Abstract
Au-Ge-based solder alloys are promising alternatives to lead containing solders due to the fact that they offer a combination of interesting properties such as good thermal and electrical conductivity and high corrosion resistance in addition to a relatively low melting temperature (361 °C for eutectic Au-28Ge at.%). By adding a third element to the eutectic Au-28Ge alloy not only the Au content could be reduced but also the melting temperatures could be further decreased. In this study, in addition to the eutectic Au-28Ge (at.%) two ternary alloys were chosen from the Au-Ge-Sb and Au-Ge-Sn system, respectively. The soldering behavior of these alloys in combination with the frequently used metals Cu, Ni, and Ti was investigated. The interface reactions and microstructures of the joints were characterized in detail by SEM and EDX analysis. For the determination of the mechanical properties, shear tests were conducted. Mean shear strength values up to 104 MPa could be achieved.
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V. Chidambaram, J. Hattel, and J. Hald, High Temperature Lead-Free Solder Alternatives, Microelectron. Eng., 2011, 88(6), p 981–989
V. Chidambaram, J. Hald, and J. Hattel, Development of Au-Ge Based Candidate Alloys as an Alternative to High-Lead Content Solders, J. Alloys Compd., 2010, 490(1–2), p 170–179
F.Q. Lang, H. Yamaguchi, H. Ohashi, and H. Sato, Improvement in Joint Reliability of SiC Power Devices by a Diffusion Barrier Between Au-Ge Solder and Cu/Ni(P) Metalized Ceramic Substrates, J. Electron. Mater., 2011, 40(7), p 1563–1571
V. Chidambaram, H.B. Yeung, and G. Shan, Reliability of Au-Ge and Au-Si Eutectic Solder Alloys for High-Temperature Electronics, J. Electron. Mater., 2012, 41(8), p 2107–2117
S. Msolli, O. Dalverny, J. Alexis, and M. Karama, Mechanical Characterization of an Au-Ge Solder Alloy for High Temperature Electronic Devices, Presented at: CIPS (2010), Nuremberg, Poster P4.
C. Leinenbach, F. Valenza, D. Giuranno, H.R. Elsener, S. Jin, and R. Novakovic, Wetting and Soldering Behavior of Eutectic Au-Ge Alloy on Cu and Ni Substrates, J. Electron. Mater., 2011, 40(7), p 1533–1541
N. Weyrich and C. Leinenbach, Low Temperature TLP Bonding of Al2O3-Ceramics Using Eutectic Au-(Ge, Si) Alloys, J. Mater. Sci., 2013, 48, p 7115–7124
N. Weyrich, L.I. Duarte, C. Leinenbach, and D. Lado, Joining of Titanium and Nickel at Temperatures Below 450 °C, Brazing, High Temperature Brazing and Diffusion Bonding – Löt 2013, Aachen, Germany, June 18–20, 2013, p 22–27.
J. Wang, C. Leinenbach, and M. Roth, Thermodynamic Description of the Au-Ge-Sb Ternary System, J. Alloys Compd., 2009, 485(1), p 577–582
J. Wang, C. Leinenbach, and M. Roth, Thermodynamic Modeling of the Au-Ge-Sn Ternary System, J. Alloys Compd., 2009, 481(1–2), p 830–836
V. Chidambaram, J. Hard, R. Ambat, and J. Hattel, A Corrosion Investigation of Solder Candidates for High-Temperature Applications, JOM, 2009, 61(6), p 59–65
S. Jin, F. Valenza, R. Novakovic, and C. Leinenbach, Wetting Behavior of Ternary Au-Ge-X (X = Sb, Sn) Alloys on Cu and Ni, J. Electron. Mater., 2013, 42(6), p 1024–1032
T.B. Massalski, H. Okamoto, P.R. Subramanlan, and L. Kacprzak, Binary Alloy Phase Diagrams. ASM, Materials Park, 1990. Reprinted with the permission of ASM International. All rights reserved. www.asminternational.org. Accessed 21 Oct 2013
H. Raether, Study of Ordering Transformation of the Au-Cu Alloy AuCu3 with Electron Diffraction, Z. Angew. Phys., 1952, 4, p 7
S. Yamaguchi, D. Watanabe, and S. Ogawa, Study of Anti-phase Domains in Cu3Au by Means of Electron Diffraction and Electron Microscopy, J. Phys. Soc. Jpn., 1962, 17, p 1030–1041
M. Sakai and D.E. Mikkola, The Growth of Antiphase Domains in Cu3Au as Studies by Transmission Electron Microscopy, Metall. Trans., 1971, 2(6), p 1635–1641
Y. Zhang, C. Li, Z. Du, and C. Guo, A Thermodynamic Assessment of Ni-Sb System, CALPHAD, 2008, 32(2), p 378–388
S. Jin, C. Leinenbach, J. Wang, L.I. Duarte, S. Delsante, G. Borzone, A. Scott, and A. Watson, Thermodynamic Study and Re-assessment of the Ge-Ni System, CALPHAD, 2012, 38, p 23–34
A. Paul, Growth Mechanism of Phases, Kirkendall Voids, Marker Plane Positions and Indication of the Relative Mobilities of the Species in the Interdiffusion Zone, J. Mater. Sci. Mater. Electron., 2011, 22, p 833–837
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The authors thank the Laboratory of Metal Physics and Technology, Department of Materials, ETH Zürich for providing support with melt spinning.
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This article is an invited submission to JMEP selected from presentations at the Symposia “Wetting,” “Interface Design,” and “Joining Technologies” belonging to the Topic “Joining and Interface Design” at the European Congress and Exhibition on Advanced Materials and Processes (EUROMAT 2013), held September 8-13, 2013, in Sevilla, Spain, and has been expanded from the original presentation.
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Weyrich, N., Jin, S., Duarte, L.I. et al. Joining of Cu, Ni, and Ti Using Au-Ge-Based High-Temperature Solder Alloys. J. of Materi Eng and Perform 23, 1585–1592 (2014). https://doi.org/10.1007/s11665-014-0864-4
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DOI: https://doi.org/10.1007/s11665-014-0864-4