Abstract
Corrosion behavior of 18Cr ferritic steel with and without yttria produced by high-energy milling followed by hot extrusion was studied in 3.5% NaCl solution using electrochemical and immersion techniques. The cyclic polarization study showed that pitting corrosion is predominant in all the materials. The pitting rate is higher in yttria dispersed steels and also increases with milling time. Impedance analysis revealed the formation of better corrosion resistance film on the surface of the steel without yttria. Potentiodynamic polarization studies indicated that the corrosion rate decreased up to 48 h of exposure time and increased beyond 48 h. The increase in corrosion rate beyond 48 h is due to the porous passive film. The corrosion behavior of all the materials in immersion studies followed the same trend as observed in electrochemical studies. Even though the corrosion rate of yttria dispersed 18Cr ferritic steel is less than that of the base material, the difference is marginal. The presence of dispersoids appears to promote nucleation of pits when compared to the steel without the dispersoids.
Similar content being viewed by others
References
S.J. Zinkle and J.T. Busby, Structural Materials for Fission & Fusion Energy, Mater. Today, 2009, 12, p 12–19
K.L. Murty and I. Charit, Structural Materials for Gen-IV Nuclear Reactors: Challenges and Opportunities, J. Nucl. Mater., 2008, 383, p 189–195
A. Alamo, V. Lambard, X. Averty, and M.H. Mathon, Assessment of ODS-14%Cr Ferritic Alloy for High Temperature Applications, J. Nucl. Mater., 2004, 329–333, p 333–337
G.R. Odette, M.J. Alinger, and B.D. Wirth, Recent Developments in Irradiation-Resistant Steels, Annu. Rev. Mater. Res., 2008, 38, p 471–503
S. Ukai and M. Fujiwara, Perspective of ODS Alloys Application in Nuclear Environments, J. Nucl. Mater., 2002, 307–311, p 749–757
S. Ukai, Oxide Dispersion Strengthened Steels, Comp. Nucl. Mater., 2012, 4, p 241–271
M.K. Miller, D.T. Hoelzer, E.A. Kenik, and K.F. Russell, Stability of Ferritic MA/ODS Alloys at High Temperatures, Intermetallics, 2005, 13, p 387–392
R.L. Klueh, J.P. Shingledecker, R.W. Swindeman, and D.T. Hoelzer, Oxide Dispersion-Strengthened Steels: A Comparison of Some Commercial and Experimental Alloys, J. Nucl. Mater., 2005, 341, p 103–114
H.S. Cho, A. Kimura, S. Ukai, and M. Fujiwara, Corrosion Properties of Oxide Dispersion Strengthened Steels in Super-Critical Water Environment, J. Nucl. Mater., 2004, 329–333, p 387–391
A. Kimura, H.S. Cho, N. Toda, R. Kasada, K. Yutani, H. Kishimoto, N. Iwata, S. Ukai, and M. Fujiwara, High Burn Up Fuel Cladding Materials R&D for Advanced Nuclear Systems: Nano-Sized Oxide Dispersion Strengthening Steels, J. Nucl. Sci. Technol., 2007, 44, p 323–328
T. Kaito, T. Narita, S. Ukai, and Y. Matsuda, High Temperature Oxidation Behavior of ODS Steels, J. Nucl. Mater., 2004, 329–333, p 1388–1392
J.H. Kim, K.M. Kim, T.S. Byun, D.W. Lee, and C.H. Park, High Temperature Oxidation Behavior of Nano-structured Ferritic Oxide Dispersion Strengthened Alloys, Thermochem. Acta, 2014, 579, p 1–8
M.J. Alinger, G.R. Odette, and D.T. Hoelzer, On the Role of Alloy Composition and Processing Parameters in Nanocluster Formation and Dispersion Strengthening in Nanostructured Ferritic Alloys, Acta Mater., 2009, 57, p 392–406
J.H. Lee, Development of Oxide Dispersion Strengthened Ferritic Steels with and Without Aluminum, Front. Energy, 2012, 6, p 29–34
J.H. Lee, R. Kasada, A. Kimura, T. Okuda, M. Inoue, S. Ukai, S. Ohnuki, T. Fujisawa, and F. Abe, Influence of Alloy Composition and Temperature on Corrosion Behavior of ODS Ferritic Steels, J. Nucl. Mater., 2011, 417, p 1225–1228
H.L. Hu, Z.J. Zhou, L. Liao, L.F. Zhang, M. Wang, S.F. Li, and C.C. Ge, Corrosion Behavior of a 14Cr-ODS Steel in Supercritical Water, J. Nucl. Mater., 2013, 437, p 196–200
H. Je and A. Kimura, Stress corrosion Cracking Susceptibility of Oxide Dispersion Strengthened Ferritic Steel in Supercritical Pressurized Water Dissolved with Different Hydrogen and Oxygen Contents, Corros. Sci., 2014, 78, p 193–199
F.D. Gabriele, S. Amore, C. Scaiola, E. Arato, D. Giuranno, R. Novakovic, and E. Ricci, Corrosion Behaviour of 12Cr-ODS Steel in Molten Lead, Nucl. Eng. Des., 2014, 280, p 69–75
O. Yeliseyeva, V. Tsisara, and Z. Zhou, Corrosion Behavior of Fe-14Cr-2W and Fe-9Cr-2W ODS Steels in Stagnant Liquid Pb with Different Oxygen Concentration at 550 and 650 °C, J. Nucl. Mater., 2013, 442, p 434–443
P. Hosemann, H.T. Thau, A.L. Johnson, S.A. Maloy, and N. Li, Corrosion of ODS Steels in Lead-Bismuth Eutectic, J. Nucl. Mater., 2008, 373, p 246–253
K. Lambrinou, V. Koch, G. Coen, J. Van den Bosch, and C. Schroer, Corrosion Scales on Various Steels After Exposure to Liquid Lead-Bismuth Eutectic, J. Nucl. Mater., 2014, 450, p 244–255
T. Furukawa, S. Kato, and E. Yoshida, Compatibility of FBR Materials with Sodium, J. Nucl. Mater., 2009, 392, p 249–254
E. Yoshida and S. Kato, Sodium Compatibility of ODS Steel at Elevated Temperature, J. Nucl. Mater., 2004, 329–333, p 1393–1397
B. El-Dasher, J. Farmer, J. Ferreira, M. Serrano de Caro, A. Rubenchik, and A. Kimura, Corrosion of Oxide Dispersion Strengthened Iron-Chromium Steels and Tantalum in fluoride Salt Coolant: An In Situ Compatibility Study for Fusion and Fusion-fission Hybrid Reactor Concepts, J. Nucl. Mater., 2011, 419, p 15–23
S. Ningshen, M. Sakairi, K. Suzuki, and S. Ukai, Corrosion Resistance of 9% Cr Oxide Dispersion Strengthened Steel in Different Electrolytic Media, Corrosion, 2013, 69, p 863–874
S. Ningshen, M. Sakairi, K. Suzuki, and S. Ukai, The Passive film Characterization and Anodic Polarization Behavior of 11% Cr Ferritic/Martensitic and 15% Cr Oxide Dispersion Strengthened Steels in Different Electrolytic Solutions, Appl. Surf. Sci., 2013, 274, p 345–355
M. Sakairi, S. Ningshen, K. Suzuki, and S. Ukai, Corrosion Study and Passive Film Characterization of 11% Cr F/M and 15% Cr ODS Steels, J Civil Eng Archit, 2013, 7, p 940–955
S. Ningshen, M. Sakairi, K. Suzuki, and S. Ukai, The Surface Characterization and Corrosion Resistance of 11% Cr Ferritic/Martensitic and 9%-15% Cr ODS Steels for Nuclear Fuel Reprocessing Application, J. Solid State Electrochem., 2014, 18, p 411–425
S. Ningshen, M. Sakairi, K. Suzuki, and S. Ukai, The Corrosion Resistance and Passive film Compositions of 12% Cr and 15% Cr Oxide Dispersion Strengthened Steels in Nitric Acid Media, Corros. Sci., 2014, 78, p 322–334
J. Isselin, R. Kasada, and A. Kimura, Effects of Aluminum on the Corrosion Behavior of 16% Cr ODS Ferritic Steels in a Nitric Acid Solution, J. Nucl. Sci. Technol., 2011, 48, p 169–171
M. Terada, A.J.O. Zimmermann, H.R.Z. Sandim, I. Costa, and A.F. Padilha, Corrosion Behavior of Eurofer 97 and ODS-Eurofer Alloys Compared to Traditional Stainless Steels, J. Appl. Electrochem., 2011, 41, p 951–959
H. Hu, Z. Zhou, M. Li, L. Zhang, M. Wang, S. Li, and C. Ge, Study of the Corrosion Behavior of a 18Cr-Oxide Dispersion Strengthened Steel in Supercritical Water, Corros. Sci., 2012, 65, p 209–213
B. Gwinner, M. Auroy, D. Mas, A. Saint Jevin, and S. Pasquier-Tilliette, Impact of the Use of the Ferritic/Martensitic ODS Steels Cladding on the Fuel Reprocessing PUREX Process, J. Nucl. Mater., 2012, 428, p 110–116
P. Dubuisson, Y. de Carlan, V. Garat, and M. Blat, ODS Ferritic/Martensitic alloys for Sodium Fast Reactor Fuel Pin Cladding, J. Nucl. Mater., 2012, 428, p 6–12
G. Sundararajan, P. Sudharshan Phani, A. Jyothirmayi, C. Ravi, and C. Gundakaram, The Influence of Heat Treatment on the Microstructural, Mechanical and Corrosion Behaviour of Cold Sprayed SS 316L Coatings, J. Mater. Sci., 2009, 44, p 2320–2326
G.S. Frankal, Pitting Corrosion of Metals: A Review of the Critical Factors, J. Electrochem. Soc., 1998, 145, p 2186–2198
L.M. Calle, R.D Vinje, and L.G. MacDowell, Electrochemical evaluation of stainless steels in acidified sodium chloride solutions, Corrosion/2004, Paper No. 04303 (Houston, TX: NACE)
M. Darabara, L. Bourithis, S. Zinelis, and G.D. Papadimitriou, Susceptibility to Localized Corrosion of Stainless Steel and NiTi Endodontic Instruments in Irrigating Solutions, Int. Endod. J., 2004, 37, p 705–710
A.H. Kandil, A.A. Fahmy Waheed, and H.M.T. Tawfik, Water Chemistry Effect on Corrosion of Nuclear Fuel Cladding Material, Zircaloy-4 (Zr-4), Int. J. Adv. Res., 2014, 2, p 149–162
W.S. Tait, An introduction to Electrochemical Corrosion Testing for Practicing Engineers and Scientists, Pair Docs Publication, Madison, 1994
E. Klar and P.K. Samal, Powder Metallurgy Stainless Steels: Processing, Microstructures and Properties, ASM International, Materials Park, 2007, p 155
Z. Szklarska-Smialowska, Mechanism of Pit Nucleation by Electrical Breakdown of the Passive Film, Corros. Sci., 2002, 44, p 1143–1149
L. Bertolini, B. Elsener, P. Pedeferri, E. Redaelli, and R.B. Polder, Corrosion of Steel in Concrete: Prevention, Diagnosis, Repair, Wiley-VCH, Weinheim, 2013
C. Liu, Q. Bi, A. Leyland, and A. Matthews, An Electrochemical Impedance Spectroscopy Study of the Corrosion Behaviour of PVD Coated Steels in 0.5 N NaCl Aqueous Solution: Part II. EIS Interpretation of Corrosion Behaviour, Corros. Sci., 2003, 45, p 1257–1273
R.T. Loto, Pitting Corrosion Evaluation of Austenitic Stainless Steel Type 304 in Acid Chloride Media, J. Mater. Environ. Sci., 2013, 4, p 448–459
Acknowledgments
The authors thank Mr. G. V. R. Reddy and Mr. M. Ramakrishna for carrying out electron microscopy analysis. They are thankful to Dr. K. Satya Prasad and Dr. B. V. Sarada for valuable technical discussions. The authors gratefully acknowledge Indira Gandhi Centre for Atomic Research (IGCAR), Kalpakkam, for funding (No. IGC/MMG/MMD/ODS/01/2010) the work and NFC, Hyderabad, for carrying out hot extrusion.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Nagini, M., Jyothirmayi, A., Vijay, R. et al. Influence of Dispersoids on Corrosion Behavior of Oxide Dispersion-Strengthened 18Cr Steels made by High-Energy Milling. J. of Materi Eng and Perform 25, 577–586 (2016). https://doi.org/10.1007/s11665-015-1859-5
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-015-1859-5