., Gurrappa, I. Corrosion Characteristics of New Superalloy Under Industrial Environmental Conditions. J. of Materi Eng and Perform 26, 6057–6063 (2017). https://doi.org/10.1007/s11665-017-3042-7

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  • DOI: https://doi.org/10.1007/s11665-017-3042-7

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