Skip to main content
Log in

The Synthesis and Electrochemical Behavior of High-Nitrogen Nickel-Free Austenitic Stainless Steel

  • Published:
Journal of Materials Engineering and Performance Aims and scope Submit manuscript

Abstract

A new smelting method to synthesize high-nitrogen nickel-free austenitic stainless steel was suggested. The synthesized steel completely consists of austenite and represents more brilliant anti-corrosion ability both in salt solution and sulfuric acid solution. The brilliant anti-corrosion ability is retained even after severe cold-rolling deformation, which ensures its workability in practice. The potentiodynamic polarization curves, electrochemical impedance spectroscopy, and passivating treatment were used to characterize its corrosion properties and uncover its corrosion mechanism in salt solution. X-ray photoelectron spectroscopy was used to clarify the mechanism of passivation. The results demonstrate that the steel has a more uniform and thicker passive film than traditional stainless steel due to the cooperation of nitrogen and chromium.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. A.F. Padilha and P.R. Rios, Decomposition of Austenite in Austenitic Stainless Steels, ISIJ Int., 2002, 42, p 325–337

    Article  Google Scholar 

  2. L.R. Bairi, S. Ningshen, U.K. Mudali, and B. Raj, Microstructural Analysis and Corrosion Behaviour of D9 Stainless Steel-Zirconium Metal Waste Form Alloys, Corros. Sci., 2010, 52, p 2291–2302

    Article  Google Scholar 

  3. H. Luo, C.F. Dong, X.G. Li, and K. Xiao, The Electrochemical Behaviour of 2205 Duplex Stainless Steel in Alkaline Solutions with Different pH in the Presence of Chloride, Electrochim. Acta, 2012, 64, p 211–220

    Article  Google Scholar 

  4. S. Ningshen and U.K. Mudali, Pitting and Intergranular Corrosion Resistance of AISI, Type 301LN Stainless Steels, J. Mater. Eng. Perform., 2010, 19, p 274–281

    Article  Google Scholar 

  5. S.N. Ghali, Low Carbon High Nitrogen Low Nickel Stainless Steel, Steel Res. Int., 2013, 84, p 450–456

    Article  Google Scholar 

  6. Z.-H. Jiang, Z.-R. Zhang, H.-B. Li, Z. Li, and Q.-F. Ma, Microstructural Evolution and Mechanical Properties of Aging High Nitrogen Austenitic Stainless Steels, Int. J. Miner. Metall. Mater., 2010, 17, p 729–736

    Article  Google Scholar 

  7. L. Escalada, J. Lutz, S. Maendl, D. Manova, H. Neumann, and S. Simison, Corrosion Properties of Stainless Steel 316 L After Energetic Nitrogen Insertion, Surf. Coat. Technol., 2012, 211, p 76–79

    Article  Google Scholar 

  8. D. Cui, Preparation of Nickel-Free Cr-Mn-Mo-N Stainless Steel by High Energy Ball Milling and Cold Pressing Sintering, Rare Met. Mater. Eng., 2008, 37, p 2249–2252

    Google Scholar 

  9. D.W. Cui, X.H. Qu, P. Guo, and K. Li, Sintering Optimisation and Solution Annealing of high Nitrogen Nickel Free Austenitic Stainless Steels Prepared by PIM, Powder Metall., 2010, 53, p 91–95

    Article  Google Scholar 

  10. H. Li, Z. Jiang, Q. Ma, and W. Li, Manufacturing High Nitrogen Austenitic Stainless Steels by Pressurized Induction Furnace, Appl. Mech. Mater., 2011, 5254, p 1687–1691

  11. R.F.A. Jargelius-pettersson, Electrochemical Investigation of the Influence of Nitrogen Alloying on Pitting Corrosion of Austenitic Stainless Steel, Corros. Sci., 1999, 41, p 1639–1664

    Article  Google Scholar 

  12. H. Ma, Y. Berthier, and P. Marcus, NH3 Probing of the Surface Acidity of Passive Films on Chromiun, Corros. Sci., 2002, 44, p 171–178

    Article  Google Scholar 

  13. H.J. Grake, The Role of Nitrogen in the Corrosion of Iron and Steels, ISIJ Int., 1996, 36, p 777–786

    Article  Google Scholar 

  14. J.W. Simmons, Overview: High-Nitrogen Alloying of Stainless Steel, Mater. Sci. Eng. A, 1996, 207, p 159–169

    Article  Google Scholar 

  15. P.R. Levey and A. van Bennekom, A Mechanistic Study of the Effects of Nitrogen on the Corrosion Properties on Stainless Steel, Corrosion, 1995, 51, p 911–921

    Article  Google Scholar 

  16. Y.S. Lim, J.S. Kim, S.J. Ahn, H.S. Kwon, and Y. Katada, The Influence of Microestruture and Nitrogen Alloying on Pitting Corrosion of Type 316 L and 20 wt% Mn-Substituted Type 316 L Stainless Steel, Corros. Sci., 2001, 43, p 53–68

    Article  Google Scholar 

  17. S.H. Kim, H.K. Moon, T. Kang, and C.S. Lee, Dissolution Kinetics of Delta Ferrite in AISI, ASS Stainless Steel Produced by Strip Casting Process, Mater. Sci. Eng. A, 2003, 356, p 390–398

    Article  Google Scholar 

  18. S.H.C. Park, Y.S. Sato, H. Kokawa, K. Okamoto, S. Hirano, and M. Inagaki, Microstructural Characterisation of Stir Zone Containing Residual Ferrite in Friction Stir Welded ASS Austenitic Stainless Steel, Sci. Technol. Weld. Join., 2005, 10, p 550–556

    Article  Google Scholar 

  19. S.G. Wang, M. Sun, H.B. Han, K. Long, and Z.D. Zhang, The High-Temperature Oxidation of Bulk Nanocrystalline ASS Stainless Steel in Air, Corros. Sci., 2013, 72, p 64–72

    Article  Google Scholar 

  20. A.A. Hermas and M.S. Morad, A Comparative Study on the Corrosion Behaviour of 304 Austenitic Stainless Steel in Sulfamic and Sulfuric Acid Solutions, Corros. Sci., 2008, 50, p 2710–2717

  21. S.C. Gallo and H. Dong, Corrosion Behaviour of Direct Current and Active Screen Plasma Carburised AISI, 316 Stainless Steel in Boiling Sulphuric Acid Solution, Corros. Eng. Sci. Technol., 2011, 46, p 8–16

    Article  Google Scholar 

  22. V. Vignal, H. Krawiec, O. Heintz, and D. Mainy, Passive Properties of Lean Duplex Stainless Steels After Long-Term Ageing in Air Studied Using EBSD, AES, XPS and Local Electrochemical Impedance Spectroscopy, Corros. Sci., 2013, 67, p 109–117

    Article  Google Scholar 

  23. M.A. Azam, K. Isomura, A. Fujiwara, and T. Shimoda, Direct Growth of Vertically Aligned Single-Walled Carbon Nanotubes on Conducting Substrate and Its Electrochemical Performance in Ionic Liquids, Phys. Status Solidi A, 2012, 209, p 2260–2266

    Article  Google Scholar 

  24. C. García, F. Martín, Y. Blanco, M.P. Tiedra, and M.L. Aparicio, Corrosion Behaviour of Duplex Stainless Steels Sintered in Nitrogen, Corros. Sci., 2009, 51, p 76–86

    Article  Google Scholar 

  25. B. Normand, A. Pierre, and J. Pagetti, Electrochemical and Surface Studies of the Passive Layers Grown on Sputter-Deposited Nitrogen-Stainless Steel Alloys in 1 M H2SO4 Solution, Corros. Sci., 1995, 37, p 1537–1549

    Article  Google Scholar 

  26. S. Ningshen, U.K. Mudali, V.K. Mittal, and H.S. Khatak, Semiconducting and Passive Film, Properties of Nitrogen-Containing Type 316LN Stainless Steels, Corros. Sci., 2007, 49, p 481–496

    Article  Google Scholar 

  27. A.H. Heuer, H. Kahn, F. Ernst, G.M. Michal, D.B. Hovis, R.J. Rayne, F.J. Martin, and P.M. Natishan, Enhanced Corrosion Resistance of Interstitially Hardened Stainless Steel: Implications of a Critical Passive Layer Thickness for Breakdown, Acta Mater., 2012, 60, p 716–725

    Article  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the Foundation of National Key Basic Research and Development Program (Grant No. 2010CB631001) and the National Natural Science Foundation of China (Grant Nos. 50771049 and 50871046).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Sufeng Wei or Guoyong Wang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sun, S., Wei, S., Wang, G. et al. The Synthesis and Electrochemical Behavior of High-Nitrogen Nickel-Free Austenitic Stainless Steel. J. of Materi Eng and Perform 23, 3957–3962 (2014). https://doi.org/10.1007/s11665-014-1169-3

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11665-014-1169-3

Keywords

Navigation