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Influence of annealing on depth distributions and microstructure of ion-implanted Ti6Al4V

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Abstract

Ti6Al4V alloy was ion implanted with carbon, nitrogen, platinum, or gold. The effect of heat treatment at 500°C on the depth distributions of oxygen and implanted atoms was investigated using backscattering spectrometry. The phases in the near-surface region were determined using transmission electron microscopy (TEM) and X-ray diffraction (XRD). Platinum and gold are enriched in both α- and β-titanium solid solutions. Implanted carbon forms titanium carbide at lower concentration than nitrogen forms titanium nitride. The depth profiles of Au, Pt, and N are not altered by annealing. Implanted carbon as well as oxygen diffuse to larger depth upon heat treatment. Noble metal-implanted layers are permeable to oxygen diffusion. At concentrations exceeding 35 at. pct, implanted carbon and nitrogen act as a diffusion barrier for oxygen.

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References

  1. M. Semlitsch: Clin. Mater., 1997, vol. 1, pp. 1–13.

    Google Scholar 

  2. S. Nasser, P.A. Campbell, D. Kilgus, N. Kossovsky, and H.C. Amstutz: Clin. Orthop., 1990, vol. 261, pp. 171–85.

    Google Scholar 

  3. W.C. Oliver, R. Hutchings, and J.B. Pethica: Metall. Trans. A, 1984, vol. 15A, pp. 2221–29.

    CAS  Google Scholar 

  4. H. Schmidt, H.E. Exner, D.M. Ruck N. Angert, and U. Fink: in Advances in Materials Science and Implant Orthopedic Surgery, R. Kossowsky and N. Kossovsky, eds., Kluwer, Dordrecht, 1995, pp. 207–21.

    Google Scholar 

  5. H. Schmidt, A. Schminke, and D.M. Ruck: Wear, 1997, vol. 209, pp. 49–56.

    Article  CAS  Google Scholar 

  6. X. Qiu, J.R. Conrad, R.A. Dodd, and F.J. Worzala: Metall. Trans. A, 1990, vol. 21A, pp. 1663–67.

    CAS  Google Scholar 

  7. R. Martinella, S. Giovanardi, G. Chevallard, M. Villani, A. Molinari, and C. Tosello: Mater. Sci. Eng., 1985, vol. 69, pp. 247–52.

    Article  CAS  Google Scholar 

  8. R.G. Vardiman: Materials Research Society Symposia Proceedings, G.K. Hubler, O.W. Holland, C.R. Clayton, and C.W. White, eds., Materials Research Society, Pittsburgh, PA, 1984, vol. 27, pp. 699–704.

    Google Scholar 

  9. R.N. Bolster, I.L. Singer, and R.G. Vardiman: Surf. Coat. Technol., 1987, vol. 33, pp. 469–77.

    Article  CAS  Google Scholar 

  10. G. Farges, J.C. Pivin, and F. Pons: Surf. Coat. Technol., 1988, vol. 35, pp. 231–39.

    Article  CAS  Google Scholar 

  11. M. Guemmaz, A. Mosser, L. Boudoukha, J.J. Grob, D. Raiser, and J.C. Sens: Nucl Instr. Meth. B, 1996, vol. B111, pp. 263–70.

    Article  Google Scholar 

  12. P. Zheng, J.C. Pivin, and M.O. Ruault: Europhys. Lett., 1988, vol. 6, pp. 689–94.

    CAS  Google Scholar 

  13. D. Krupa, E. Jezierska, J. Baszkiewicz, M. Kaminski, T. Wierzchon, and A. Barcz: Surf. Coat. Technol., 1996, vol. 79, pp. 240–45.

    Article  CAS  Google Scholar 

  14. R. Hutchings: Mater. Sci. Eng., 1985, vol. 69, pp. 129–38.

    Article  CAS  Google Scholar 

  15. X. Qiu, R.A. Dodd, J.R. Conrad, A. Chen, and F.J. Worzala: Nucl. Instr. Meth. B, 1991, vols. B59-B60, pp. 951–56.

    Article  Google Scholar 

  16. R.G. Vardiman: Def. Diffus. Forum, 1988, vols. 57–58, pp. 135–42.

    Article  Google Scholar 

  17. R.G. Vardiman and R.A. Kant: J. Appl. Phys., 1982, vol. 53, pp. 690–94.

    Article  CAS  Google Scholar 

  18. A. Wenzel, C. Hammerl, A. Koniger, and B. Rauschenbach: Nucl. Instr. Meth. B, 1997, vol. B129, pp. 369–76.

    Article  Google Scholar 

  19. Y. Sugizaki, T. Yasunaga, and H. Satoh: Nucl. Instr. Meth. B, 1993, vols. B80–B81, pp. 279–84.

    Article  Google Scholar 

  20. Y. Sugizaki, T. Yasunaga, and H. Tomari: Surf. Coat. Technol., 1996, vol. 83, pp. 167–74.

    Article  CAS  Google Scholar 

  21. N.D. Tomashov, M.I. Guseva, G.A. Fedoseeva, A.E. Gorodetskil, A.P. Zakharov, D.B. Bogomolov, G.P. Chernova, B.G. Vladimirov, and S.M. Ivanov: Sov. Phys. Dokl., 1981, vol. 26, pp. 222–24.

    Google Scholar 

  22. M.T. Pham, I. Zyganow, W. Matz, H. Reuther, S. Oswald, E. Richter, and E. Wieser: Thin Solid Films, 1997, vol. 310, pp. 251–59.

    Article  CAS  Google Scholar 

  23. A.D. Marwick: Metall. Trans. A, 1989, vol. 20A, pp. 2627–36.

    Google Scholar 

  24. J.A. Leavitt, L.C. McIntyre, and M.R. Weller: in Handbook of Modern Ion Beam Materials Analysis, J.R. Tesmer and M. Nastasi, eds., Materials Research Society, Pittsburgh, PA, 1995, pp. 37–81.

    Google Scholar 

  25. L.R. Doolittle: Nucl. Instr. Meth. B, 1985, vol. B9, pp. 344–51.

    Article  CAS  Google Scholar 

  26. Y. Feng, Z. Zhou, Y. Zhou, and G. Zhao: Nucl. Instr. Meth. B, 1994, vol. B86, pp. 225–30.

    Article  Google Scholar 

  27. J. Kempter, H. Baumann and K. Bethge: in Annual Report 1996 of the Institute for Nuclear Physics Frankfurt, Institute for Nuclear Physics, Frankfurt, 1997, p. 55 (in German).

    Google Scholar 

  28. F.J.D. Almeida, J.A. Davies, and T.E. Jackman: Nucl. Instr. Meth. B, 1993, vol. B82, pp. 393–98.

    Article  Google Scholar 

  29. M. Ask, J. Lausmaa, and B. Kasemo: Appl. Surf. Sci., 1988–89, vol. 35, pp. 283–301.

    Article  Google Scholar 

  30. T.B. Massalski: Binary Alloy Phase Diagrams, ASM, Metals Park, OH, 1986.

    Google Scholar 

  31. J.-P. Bars, D. David, E. Etchessahar, and J. Debuigne: Metall. Trans. A, 1983, vol. 14A, pp. 1537–43.

    CAS  Google Scholar 

  32. E.A. Brandes and G.B. Brook: Smithells Metals Reference Book, Butterworth and Co., Oxford, United Kingdom, 1992.

    Google Scholar 

  33. L.E. Toth: Transition Metal Carbides and Nitrides, Academic Press, New York, NY, 1971.

    Google Scholar 

  34. O. Knotek, M. Bohmer, and T. Leyendecker: J. Vac. Sci. Technol. A, 1986, vol. A4, pp. 2695–2700.

    Article  Google Scholar 

  35. W. Lengauer and P. Ettmayer: J. Less-Common Met., 1986, vol. 120, pp. 153–59.

    Article  CAS  Google Scholar 

  36. W. Lengauer: J. Less-Common Met., 1986, vol. 125, pp. 127–34.

    Article  CAS  Google Scholar 

  37. J.L. Bocquet, G. Brebec, and Y. Limoge: in Physical Metallurgy, Fourth Edition. R.W. Cahn and P. Haasen, eds., Elsevier, Amsterdam, 1995, pp. 535–668.

    Google Scholar 

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Schmidt, H., Miehe, G., Schminke, A. et al. Influence of annealing on depth distributions and microstructure of ion-implanted Ti6Al4V. Metall Mater Trans A 30, 2121–2127 (1999). https://doi.org/10.1007/s11661-999-0023-y

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