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Pack Cementation Coatings for High-Temperature Oxidation Resistance of AISI 304 Stainless Steel

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Abstract

Aluminum and titanium are deposited on the surface of steel by the pack cementation method to improve its hot-corrosion and high-temperature oxidation resistance. In this research, coatings of aluminum and titanium and a two-step coating of aluminum and titanium were applied on an AISI 304 stainless steel substrate. The coating layers were examined by carrying out scanning electron microscopy (SEM) and x-ray diffraction (XRD). The SEM results showed that the aluminized coating consisted of two layers with a thickness of 450 μm each, the titanized coating consisted of two layers with a thickness of 100 μm each, and the two-step coatings of Al and Ti consisted of three layers with a thickness of 200 μm each. The XRD investigation of the coatings showed that the aluminized coating consisted of Al2O3, AlCr2, FeAl, and Fe3Al phases; the titanized layers contained TiO2, Ni3Ti, FeNi, and Fe2TiO5 phases; and the two-step coating contained AlNi, Ti3Al, and FeAl phases. The uncoated and coated specimens were subjected to isothermal oxidation at 1050 °C for 100 h. The oxidation results revealed that the application of a coating layer increased the oxidation resistance of the coated AISI 304 samples as opposed to the uncoated ones.

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References

  1. F. Riffard, H. Buscail, E. Caudron, R. Cueff, C. Issartel, and S. Perrier, The Influence of Implanted Yttrium on the Cyclic Oxidation Behaviour of 304 Stainless Steel, Appl. Surf. Sci., 2006, 252(10), p 3697–3706

    Article  CAS  Google Scholar 

  2. F.J. Pérez, M. Jcristóbal, M.P. Hierro, and F. Pedraza, The Influence of Implanted Silicon on the Cyclic Oxidation Behavior of Two Different Stainless Steels, Surf. Coat. Technol., 1999, 120–121, p 442–447

    Article  Google Scholar 

  3. D. Laverde, T. Gómez-Acebo, and F. Castro, Continuous and Cyclic Oxidation of T91 Ferritic Steel Under Steam, Corr. Sci., 2004, 46(3), p 613–631

    Article  CAS  Google Scholar 

  4. S. Sharafi and M.R. Farhang, Effect of Aluminizing on Surface Microstructure of an HH309 Stainless Steel, Surf. Coat. Technol., 2006, 200(16–17), p 5048–5051

    Article  CAS  Google Scholar 

  5. Z.D. Xiang, S.R. Rose, and P.K. Datta, Pack Codeposition of Al and Cr to Form Diffusion Coatings Resistant to High Temperature Oxidation and Corrosion for γ-TiAl, Mater. Sci. Technol. (UK), 2002, 18(12), p 1479–1484

    Article  CAS  Google Scholar 

  6. Z.D. Xiang and P.K. Datta, Relationship Between Pack Chemistry and Aluminide Coating Formation for Low-Temperature Aluminisation of Alloy Steels, Acta Mater., 2006, 54(17), p 4453–4463

    Article  CAS  Google Scholar 

  7. S.P. Chakraborty, S. Banerjee, K. Singh, I.G. Sharma, A.K. Grover, and A.K. Suri, Studies on the Development of Protective Coating on TZM Alloy and Its Subsequent Characterization, J. Mater. Process Technol. (Switzerland), 2008, 207(1–3), p 240–247

    CAS  Google Scholar 

  8. M.T. Kim, N.H. Heo, J.H. Shin, and C.Y. Kim, Simultaneous Chromizing and Aluminizing Using Chromium Oxide and Aluminum: (I) on Low Alloy Steel, Surf. Coat. Technol., 2000, 123(2–3), p 227–230

    Article  CAS  Google Scholar 

  9. R. Mevrel, C. Duret, and R. Pichoir, Pack Cementation Processes, Mater Sci. Technol., 1984, 2(3), p 201–206

    Article  Google Scholar 

  10. C.H. Koo and T.H. Yu, Pack Cementation Coatings on Ti3Al-Nb Alloys to Modify the High-Temperature Oxidation Properties, Surf. Coat. Technol., 2000, 126(2–3), p 171–180

    Article  CAS  Google Scholar 

  11. F.J. Pérez, M.P. Hierro, F. Pedraza, M.C. Carpintero, C. Gómez, and R. Tarín, Effect of Fluidized Bed CVD Aluminide Coatings on the Cyclic Oxidation of Austenitic AISI, 304 Stainless Steel, Surf. Coat. Technol., 2001, 145(13), p 1–7

    Article  Google Scholar 

  12. T.L. Hu, H.L. Huang, D. Gan, and T.Y. Lee, The Microstructure of Aluminized Type 310 Stainless Steel, Surf. Coat. Technol., 2006, 201(6), p 3502–3509

    Article  CAS  Google Scholar 

  13. F. Üstel and S. Zeytin, Growth Morphology and Phase Analysis of Titanium-Based Coating Produced by Thermochemical Method, Vacuum., 2006, 81(3), p 360–365

    Article  Google Scholar 

  14. R.S. Sundar, R.G. Baligidad, Y.V.R.K. Prasad, and D.H. Sastry, Processing of Iron Aluminides, 1988, Mater. Sci. Eng. A, 1998, 258(1998), p 219–228

    Google Scholar 

  15. Y. Mishin and C. Herzig, Diffusion in the Al-Ti System, Acta Mater., 2000, 48(3), p 589–623

    Article  CAS  Google Scholar 

  16. M. Entezarian, “Reactive Plasma Spray Forming of Al-TiAl3 Composites Using a Triple Plasma System”, Ph.D. Thesis, Department of Minning and Metallurgical Engineering, McGill University, Montreal, Canada, 1997

  17. J. Stringer, Surface Engineering, Series E: Applied Science, vol. 85, R. Kossowsky and S. Singhal, Ed., 1984, p 561–587

  18. M.J. Bennett, A.T. Tuson, C.F. Knights, and C.F. Ayres, Oxidation Protection of Alloy IN 738 LC by Plasma Assisted Vapour Deposited Silica Coating, Mater. Sci. Technol., 1989, 8, p 841–852

    Google Scholar 

  19. R.E. Reed-Hill, Physical Metallurgy Principles, 2nd ed., Van Nostrand, New York, 1973

    Google Scholar 

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Correspondence to Morteza Zandrahimi.

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Zandrahimi, M., Vatandoost, J. & Ebrahimifar, H. Pack Cementation Coatings for High-Temperature Oxidation Resistance of AISI 304 Stainless Steel. J. of Materi Eng and Perform 21, 2074–2079 (2012). https://doi.org/10.1007/s11665-012-0135-1

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  • DOI: https://doi.org/10.1007/s11665-012-0135-1

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