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Eu2+ and Mn2+ Co-doped BaMgAl10O17 Blue- and Green-Emitting Phosphor: A Luminescence and EPR Study

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Abstract

Eu2+ and Mn2+ co-doped BaMgAl10O17 phosphor has been prepared by a solution combustion method. The structural, morphological and compositional analysis of the BaMgAl10O17:Eu2+ and Mn2+ powders have been studied by x-ray diffraction, scanning electron microscopy and energy dispersive x-ray spectroscopy. The electron paramagnetic resonance (EPR) spectrum exhibited resonance signals with the effective g values of g ≈ 4.88 and g ≈ 1.98. The resonance signal with the effective g value of g ≈ 4.88 is characteristic of Eu2+ ions whereas g ≈ 1.98 is due to Mn2+ ions. The number of spins participating in resonance, Gibbs free energy, magnetic susceptibility, Curie constant, effective magnetic moment, zero-field splitting parameter and hyperfine splitting constant have been evaluated. From optical and EPR correlation, it is inferred that Eu2+ and Mn2+ are present in the BaMgAl10O17 matrix.

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Acknowledgement

This paper was supported by the KU Research Professor Program of Konkuk University.

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Authors and Affiliations

  1. Department of Chemical Engineering, Konkuk University, Seoul, 143-701, South Korea

    Vijay Singh, N. Singh, J. Li & H. Gao

  2. Department of Physics, Government College for Men (Autonomous), Kadapa, 516004, India

    G. Sivaramaiah

  3. Department of Physics, Sri Venkateswara University, Tirupati, 517502, India

    J. L. Rao

  4. Division of Electronics Engineering, Chonbuk National University, Jeonju, Jeonbuk, 561-756, South Korea

    Anoop K. Srivastava

  5. School of Chemical Sciences, North Maharashtra University, Jalgaon, 425001, India

    H. D. Jirimali

  6. Department of Biological Engineering, Konkuk University, Seoul, 143-701, South Korea

    R. Senthil Kumaran

  7. Material Research Laboratory, Sharda University, Greater Noida, U.P., 201310, India

    Pramod K. Singh

  8. Department of Physics, RTM Nagpur University, Nagpur, 440033, India

    S. J. Dhoble

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  1. Vijay Singh
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  2. G. Sivaramaiah
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  9. R. Senthil Kumaran
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Correspondence to Vijay Singh.

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Singh, V., Sivaramaiah, G., Rao, J.L. et al. Eu2+ and Mn2+ Co-doped BaMgAl10O17 Blue- and Green-Emitting Phosphor: A Luminescence and EPR Study. J. Electron. Mater. 45, 2776–2783 (2016). https://doi.org/10.1007/s11664-016-4370-3

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  • DOI: https://doi.org/10.1007/s11664-016-4370-3

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