Abstract
The behavior of the interface between molten Sn and the LiCl–KCl eutectic melt system was observed directly. We found that the transient behavior of the interface exhibits considerable temperature dependence through a change in its physical properties. The “metal film” generated in the upper molten salt phase significantly influences the shape of the interface. Although the lifetime of the metal film depends on the gas flow rate, it is not affected by the buoyancy if the interfacial tension is dominant.
Similar content being viewed by others
References
D. Mazumdar, and R. I. L Guthrie: ISIJ Int., 1995, vol. 35, pp. 1–20.
G. Kaptay: Metall. Mater. Trans. B, 2001, vol. 32, pp. 555–557.
Subagyo and G.A. Brooks: ISIJ Int., 2002, vol. 42, pp. 1182–1184.
N. Dogan, G. A. Brooks, and M. A. Rhamdhani: ISIJ Int., 2011, vol. 51, pp. 1093–1101.
B. S. Terry, and P. Grieveson: ISIJ Int., 1993, vol. 33, pp. 166–175.
R. Minto, and W. G. Davenport: Can. Mining Metall. Bull., 1972, vol. 65, pp. 70–76.
G. Reiter, and K. Schwerdtfeger: ISIJ Int., 1992, vol. 32, pp. 50–56.
G. Reiter, and K. Schwerdtfeger: ISIJ Int., 1992, vol. 32, pp. 57–65.
Z. Lin, and R. I. L. Guthrie: Metall. Mater. Trans. B, 1994, vol. 25, pp. 855–864.
K. Sakaguchi, and K. Ito: ISIJ Int., 1995, vol. 35, pp. 1348–1353.
A. Kumar, M. Malathi, K. M. Godiwalla, E. Z. Chacko, S. K. Ajmani, and S. Ranganathan: ISIJ Int., 2014, vol. 54, pp. 2239–2247.
V. F. Chevrier, and A. W. Cramb: Metall. Mater. Trans. B, 2000, vol. 31, pp. 537–540.
M. Iguchi, T. Chihara, N. Takanashi, Y. Ogawa, N. Tokumitsu, and Z. I. Morita: ISIJ Int., 1995, vol. 35, pp. 1354–1361.
P. K. Iwamasa, and R. J. Fruehan: ISIJ Int., 1996, vol. 36, pp. 1319–1327.
Z. Han, and L. Holappa: Metall. Mater. Trans. B, 2003, vol. 34, pp. 525–532.
Z. Han, and L. Holappa: ISIJ Int., 2003, vol. 43, pp. 292–297.
L. Holappa, L. Forsbacka, and Z. Han: ISIJ Int., 2006, vol. 46, pp. 394–399.
D. Poggi, R. Minto, and G. Davenport: J. Met., 1969, vol. 21, pp. 40–45.
D. Y. Song, N. Maruoka, T. Maeyama, H. Shibata, and S. Y. Kitamura: ISIJ Int., 2010, vol. 50, pp. 1539–1545.
D. Y. Song, N. Maruoka, G. S. Gupta, H. Shibata, S. Y. Kitamura, and S. Kamble: Metall. Mater. Trans. B, 2012, vol. 43, pp. 973–983.
J. R. Grace, Trans. Inst. Chem. Eng., 1973, vol. 51, pp. 116–120.
Z. Yuan, K. Mukai, K. Takagi, and M. Ohtaka: J. Japan Inst. Metals, 2001, vol. 65, pp. 21–28.
L. Wang and Q. Mei: J. Mater. Sci. Technol., 2006, vol. 22, pp. 569–571.
E. V. Rozhitsina, S. Gruner, I. Kaban, W. Hoyer, V. E. Sidorov, and P. S. Popel: Russ. Metall. (Metally), 2011, vol. 2011, pp. 118–121.
G. J. Janz, R. P. T. Tomkins, C. B. Allen, J. R. Downey Jr., G. L. Garner, U. Krebs, and S. K. Singer: J. Phys. Chem. Ref. Data, 1975, vol. 4, pp. 871–1178.
S. Natsui, H. Takai, T. Kumagai, T. Kikuchi, R. O. Suzuki: Mater. Trans., 2014, vol. 55, pp. 1707–1715.
S. Natsui, R. Nashimoto, H. Takai, T. Kumagai, T. Kikuchi, and R. O. Suzuki, Chem. Eng. Sci., 2016, vol. 141, pp. 342–355.
P. de Gennes, F. Brochard–Wyart, and D. Quéré: Capillarity and Wetting Phenomena: Drops, Bubbles, Pearls, Waves, Yosioka Shoten, Kyoto, 2003, pp. 210–212.
This study was supported by the Japan Oil, Gas, and Metals National Corporation (JOGMEC).
Author information
Authors and Affiliations
Corresponding author
Additional information
Manuscript submitted July 3, 2015.
Rights and permissions
About this article
Cite this article
Natsui, S., Nashimoto, R., Takai, H. et al. Temperature Dependence of Behavior of Interface Between Molten Sn and LiCl–KCl Eutectic Melt Due to Rising Gas Bubble. Metall Mater Trans B 47, 1532–1537 (2016). https://doi.org/10.1007/s11663-016-0618-9
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11663-016-0618-9