Abstract
High cleanliness is an important guarantee for the long-service of bearing steel. In this study, the effect of crucible materials on cleanliness and inclusion characteristics of high-nitrogen stainless bearing steel (HNSBS) during vacuum carbon deoxidation was comprehensively investigated by microstructure characterization and thermodynamic analysis. The results showed that the ultimate O contents using MgO·Al2O3, MgO, and ZrO2 (MA, M, and Z) crucibles could be decreased from about 0.0060 to 0.0028, 0.0012, and 0.0022 wt pct, respectively. The ranking of crucible thermodynamic stability during vacuum carbon deoxidation was M < MA < Z, representing the decreasing of oxygen transfer rate due to crucible decomposition. The deoxidation rate of carbon–oxygen reaction increased with the decreasing of CO partial pressure, and the ranking of deoxidation rate using various crucibles was Z < MA < M. Meanwhile, the main oxide inclusions in steel using MA, M, and Z crucibles transformed from Al2O3 to MgO·Al2O3, MgO, and ZrO2, respectively. The area and average size of inclusions in steel using M crucible were smaller than the others owing to the decreasing of large-size Al2O3 inclusions and the increasing of percentage of low-density Mg-containing inclusions, while the existence of high-density ZrO2 inclusions in steel using Z crucible restricted the floating and removal of inclusions. Therefore, MgO crucible was more appropriate to melt high-cleanliness HNSBS with lower O content and fewer deleterious inclusions.
Similar content being viewed by others
Change history
14 June 2023
A Correction to this paper has been published: https://doi.org/10.1007/s11663-023-02831-3
References
H.F. Xu, G.L. Wu, C. Wang, J. Li, and W.Q. Cao: J. Iron Steel Res. Int., 2018, vol. 25, pp. 954–67.
N.B. Dhokey, A. Upadhye, N. Shah, and K.T. Tharian: Mater. Today: Proc., 2021, vol. 43, pp. 3023–29.
H. Feng, Z.H. Jiang, H.B. Li, P.C. Lu, S.C. Zhang, H.C. Zhu, B.B. Zhang, T. Zhang, D.K. Xu, and Z.G. Chen: Corros. Sci., 2018, vol. 144, pp. 288–300.
Y.X. Qiao, Y.G. Zheng, P.C. Okafor, and W. Ke: Electrochim. Acta, 2009, vol. 54, pp. 2298–2304.
H. Feng, H.B. Li, Z.H. Jiang, T. Zhang, N. Dong, S.C. Zhang, P.D. Han, S. Zhao, and Z.G. Chen: Corros. Sci., 2019, vol. 158, p. 108081.
P.C. Lu, H.B. Li, H. Feng, Z.H. Jiang, H.C. Zhu, Z.Z. Liu, and T. He: Metall. Mater. Trans. B, 2021, vol. 52B, pp. 2210–23.
L. Cao, L.G. Zhu, and Z.H. Guo: J. Iron Steel Res. Int., 2022, vol. 30, pp.1–20.
K. Hashimoto, T. Fujimatsu, N. Tsunekage, K. Hiraoka, K. Kida, and E.C. Santos: Mater. Des., 2011, vol. 32, pp. 1605–11.
Z.X. Cao, Z.Y. Shi, F. Yu, G.L. Wu, W.Q. Cao, and Y.Q. Weng: Int. J. Fatigue, 2019, vol. 126, pp. 1–5.
C.Y. Yang, Y.K. Luan, D.Z. Li, and Y.Y. Li: J. Mater. Sci. Technol., 2019, vol. 35, pp. 1298–1308.
G.X. Qiu, D.P. Zhan, L. Cao, and H.S. Zhang: J. Iron Steel Res. Int., 2021, vol. 28, pp. 1168–79.
A.L.V.D. Costa e Silva: J. Mater. Res. Technol., 2019, vol. 8, pp. 2408–22.
H. Feng, H.B. Li, Z.Z. Liu, Z.H. Jiang, P.C. Lu, and T. He: Metall. Mater. Trans. B, 2021, vol. 52B, pp. 3777–87.
P.C. Lu, H.B. Li, H. Feng, Z.H. Jiang, and Y.B. Dai: Metall. Mater. Trans. B, 2022, vol. 53B, pp. 1920–35.
P.V. Sklyuev, V.S. Gulyakov, O.A. Polzunov, and V.E. Sokolov: Met. Sci. Heat Treat., 1982, vol. 24, pp. 774–77.
J.L. Guo, L.H. Zhao, Y.P. Bao, S. Gao, and M. Wang: Int. J. Miner. Metall. Mater., 2019, vol. 26, pp. 681–88.
B.H. Kang, Y.R. Gwak, and K.Y. Kim: Trans. Indian Inst. Met., 2014, vol. 67, pp. 617–22.
H. Ling and L. Zhang: Metall. Mater. Trans. B, 2018, vol. 49B, pp. 2963–68.
P.H. Li, Q.J. Wu, W.H. Hu, and J.S. Ye: J. Iron Steel Res. Int., 2015, vol. 22, pp. 63–67.
Z.L. Xue, Z.B. Li, J.W. Zhang, and Y.L. Gao: J. Iron Steel Res. Int., 2003, vol. 15, pp. 5–8.
J. Feng, Y.P. Bao, X. Wu, and H. Cui: Int. J. Miner. Metall. Mater., 2010, vol. 17, pp. 541–45.
T. Kuwabara, K. Umezawa, K. Mori, and H. Watanabe: Trans. Iron Steel Inst. Jpn., 1988, vol. 28, p. 305.
K. Wang, Y. Wang, J. Xu, W. Xie, T. Chen, and M. Jiang: Metall. Mater. Trans. B, 2022, vol. 53B, pp. 3370–75.
Y. Li, C.Y. Chen, G.Q. Qin, Z.H. Jiang, M. Sun, and K. Chen: Int. J. Miner. Metall. Mater., 2020, vol. 27, pp. 1083–99.
S. Jansson, V. Brabie, and P. Jönsson: Ironmak. Steelmak., 2006, vol. 33, pp. 389–97.
S. Smets, S. Parada, J. Weytjens, G. Heylen, P.T. Jones, M. Guo, B. Blanpain, and P. Wollants: Ironmak. Steelmak., 2003, vol. 30, pp. 293–300.
F. Simbarashe, L. Mykhaylo, W.D. Moegamat, P. Lydia, L. Vladimir, T. Sun, R. Tang, F. Xiao, F.V. Pavel, and T.P. Boris: Mater. Des., 2020, vol. 186, p. 108295.
S.A. Kiseleva, M.I. Vinograd, V.G. Kostogonov, and O.S. Tuchkina: Refractories, 1979, vol. 20, pp. 573–75.
S. Imashuku: Metall. Mater. Trans. B, 2022, vol. 53B, pp. 190–97.
Y. Zhao, L. Wang, C. Chen, J. Li, and X. Li: Ceram. Int., 2023, vol. 49, pp. 117–25.
A.L.V.D. Costa e Silva: J. Mater. Res. Technol., 2018, vol. 7, pp. 283–99.
M. Jiang, X.H. Wang, and J.J. Pak: Metall. Mater. Trans. B, 2014, vol. 45B, pp. 1248–59.
H. Li, Y. Han, H. Feng, G. Zhou, Z. Jiang, M. Cai, Y. Li, and M. Huang: J. Mater. Sci. Technol., 2023, vol. 141, pp. 184–92.
G. Sigworth and J. Elliott: Met. Sci., 1974, vol. 8, pp. 298–310.
Q. Ren, L.F. Zhang, Z.Y. Hu, and L. Cheng: Ironmak. Steelmak., 2021, vol. 48, pp. 191–99.
Y. Ren, L. Zhang, W. Yang, and H. Duan: Metall. Mater. Trans. B, 2014, vol. 45B, pp. 2057–71.
D. Hou, D. Wang, Z. Jiang, T. Qu, and H. Wang: J. Sustain. Metall., 2020, vol. 6, pp. 463–77.
R.M. Geng, J. Li, and C.B. Shi: ISIJ Int., 2021, vol. 61, pp. 1506–13.
S.B. Lee, D. Kim, and J.J. Pak: ISIJ Int., 2009, vol. 49, pp. 337–42.
H. Liu, J. Liu, S. Michelic, F. Wei, C. Zhuang, Z. Han, and S. Li: Ironmak. Steelmak., 2015, vol. 43, pp. 1–9.
C.B. Shi, X.C. Chen, and H.J. Guo: Int. J. Miner. Metall. Mater., 2012, vol. 19, pp. 295–302.
W. Gong, Z.H. Jiang, L.X. Zhang, C.Y. Chen, and Y.W. Dong: Mater. Sci. Eng. A, 2020, vol. 791, p. 139410.
T. Miki: Treatise on Process Metallurgy, Elsevier, Boston, 2014, pp. 557–85.
H. Itoh, M. Hino, and S. Ban-Ya: Metall. Mater. Trans. B, 1997, vol. 28B, pp. 953–56.
H.C. Zhu, H.B. Li, Z.W. Ni, Z.Y. He, Z.H. Jiang, H. Feng, S.C. Zhang, and D.S. Mao: Metall. Mater. Trans. B, 2021, vol. 53B, pp. 50–59.
S. Zhang, J. Yu, H. Li, Z. Jiang, Y. Geng, H. Feng, B. Zhang, and H. Zhu: J. Mater. Sci. Technol., 2022, vol. 102, pp. 105–14.
M. Wakoh and N. Sano: ISIJ Int., 2007, vol. 47, pp. 627–32.
C. Wang, R. Ma, Y. Zhou, Y. Liu, E.F. Daniel, X. Li, P. Wang, J. Dong, and W. Ke: J. Mater. Sci. Technol., 2021, vol. 93, pp. 232–43.
H. Feng, H.B. Li, J. Dai, Y. Han, J.D. Qu, Z.H. Jiang, Y. Zhao, and T. Zhang: Corros. Sci., 2022, vol. 204, p. 110396.
D. Kumar and P.C. Pistorius: Metall. Mater. Trans. B, 2019, vol. 50B, pp. 181–91.
C. Liu, F. Huang, J. Suo, and X. Wang: Metall. Mater. Trans. B, 2016, vol. 47B, pp. 989–98.
S. Zhang, H. Li, M. Ran, Z. Jiang, L. Zheng, H. Feng, J. Yu, and Y. Dai: ISIJ Int., 2022, vol. 62, pp. 2207–16.
S.F. Yang, Q.Q. Wang, L.F. Zhang, J.S. Li, and K. Peaslee: Metall. Mater. Trans. B, 2012, vol. 43B, pp. 731–50.
K. Fujii, T. Nagasaka, and M. Hino: ISIJ Int., 2000, vol. 40, pp. 1059–66.
W.J. Ma, Y.P. Bao, M. Wang, and L.H. Zhao: ISIJ Int., 2014, vol. 54, pp. 536–42.
A.A.B. Sugden and H.K.D.H. Bhadeshia: Metall. Trans. A, 1988, vol. 19, pp. 669–74.
H.S. Kim, C. Chang, and H. Lee: Scr. Mater., 2005, vol. 53, pp. 1253–58.
B.A. Wang, N. Wang, Y.J. Yang, H. Zhong, M.Z. Ma, X.Y. Zhang, and R.P. Liu: Trans. Nonferrous Met. Soc. China, 2018, vol. 28, pp. 1132–40.
Acknowledgments
This research was sponsored by the National Natural Science Foundation of China [Grant Nos. U1960203/52004060/52174308], China Postdoctoral Science Foundation [Grant No. 2020M670775], Talent Project of Revitalizing Liaoning [Grant No. XLYC1902046], Northeastern University Postdoctoral Funds [Grant No. 20200101], Fundamental Research Funds for the Central Universities [Grant Nos. N2125017/N2225031], Program of Introducing Talents of Discipline to Universities [Grant No. B21001], and Elite Program of Southern Taihu Lake.
Conflict of interest
On behalf of all authors, the corresponding author states that there is no conflict of interest.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Manuscript submitted August 25, 2022, accepted January 28, 2023.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Li, HB., Lu, PC., Feng, H. et al. Influence Mechanism of Crucible Materials on Cleanliness and Inclusion Characteristics of High-Nitrogen Stainless Bearing Steel During Vacuum Carbon Deoxidation. Metall Mater Trans B 54, 1099–1112 (2023). https://doi.org/10.1007/s11663-023-02743-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11663-023-02743-2