Skip to main content
Log in

Electrical Impedance of V2O5/POMA Hybrid Film Deposited by Casting for Application in Ammonia Gas Sensor

  • Original Research Article
  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

The sensitivity evaluation of a vanadium pentoxide/poly-o-methoxyaniline hybrid material (V2O5/POMA) using casting deposition for the preparation of an ammonia gas sensor was investigated herein. V2O5/POMA was produced by the intercalation of V2O5 via sol–gel and o-methoxyaniline monomers. V2O5/POMA thin film deposition onto electrodes was performed by casting. The electrical studies confirmed that V2O5/POMA exhibited increased complex impedance as a function of increasing ammonia concentration. The conductivity of the film decreased with increasing ammonia concentration due to the de-doping process. According to theoretical adjustment, a significant increase in the bulk and interfacial electrical resistance in the presence of ammonia was observed. The combination of these effects contributed to the high sensitivity of the prepared film in both the real and imaginary components of the complex impedance for ammonia gas in a range of 0 to 100 ppm, which indicated that the film is a good candidate for use as an ammonia sensing material.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. Evyapan and A.D.F. Dunbar, Appl. Surf. Sci. 362, 191 (2016).

    Article  CAS  Google Scholar 

  2. B. Timmer, W. Olthuis, and A. Van Den Berg, Sensors actuators. B Chem. 107, 666 (2005).

    CAS  Google Scholar 

  3. M.C. de Santos, F.A. dos Santos, F.P. Teixeira, G.E. Gonçalves, A.G.C. Bianchi, and R.F. Bianchi, Polímeros 20, 107 (2010).

    Article  CAS  Google Scholar 

  4. T. Becker, S. Mühlberger, CBv Braunmühl, G. Müller, T. Ziemann, and K.V. Hechtenberg, Sensors Actuators. B Chem. 69, 108 (2000).

    CAS  Google Scholar 

  5. M.A. Sutton, J.W. Erisman, F. Dentener, and D. Möller, Environ. Pollut. 156, 583 (2008).

    Article  CAS  Google Scholar 

  6. S. Helmers, F.H. Top, and L.W. Knapp, J. Iowa Med. Soc. 61, 271 (1971).

    CAS  Google Scholar 

  7. J. Mulder and H. Van Der Zalm, Tijdschr. Voor Soc. Gezondheidszorg 45, 458 (1967).

    Google Scholar 

  8. A.N. Owada, I.A. de Nääs, D.J. de Moura, and M.D.S. Baracho, Eng. Agrícola 27, 611 (2007).

    Article  Google Scholar 

  9. D.M. Xu, M.Y. Guan, Q.H. Xu, and Y. Guo, J. Hazard. Mater. 262, 64 (2013).

    Article  CAS  Google Scholar 

  10. M. Das and D. Sarkar, J. Mater. Sci.: Mater. Electron. 27, 4109 (2016).

    CAS  Google Scholar 

  11. M.O. Diniz, A.F. Golin, M.C. Santos, R.F. Bianchi, and E.M. Guerra, Org. Electron. 67, 215 (2019).

    Article  CAS  Google Scholar 

  12. M.C. Santos, O.H.C. Hamdan, S.A. Valverde, and E.M. Guerra, R. F. Bianchi 65, 116 (2018).

    Google Scholar 

  13. H.P. Oliveira, C.F.O. Graeff, C.A. Brunello, and E.M. Guerra, J. Non. Cryst. Solids 273, 193 (2000).

    Article  CAS  Google Scholar 

  14. E.M. Guerra, C.A. Brunello, C.F.O. Graeff, and H.P. Oliveira, J. Solid State Chem. 168, 134 (2002).

    Article  CAS  Google Scholar 

  15. L.H.C. Mattoso and L.O.S. Bulhoes, Synthesis and characterization of poly (o-anisidine) films. Synth. Metals 52, 171 (1992).

    Article  CAS  Google Scholar 

  16. M.C. Santos, A.G.C. Bianchi, D.M. Ushizima, F.J. Pavinatto, and R.F. Bianchi, Sensors Actuators A Phys. 253, 156 (2017).

    Article  CAS  Google Scholar 

  17. E.M. Guerra, K.J. Ciuffi, and H.P. Oliveira, J. Solid State Chem. 179, 3814 (2006).

    Article  CAS  Google Scholar 

  18. M. P. Regaço, Sensor de Amônia Baseado Em Filmes Finos de Polianilina Para Criadouros de Frango de Corte., Biblioteca Digital de Teses e Dissertações da Universidade de São Paulo (2006)

  19. M. O. Diniz, Filmes Finos Sensíveis à Amonia Baseado Em Poli-o-Metoxianilina (POMA) e Pentóxido de Vanádio (V2O5), Universidade Federal de São João Del Rei (2017)

  20. M.C. Santos, O.H.C. Hamdan, S.A. Valverde, E.M. Guerra, and R.F. Bianchi, Org. Electron. 65, 116 (2019).

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by INEO, FAPEMIG, RQ-MG/FAPEMIG, CNPq, and CAPES.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. M. Guerra.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Diniz, M.O., Coelho, R.S., Bianchi, R.F. et al. Electrical Impedance of V2O5/POMA Hybrid Film Deposited by Casting for Application in Ammonia Gas Sensor. J. Electron. Mater. 50, 450–455 (2021). https://doi.org/10.1007/s11664-020-08587-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11664-020-08587-9

Keywords

Navigation