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Thermodynamic Properties of Liquid Ag-Bi-Sn Alloys

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Abstract

As a promising lead-free solder, the thermodynamic properties of the liquid ternary Ag-Bi-Sn system were investigated. Using an appropriate galvanic cell, the partial free energies of Sn in liquid Ag-Bi-Sn alloys were determined as a function of concentration and temperature. Thermodynamic properties were obtained for 27 alloys. Their composition was situated on three cross sections with the constant ratios of Ag:Bi = 2:1, 1:1, and 1:2. The integral Gibbs free energy and the integral enthalpy for the ternary system at 900 K were calculated by Gibbs–Duhem integration.

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Acknowledgements

Financial support of this investigation from the Austrian Fonds Zur Förderung der Wissenschaftlichen Forschung under Grant No. P16491-N11 and COST 531 is gratefully acknowledged.

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  1. Institut für Anorganische Chemie/Materialchemie, Universität Wien, A-1090, Wien, Austria

    Zuoan Li, Sabine Knott & Adolf Mikula

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  1. Zuoan Li
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  2. Sabine Knott
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  3. Adolf Mikula
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Correspondence to Adolf Mikula.

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Li, Z., Knott, S. & Mikula, A. Thermodynamic Properties of Liquid Ag-Bi-Sn Alloys. J. Electron. Mater. 36, 40–44 (2007). https://doi.org/10.1007/s11664-006-0002-7

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