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Corrosion Behavior of Sintered NdFeB Magnets Coated with Ni Coatings Deposited by Ion Beam Sputtering

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Abstract

To improve the corrosion resistance of a sintered NdFeB magnet, pure Ni coatings were deposited on the magnet by ion beam sputtering, and the effect of the deposition process parameters upon the microstructure and the corrosion resistance of the Ni coating was investigated by scanning electron microscopy and potentiodynamic polarization curves, respectively. A dense Ni coating was obtained via room temperature deposition for 3 h, which exhibited high adhesive strength with the NdFeB substrate and excellent corrosion resistance. The Ni coatings deposited at high temperature, however, possessed a lower corrosion resistance that can be attributed to the atom diffusion and crystallization of the coatings grown at high temperature. A magnetic field is found to affect the corrosion behavior of NdFeB magnets with or without Ni coatings, reducing its corrosion resistance. The corrosion resistance of a Ni-coated NdFeB sample in the presence of a magnetic field is better than that of an uncoated sample.

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References

  1. M. Sagawa, S. Fujimura, N. Togawa, H. Yamamoto, and Y. Mataura, New Material for Permanent Magnets on a Base of Nd and Fe, Appl. Phys., 1984, 55, p 2083–2087

    Article  Google Scholar 

  2. S.M.T. Takeuchi, D.S. Azambuja, A.M. Saliba-Silva, and I. Costa, Corrosion Protection of NdFeB Magnets by Phosphating with Tungstate Incorporation, Surf. Coat. Technol., 2006, 200, p 6826–6831

    Article  Google Scholar 

  3. L. Schultz, A.M.E. Aziz, and G. Barkleit, Corrosion Behavior of Nd-Fe-B Permanent Magnetic Alloys, Mater. Sci. Eng. A, 1999, 267, p 307–313

    Article  Google Scholar 

  4. F. Cygand and J. Mcnllan, Corrosion of NdFeB Permanent Magnets in Humid Environments at Temperature up to 150 °C, J. Magn. Magn. Mater., 1995, 139, p 131–138

    Article  Google Scholar 

  5. A.M. El-Aziz, Corrosion Resistance of Nd-Fe-B Permanent Magnetic Alloys, Mater. Corros., 2003, 54(2), p 88

    Article  Google Scholar 

  6. L.Q. Yu, Y.H. Wen, and M. Yan, Effects of Dy and Nb on the Magnetic Properties and Corrosion Resistance of Sintered NdFeB, J. Magn. Magn. Mater., 2004, 283, p 353–356

    Article  Google Scholar 

  7. A.A. El-Moneim, A. Gebert, and M. Uhlemann, The Influence of Co and Ga on the Corrosion Behavior of Nanocrystalline NdFeB-Based Magnets, Corros. Sci., 2002, 44, p 1257–1874

    Article  Google Scholar 

  8. A.A. El-Moneim, O. Gutfleisch, A. Plotnikov, and A. Gebert, Corrosion Behavior of Hot-Pressed and Die-Upset Nanocrystalline NdFeB-Based Magnets, J. Magn. Magn. Mater., 2002, 248, p 121–123

    Article  Google Scholar 

  9. A. Ali, A. Ahmad, and K.M. Deen, Impeding Corrosion of Sintered NdFeB Magnets with Titanium Nitride Coating, Mater. Corros., 2010, 61, p 130–135

    Google Scholar 

  10. D.J. Blackwood, B. Balakrisnan, and Y.Z. Huang, Influence of the Chemical Composition of the Plating Solution on the Ability of Nickel Coating to Protect Nd2Fe14B Magnets Against Corrosion, J. Magn. Magn. Mater., 2001, 223, p 103–111

    Article  Google Scholar 

  11. J. Zheng, M. Lin, and Q. Xia, A Preparation Method and Effects of Al-Cr Coating on NdFeB Sintered Magnets, J. Magn. Magn. Mater., 2012, 324, p 3966–3969

    Article  Google Scholar 

  12. Y. Wang, Y. Deng, Y. Ma, and F. Gao, Improving Adhesion of Electroless Ni–P Coating on Sintered NdFeB Magnet, Surf. Coat. Technol., 2011, 206, p 1203–1210

    Article  Google Scholar 

  13. J.L. Xu, Z.C. Zhang, Z.X. Huang, and J.M. Luo, Corrosion Resistance of the Titania Particles Enhanced Acrylic Resin Composites Coatings on Sintered NdFeB Magnets, J. Alloys Compd., 2013, 570, p 28–33

    Article  Google Scholar 

  14. X. Zhang, Y. Mai, B. Zhang et al., Corrosion of Hot-Pressed Nanocrystalline NdFeB Magnet in Simulated Marine Atmosphere, Corros. Sci., 2014, 87, p 156–166

    Article  Google Scholar 

  15. T. Xie, S. Mao, Y. Chao, S. Wang, and Z. Song, Structure, Corrosion and Hardness Properties of Ti/Al Multilayers Coated on NdFeB by Magnetron Sputtering, Vacuum, 2012, 86, p 1583–1588

    Article  Google Scholar 

  16. J. Li, S. Mao, K. Sun, X. Li, and Z. Song, AlN/Al Dual Protective Coatings on NdFeB by DC Magnetron Sputtering, J. Magn. Magn. Mater., 2009, 321, p 3799–3803

    Article  Google Scholar 

  17. S. Mao, H. Yang, J. Li, F. Huang, and Z. Song, Corrosion Properties of Aluminum Coatings Deposited on Sintered NdFeB by Ion-Beam-Assisted Deposition, Appl. Surf. Sci., 2011, 257, p 5581–5585

    Article  Google Scholar 

  18. E. Chen, K. Peng, W. Yang, J. Zhu, D. Li, and L. Zhou, Effects of Al Coatings on Corrosion Resistance of Sintered NdFeB Magnets, Trans. Nonferr. Metals Soc. China, 2014, 24, p 2864–2869

    Article  Google Scholar 

  19. Z. Chen, N. Alice, J. Yi, and X. Chen, Multi-Layered Electroless Ni-P Coatings on Power-Sintered Nd-Fe-B Permanent Magnet, J. Magn. Magn. Mater., 2006, 302, p 216–222

    Article  Google Scholar 

  20. T. Yinowa, Y. Yoshikawa, and M. Honahima, Improvement of the Corrosion Resistance on Nd-Fe-B Magnet with Nickel Plating, IEEE High. Electrochem. Act. Trans. Magn., 1989, 25, p 3776–3778

    Article  Google Scholar 

  21. P. Crook, Corrosion of Nickel and Nickel-Base Alloys, Corrosion Materials, Vol13B, ASM Handbook, ASM International, Materials Park, 2005, p 228–251

    Google Scholar 

  22. H. Koivuluoto, A. Milanti, G. Bolelli, L. Lusvarghi, and P. Vuoristo, High-Pressure Cold-Sprayed Ni and Ni-Cu Coatings: Improved Structures and Corrosion Properties, J. Therm. Spray Technol., 2014, 23, p 98–103

    Article  Google Scholar 

  23. I. Rampin, F. Bisaglia, and M. Dabalà, Corrosion Properties of NdFeB Magnets Coated by a Ni/Cu/Ni Layer in Chloride and Sulfide Environments, J. Mater. Eng. Perform., 2010, 19, p 970–975

    Article  Google Scholar 

  24. L. Song, Y. Wang, W. Lin, and Q. Liu, Primary Investigation of Corrosion Resistance of Ni-P/TiO2 Composite Film on Sintered NdFeB Permanent Magnet, Surf. Coat. Technol., 2008, 202, p 5146–5150

    Article  Google Scholar 

  25. L. Song and Z. Yang, Corrosion Resistance of Sintered NdFeB Permanent Magnet with Ni-P/TiO2 Composite Film, J. Iron Res. Int., 2009, 16(3), p 89–94

    Article  Google Scholar 

  26. P. Cavalloti, B. Bozzini, R. Cecchini et al., Corrosion and Protection of NdFeB Type Magnets, J. Magn. Magn. Mater., 1992, 104–107, p 1216–1218

    Article  Google Scholar 

  27. W. Mo, T. Zhang, Q. Liu et al., Microstructure and Corrosion Resistance of Sintered NdFeB Magnet Modified by Intergranular Addition of MgO and ZnO, J. Rare Earth, 2008, 26(2), p 268–273

    Article  Google Scholar 

  28. J. Ding, X. Bajin, and G. Ling, Al-Mn Coating Electrodeposited Ionic Liquid on NdFeB Magnet with High Hardness and Corrosion Resistance, Appl. Surf. Sci., 2014, 305, p 309–313

    Article  Google Scholar 

  29. Lei Tao, Heqin Li, Jiong Shen et al., Corrosion Resistance of the NdFeB Coated with AlN/SiC Bilayer Thin Film by Magnetron Sputtering Under Different Environments, J. Magn. Magn. Mater., 2015, 375, p 124–128

    Article  Google Scholar 

  30. R. Sueptitz, K. Tschulik, and M. Uhlemann, Effect of Magnetization State on the Corrosion Behavior of NdFeB Permanent Magnets, Corros. Sci., 2011, 53, p 2843–2852

    Article  Google Scholar 

  31. G. Hinds, J.M.D. Coey, and M.Z.G. Lyons, Influence of Magnetic Forces on Electrochemical Mass Transport, Electrochem. Commun., 2001, 3, p 215–218

    Article  Google Scholar 

  32. H. Jing, C. Dong, X. Li, and K. Xiao, Effects of Applied Magnetic Field on Corrosion of Beryllium Copper in NaCl Solution, J. Mater. Sci. Technol., 2010, 26, p 355–361

    Article  Google Scholar 

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 51571087) and the Key Project for Science and Technology of Changsha (K1306063-11).

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Correspondence to Sheng-qing Hu or Kun Peng.

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Hu, Sq., Peng, K., Chen, E. et al. Corrosion Behavior of Sintered NdFeB Magnets Coated with Ni Coatings Deposited by Ion Beam Sputtering. J. of Materi Eng and Perform 24, 4985–4990 (2015). https://doi.org/10.1007/s11665-015-1787-4

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  • DOI: https://doi.org/10.1007/s11665-015-1787-4

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