Skip to main content

Advertisement

SpringerLink
Log in

Interfacial kinetics of hydrogen with liquid slag containing iron oxide

  • Published:
Metallurgical and Materials Transactions B Aims and scope Submit manuscript

Abstract

Interfacial kinetics on the hydrogen reduction of liquid Fe t O in Fe t O-M x O y slag (M x O y = CaO, SiO2, Al2O3, and TiO2) has been studied at 1673 K. Because the rate of hydrogen reduction was very fast, the rate was controlled by gas-phase mass transfer under most of the experimental conditions. The effect of CaO or SiO2 addition on the interfacial chemical reaction rate of hydrogen reduction was empirically evaluated as a function of the ferrous-ferric ratio in the slag. The observed interfacial chemical reaction rates in Fe t O-CaO and Fe t O-SiO2 slags showed reasonable agreement with the estimated values. Most of the available literature data on the reduction rate of liquid iron oxide by solid carbon, hot metal, and reducing gases were also reviewed and compared with the results of the present work. It was found that the rate of hydrogen reduction of liquid iron oxide slag is much faster than that with other reducing agents such as solid carbon, carbon dissolved in the liquid iron, and CO gas.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. Nagasaka and S. Ban-ya: Tetsu-to-Hagané, 1992, vol. 78, pp. 1753–67.

    CAS  Google Scholar 

  2. T. Nagasaka, Y. Iguchi, and S. Ban-ya: Tetsu-to-Hagané, 1985, vol. 71, pp. 204–11.

    CAS  Google Scholar 

  3. T. Nagasaka, Y. Iguchi, and S. Ban-ya: Process Technol. Proc., ISS-AIME, Warrendale, PA, 1986, vol. 6, pp. 669–78.

    Google Scholar 

  4. T. Nagasaka, Y. Iguchi, and S. Ban-ya: Tetsu-to-Hagané, 1989, vol. 75, pp. 74–81.

    CAS  Google Scholar 

  5. H. Katayama, S. Taguchi, and N. Tsuchiya: Tetsu-to-Hagané, 1982, vol. 68, pp. 2279–86.

    CAS  Google Scholar 

  6. S. Ban-ya, Y. Iguchi, and T. Nagasaka: Tetsu-to-Hagané, 1984, vol. 70, pp. 1689–96.

    CAS  Google Scholar 

  7. S. Hayashi and Y. Iguchi: Iron Steel Inst. Jpn. Int., 1994, vol. 34, pp. 555–61; 1995, vol. 35, pp. 242–49.

    CAS  Google Scholar 

  8. S. Taniguchi, A. Kikuchi, and S. Maeda: Tetsu-to-Hagané, 1976, vol. 62, pp. 191–200; 1977, vol. 63, pp. 1071–80.

    CAS  Google Scholar 

  9. A. Kikuchi, S. Taniguchi, and K. Arai: Proc. 95th Annual Meeting of Japan Institute of Metals, Sendai, Japan, 1984, Japanese Institute for Metals, Sendai, Japan, p. 474.

    Google Scholar 

  10. R.B. Bird, W.E. Steward, and E.N. Lightfoot: Transport Phenomena, John Wiley & Sons Inc., New York, NY, 1960, p. 569.

    Google Scholar 

  11. F. Tsukihashi, K. Kato, K. Ohtsuka, and T. Soma: Trans. Iron Steel Inst. Jpn., 1982, vol. 22, pp. 688–95.

    Google Scholar 

  12. Y. Sasaki, S. Hara, D.R. Gaskell, and G.R. Belton: Metall. Trans. B, 1984, vol. 15B, pp. 563–71.

    CAS  Google Scholar 

  13. S.K. El-Rahaiby, Y. Sasaki, D.R. Gaskell, and G.R. Belton: Metall. Trans. B, 1986, vol. 17B, pp. 307–16.

    CAS  Google Scholar 

  14. H.A. Fine, D. Meyer, D. Janke, and H.-J. Engell: Ironmaking and Steelmaking, 1985, vol. 12, pp. 157–62.

    CAS  Google Scholar 

  15. M. Mori, K. Morita, and N. Sano: Iron Steel Inst. Jpn., 1996, vol. 36, pp. 624–30.

    CAS  Google Scholar 

  16. S. Ban-ya, A. Chiba, and A. Hikosaka: Tetsu-to-Hagané, 1980, vol. 66, pp. 1484–93.

    CAS  Google Scholar 

  17. G.R. Belton: Metall. Trans. B, 1993, vol. 24B, pp. 241–58; G.R. Belton and R.J. Fruehan: Proc. E.T. Turkdogan Symp., Pittsburgh, PA, 1994, ISS, Warrendale, PA, 1994, pp. 3–22.

    CAS  Google Scholar 

  18. P.C. Glaws and G.R. Belton: Metall. Trans. B, 1990, vol. 21B, pp. 511–19.

    CAS  Google Scholar 

  19. D.I. Ryzenkov, D.M. Golenko, and L.M. Chelyadunov: Izv. VUZ Chern. Met., 1960, No. 4, pp. 19–22.

  20. V.V. Kondakov, D.I. Ryzenkov, and D.M. Golenko: Izv. VUZ Chern. Met., 1960, No. 4, pp. 23–28.

  21. K. Takahashi, M. Amatatsu, and T. Soma: Tetsu-to-Hagané, 1975, vol. 61, pp. 2525–30.

    CAS  Google Scholar 

  22. Y. Sasaki, K. Okamoto, and T. Soma: Tetsu-to-Hagané, 1978, vol. 64, pp. 367–75; Y. Sasaki and T. Soma, Tetsu-to-Hagané, 1978, vol. 64, pp. 376–84.

    Google Scholar 

  23. F. Tsukihashi, M. Amatatsu, and T. Soma: Tetsu-to-Hagané, 1982, vol. 68, pp. 1880–88.

    CAS  Google Scholar 

  24. A. Sato, G. Aragane, K. Kamihira, and S. Yoshimatsu: Tetsu-to-Hagané, 1987, vol. 73, pp. 812–19.

    CAS  Google Scholar 

  25. T.E. Dancy: J. Iron Steel Inst., 1951, vol. 169, pp. 17–24.

    CAS  Google Scholar 

  26. D.R. MacRae: J. Met., 1965, vol. 17, pp. 1391–95.

    CAS  Google Scholar 

  27. G.W. Lloyd, D.R. Young, and L.A. Baker: Ironmaking and Steelmaking, 1975, vol. 2, pp. 49–55.

    CAS  Google Scholar 

  28. A. Sato, R. Nakagawa, S. Yoshimatsu, A. Fukuzawa, and F. Ozaki: Tetsu-to-Hagané, 1981, vol. 67, pp. 303–12.

    CAS  Google Scholar 

  29. K. Kato, Y. Sasaki, and T. Soma: Trans. Iron Steel Inst. Jpn., 1977, vol. 17, pp. 532–33.

    CAS  Google Scholar 

  30. T. Soma: Bull. Jpn. Inst. Met., 1982, vol. 21, pp. 620–25.

    CAS  Google Scholar 

  31. J. Wegrzyn and L. Krol: Steel Res., 1998, vol. 69, pp. 33–40.

    CAS  Google Scholar 

  32. K. Koch, U. Harter, and R. Bruckhaus: Steel Res., 1989, vol. 60, pp. 171–75; 1990, vol. 61, pp. 14–20.

    CAS  Google Scholar 

  33. Y. Nakamura, M. Ito, and H. Ishikawa: Tetsu-to-Hagané, 1980, vol. 66, pp. 2100–05.

    CAS  Google Scholar 

  34. K. Kamiya, N. Kitamura, and I Morinaka: Tetsu-to-Hagané, 1982, vol. 68, pp. 956–64.

    CAS  Google Scholar 

  35. M. Lemperle and A. Weigel: Steel Res., 1985, vol. 56, pp. 465–69.

    CAS  Google Scholar 

  36. G.S. Ershov and Y.A. Popova: Izv. Akad. Nauk. SSSR Met. Gorn. Delo, 1964, No. 1, pp. 32–34.

  37. H. Krainer and H.P. Beer: Tech. Mitt. Krupp Forschungsberg, 1966, vol. 24, pp. 136–46.

    Google Scholar 

  38. M.W. Davies, P.N. Smith, and G.S.F. Hazeldean: Proc. The Richardson Conf., H.E. Jeffes, ed., BSC, Sheffield, United Kingdom, 1973, pp. 95–107.

    Google Scholar 

  39. M. Sugata, T. Sugiyama, and S. Kondo: Trans. Iron Steel Inst. Jpn., 1974, vol. 14, pp. 88–95.

    Google Scholar 

  40. C. Borgianni: Ironmaking and Steelmaking, 1978, vol. 5, pp. 61–66.

    CAS  Google Scholar 

  41. S. Hara and K. Ogino: Tetsu-to-Hagané, 1990, vol. 76, pp. 360–67.

    CAS  Google Scholar 

  42. T.A. Utigard, G. Sanchez, J. Manriquez, A. Luraschi, C. Diaz, D. Cordero, and E. Almendras: Metall. Trans. B, 1997, vol. 28B, pp. 821–26.

    Article  CAS  Google Scholar 

  43. A. Warczkov and T.A. Utigard: Can. Metall. Q., 1998, vol. 37, pp. 27–39.

    Article  Google Scholar 

  44. W.O. Philbrook and L.D. Kirkbride: J. TMS-AIME, 1956, vol. 206, pp. 351–56.

    Google Scholar 

  45. V.V. Kondakov and D.I. Ryzenkov: Izv. VUZ Chern. Met., 1963, No. 1, pp. 31–38.

  46. S.V. Shavrin and I.N. Zakharov: Izv. VUZ. Chern. Met., 1964, vol. 5, pp. 7–9; Izv. Akad. Nauk. SSSR Met. Gorn. Delo, 1964, vol. 2, pp. 31–37.

    Google Scholar 

  47. P.M. Shurygin, V.N. Boronenkov, V.I. Kryuk, and V.V. Rovebtsov: Izv. VUZ Chern. Met., 1965, vol. 8, pp. 23–28.

    CAS  Google Scholar 

  48. S.K. Terby and W.O. Philbrook: Trans. TMS-AIME, 1967, vol. 239, pp. 1005–17.

    Google Scholar 

  49. F. Fun: Metall. Trans., 1970, vol. 1, pp. 2537–41.

    CAS  Google Scholar 

  50. V.N. Boronenkov, O.A. Esin, and S.A. Lyamkin: Russ. Metall., 1972, No. 1, pp. 17–27.

  51. A. Sato, G. Aragane, F. Hirose, R. Nakagawa, and S. Yoshimatsu: Tetsu-to-Hagané, 1983, vol. 69, pp. 384–91.

    CAS  Google Scholar 

  52. B. Sarma, A.W. Cramb, and R.J. Fruehan: Metall. Mater. Trans. B, 1996, vol. 27B, pp. 717–30.

    Article  CAS  Google Scholar 

  53. M.P. Shalimov, V.N. Boronenkov, and S.A. Lyamkin: Russ. Metall., 1980, vol. 6, pp. 31–34.

    Google Scholar 

  54. M.S. Bafgi and M. Sano: Iron Steel Inst. Jpn. Int., 1992, vol. 32, pp. 1084–90 and 1280–86.

    Google Scholar 

  55. I.D. Sommerville, P. Grieveson, and J. Taylor: Ironmaking and Steelmaking, 1980, vol. 7, pp. 25–32; K. Upadhya, I.D. Sommerville, and P. Grieveson: Ironmaking and Steelmaking, 1980, vol. 7, pp. 33–36.

    CAS  Google Scholar 

  56. M. Hacioglu and R.J. Pomfret: Proc. Int. Symp. on Physical Chemistry of Iron and Steel Making, CIM, Toronto, 1982, pp. 27–39.

    Google Scholar 

  57. D.J. Min and R.J. Fruehan: Metall. Trans. B, 1992, vol. 23B, pp. 29–37.

    CAS  Google Scholar 

  58. R.K. Paramguru, H.S. Ray, and P. Basu: Iron Steel Inst. Jpn. Int., 1997, vol. 37, pp. 756–61.

    CAS  Google Scholar 

  59. S.R. Story, B. Sarma, R.J. Fruehan, A.W. Cramb, and G.R. Belton: Metall. Mater. Trans. B, 1998, vol. 29B, pp. 929–32.

    CAS  Google Scholar 

Download references

Author information

Author notes

  1. Shiro Ban-Ya (Professor Emeritus, President)

    Present address: Akita National College of Technology, 011, Akita, Japan

Authors and Affiliations

  1. the Department of Metallurgy, Graduate School of Engineering, Tohoku University, 980-8579, Sendai, Japan

    Tetsuya Nagasaka (Associate Professor) & Mitsutaka Hino (Professor)

  2. Iohoku University and Akita National College of Technology, Japan

    Shiro Ban-Ya (Professor Emeritus, President)

Authors
  1. Tetsuya Nagasaka
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mitsutaka Hino
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Shiro Ban-Ya
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

This article is based on a presentation made in the “Geoffrey Belton Memorial Symposium,” held in January 2000, in Sydney, Australia, under the joint sponsorship of ISS and TMS.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nagasaka, T., Hino, M. & Ban-Ya, S. Interfacial kinetics of hydrogen with liquid slag containing iron oxide. Metall Mater Trans B 31, 945–955 (2000). https://doi.org/10.1007/s11663-000-0071-6

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11663-000-0071-6

Keywords

Search

Navigation