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Optical properties of CdSxTe1−x polycrystalline thin films

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Abstract

Thin films of CdSxTe1−x (0≤x≤ 1) have been prepared by vacuum evaporation from solid solutions. Rutherford backscattering spectrometry has been used to determine the thickness of the films, which is in the range 8–50 nm, and x-ray diffraction analysis has been used to determine the phase. The refractive index and extinction coefficient of the films has been calculated from reflectance and transmittance measurements for the wavelength region 250–3200 nm. Polynomial functions are given for each sample, which describe the variation in refractive index and extinction coefficient over the entire wavelength range. Least squares fitting to the absorption spectra revealed that the films all have a direct band gap, although photon energies required for indirect transitions have also been found. CdS0.8Te0.2 is found to have the lowest absorption coefficient at energies greater than 2.1 eV.

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References

  1. T. Aramoto et al., Jpn. J. Appl. Phys. 36, 6304 (1997).

    Article  CAS  Google Scholar 

  2. D.W. Lane, K.D. Rogers, J.D. Painter, D.A. Wood, and M.E. Ozsan (Paper presented at European Materials Research Soc. Symp., Strassbourg, France, 1–4 June 1999), accepted for publication in Thin Film Solids.

  3. R.W. Birkmire, B.E. McCandless, and S.S. Hegedus, Int. J. Solar Energy 12, 145 (1992).

    Google Scholar 

  4. I. Clemminck, M. Burgelman, M. Casteleyn, and B. Depuydt, Int. J. Solar Energy 12, 67 (1992).

    Google Scholar 

  5. J.S. Lee and H.B. Im, J. Mater. Sci. 21, 980 (1986).

    Article  CAS  Google Scholar 

  6. K. Ohata, J. Saraie, and T. Tanaka, Jpn. J. Appl. Phys. 12, 1641 (1973).

    Article  CAS  Google Scholar 

  7. R. Hill and D. Richardson, Thin Solid Films 18, 25 (1973).

    Article  CAS  Google Scholar 

  8. R. Radojcuc, A.E. Hill, and M.J. Hampshire, Solar Cells 4, 101 (1981).

    Article  Google Scholar 

  9. D.G. Moon and H.B. Im, Powder Met. 35, 1 (1992).

    Google Scholar 

  10. S.K.J. Al-Ani, M.N. Makadsi, I.K. Al-Shakarchi, and C.A. Hogarth, J. Mater. Sci. 28, 251 (1993).

    Article  CAS  Google Scholar 

  11. R. Pal, J. Dutta, S. Chaundhuri, and A.K. Pal, J. Phys. D: Appl. Phys. 26, 704 (1993).

    Article  CAS  Google Scholar 

  12. D. Richardson and R. Hill, J. Phys. C: Solid State Phys. 5, 821 (1972).

    Article  CAS  Google Scholar 

  13. D. Bonnet and H. Rabenhorst, Proc. Int. Conf. on the Physics and Chemistry of Semiconductor Heterojunction Layer Structures (Budapest, Hungary: Academiai Kiado, 1971), p. 119.

    Google Scholar 

  14. D.A. Wood, K.D. Rogers, D.W. Lane, G.J. Conibeer, and D. Parton, J. Mater. Sci. Lett. 17, 1511 (1998).

    Article  CAS  Google Scholar 

  15. O.S. Heavens, Optical Properties of Thin Solid Films (London: Butterworths, 1955).

    Google Scholar 

  16. E.D. Palik, Handbook of Optical Constants of Solids (London: Academic Press, 1985), pp. 749–763.

    Google Scholar 

  17. D.T.F. Marple and H. Ehrenreich, Phys. Rev. Lett. 8, 87 (1962).

    Article  CAS  Google Scholar 

  18. T.H. Myers, S.W. Edwards, and J.F. Schetzina, J. Appl. Phys. 52, 4231 (1981).

    Article  CAS  Google Scholar 

  19. L. Ward, The Optical Constants of Bulk Materials and Films, 2nd edition (Bristol, U.K. IOP, 1994).

    Google Scholar 

  20. W. Spence, J. Appl. Phys. 38, 3767 (1967).

    Article  CAS  Google Scholar 

  21. T.E. Jenkins, Semiconductor Science, Growth and Characterisation Techniques (London: Prentice Hall International, 1995).

    Google Scholar 

  22. K.D. Rogers, J.D. Painter, D.W. Lane, and M. Healy, J. Electron. Mater. 28, 112 (1999).

    CAS  Google Scholar 

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Wood, D.A., Lane, D.W., Rogers, K.D. et al. Optical properties of CdSxTe1−x polycrystalline thin films. J. Electron. Mater. 28, 1403–1408 (1999). https://doi.org/10.1007/s11664-999-0130-y

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  • DOI: https://doi.org/10.1007/s11664-999-0130-y

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