Abstract
Low-temperature growth of undoped ZnO films with high transparency and low electrical resistance was performed by ion beam sputtering. After systematic testing, resistivity as low as 2.95 × 10−3 Ω cm was obtained at a substrate temperature of 150°C, ion source voltage of 850 V, and ion beam current of 30 mA. The transmittance of the ZnO films was in the range of 85% to 90%. Hall measurements showed that a high mobility of 21.41 cm2/Vs was obtained for films less than 200 nm thick. The related microstructures and physical properties were measured and are discussed.
Similar content being viewed by others
References
D.S. Gingley and C. Bright, MRS Bull. 25, 15 (2000).
I. Hamberg and C.G. Granqvist, J. Appl. Phys. 60, R123 (1986).
M. Yang, J. Feng, G. Li, and Q. Zhang, J. Cryst. Growth 310, 3474 (2008).
T. Koida and M. Kondo, Appl. Phys. Lett. 89, 82104 (2006).
M.A. Martínez, M.T. Gutiérrez, and C. Maffiotte, Surf. Coat. Technol. 110, 68 (1998).
T. Minami, H. Sato, H. Nanto, and S. Takata, Thin Solid Films 176, 277 (1989).
Y. Ma, G.T. Du, S.R. Yang, Z.T. Li, B.J. Zhao, X.T. Yang, T.P. Yang, Y.T. Zhang, and D.L. Liu, J. Appl. Phys. 95, 6268 (2004).
S. Kishimoto, T. Yamamoto, Y. Nakagawa, K. Ikeda, H. Makino, and T. Yamada, Superlattices Microstruct. 39, 306 (2006).
E.L. Papadopoulou, M. Varda, K. Kouroupis-Agalou, M. Androulidaki, E. Chikoidze, P. Galtier, G. Huyberechts, and E. Aperathitis, Thin Solid Films 516, 8141 (2008).
V. Bhosle, A. Tiwari, and J. Narayan, Appl. Phys. Lett. 88, 32106 (2006).
S.B. Zhang, S.-H. Wei, and A. Zunger, Phys. Rev. B 63, 75205 (2001).
T.G. Khulordava, J. Cryst. Growth 117, 366 (1992).
G. Xiong, J. Wilkinson, B. Mischuck, S. Tüzemen, K.B. Ucer, and R.T. Williams, Appl. Phys. Lett. 80, 1195 (2002).
O. Bamiduro, H. Mustafa, R. Mundle, R.B. Konda, and A.K. Pradhan, Appl. Phys. Lett. 90, 252108 (2007).
T. Minami, K. Oohashi, S. Takata, T. Mouri, and N. Ogawa, Thin Solid Films 193–194, 721 (1990)
J.F. Chang, W.C. Lin, and M.H. Hon, Appl. Surf. Sci. 183, 18 (2001).
F. Quaranta, A. Valentini, F.R. Rizzi, and G. Casamassima, J. Appl. Phys. 74, 244 (1993).
R.R. Reeber, J. Appl. Phys. 41, 5063 (1970).
J.H. Edgar, C.A. Carosella, C.R. Eddy Jr., and D.T. Smith, J. Mater. Sci.: Mater. Electron. 7, 247 (1996).
Y.N. Zhao, B. Wang, and Z. He, Vacuum 48, 427 (1997).
C.-C. Lee, J.-C. Hsu, and D.-H. Wong, Appl. Surf. Sci. 171, 151 (2001).
Y. Igasaki and H. Saito, J. Appl. Phys. 69, 2190 (1991).
M. Hiramatsu, K. Imaeda, N. Horio, and M. Nawata, J. Vac. Sci. Technol. A 16, 669 (1998).
Z.L. Pei, X.B. Zhang, G.P. Zhang, J. Gong, C. Sun, R.F. Huang, and L.S. Wen, Thin Solid Films 497, 20 (2006).
J. Lee, D. Lee, D. Lim, and K. Yang, Thin Solid Films 515, 6094 (2007).
M.S. Tokumoto, A. Smith, C.V. Santilli, S.H. Pulcinelli, A.F. Craievich, E. Elkaim, A. Traverse, and V. Briois, Thin Solid Films 416, 284 (2002).
R. Ghosh, D. Basak, and S. Fujihara, J. Appl. Phys. 96, 2689 (2004).
Acknowledgements
This works was financially supported by the National Science Council under Contract Number NSC 97-2221-E-145-001 and by the Center for Nanoscience and Nanotechnology, National Sun Yet-sen University.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Shen, JH., Yeh, SW., Huang, HL. et al. Low-Temperature Preparation of Undoped ZnO Films with High Transparency and Conductivity by Ion Beam Deposition. J. Electron. Mater. 39, 612–618 (2010). https://doi.org/10.1007/s11664-010-1130-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11664-010-1130-7