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Activity Measurement for the FeCl2-ZnCl2 System

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Abstract

The solubilities of Fe and Zn in a Bi melt in equilibrium with a FeCl2-ZnCl2 melt were measured by the isopiestic method at 917 K. The activities of FeCl2 and ZnCl2 for the FeCl2-ZnCl2 system were calculated from the solubilities of Fe and Zn in the Bi melt using the Belton–Fruehan treatment. The activities for the FeCl2-ZnCl2 system show a negative deviation from Raoult’s law. These results are in good agreement with the previously reported data determined by the transpiration method.

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Author notes

  1. Sang Han Son (formerly Graduate Student, Researcher)

    Present address: Ironmaking Research Group, Technical Research Labs., POSCO, Pohang, 790-785, Korea

Authors and Affiliations

  1. Department of Materials Engineering, The University of Tokyo, Chiba, 277-8561, Japan

    Sang Han Son (formerly Graduate Student, Researcher)

  2. Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, Chiba, 277-8561, Japan

    Fumitaka Tsukihashi (Professor)

Authors
  1. Sang Han Son
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  2. Fumitaka Tsukihashi
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Correspondence to Fumitaka Tsukihashi.

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Manuscript submitted December 10, 2006.

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Son, S., Tsukihashi, F. Activity Measurement for the FeCl2-ZnCl2 System. Metall Mater Trans B 38, 665–670 (2007). https://doi.org/10.1007/s11663-007-9069-7

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  • DOI: https://doi.org/10.1007/s11663-007-9069-7

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