Abstract
The abnormal precipitation of Ti2Ni arising from compositional inhomogeneity leads to the formation of α-laths in powder metallurgy Ti–Ni alloys. This exacerbates the detrimental effect of eutectoid on ductility. Herein, we have developed a uniform Ni-coated Ti powder to obtain rapid compositional homogeneity during sintering process. This rectified the abnormal eutectoid reaction pathway, enabling us to obtain fully equiaxed α-Ti grains. Consequently, the equiaxed microstructure effectively counteracted the degradation in ductility caused by brittle eutectoid.
Graphical Abstract
References
Z.Z. Fang, J.D. Paramore, P. Sun, K.S.R. Chandran, Y. Zhang, Y. Xia, F. Cao, M. Koopman, and M. Free: Int. Mater. Rev, 2017, vol. 63, pp. 459–07.
H. Liu, D.P. Bishop, and K.P. Plucknett: Mater. Sci. Eng. A, 2015, vol. 644, pp. 404–92.
H. Donthula, B. Vishwanadh, T. Alam, T. Borkar, R.J. Contieri, R. Caram, R. Banerjee, R. Tewari, G.K. Dey, and S. Banerjee: Acta. Mater., 2019, vol. 168, pp. 75–63.
Y.X. Mu, P.W. Xu, Y. Liang, S. Xiang, and C.H. Yin: Mater. Sci. Eng. A, 2022, vol. 851, 143642.
Y.F. Yang, M. Yan, S.D. Luo, G.B. Schaffer, and Q. Ma: J. Alloys Compd., 2013, vol. 579, pp. 557–53.
E.I. Galindo-Nava and P.E.J. Rivera-Díaz-del-Castillo: Acta Mater., 2015, vol. 98, pp. 93–81.
Y. Chong, R. Zheng, G. Deng, A. Shibata, and N. Tsuji: Metall. Mater. Trans. A, 2020, vol. 51, pp. 2862–51.
H.J. Lee and H.I. Aaronson: J. Mater. Sci., 1988, vol. 23, pp. 160–50.
A. Durgaprasad, S. Giri, S. Lenka, S. Kundu, S. Mishra, S. Chandra, R.D. Doherty, and I. Samajdar: Acta Mater., 2017, vol. 129, pp. 289–78.
S. Gaurav and R. Upadrasta: Prog. Mater. Sci., 2020, vol. 111, 100653.
R.A. Mohammad, M.M. Homayoun, H. Amir, and S.K. Hyoung: Prog. Mater. Sci., 2022, vol. 127, p. 10093.
Y. Chong, R. Gholizadeh, T. Tsuru, R.P. Zhang, K. Inoue, W.Q. Gao, A. Godfrey, M. Mitsuhara, J.W. MorrisJr, A.M. Minor, and N. Tsuji: Nat. Commun., 2023, vol. 14, p. 404.
M.X. Zhang and P.M. Kelly: Prog. Mater. Sci., 2009, vol. 54, pp. 1170–101.
Y.F. Yang, S.D. Luo, C.J. Bettles, G.B. Schaffer, and M. Qian: Mater. Sci. Eng. A, 2011, vol. 528, pp. 7387–381.
F.H. Froes: Titanium Physical Metallurgy Processing and Applications, ASM International, Ohio, 2015.
X. Zhou, X.Y. Li, and K. Lu: Science, 2018, vol. 360, pp. 530–26.
Y.F. Yang and Q. Ma: Metall. Mater. Trans. A, 2018, vol. 49, pp. 6–11.
C. Tan, S.F. Li, and Y.F. Yang: Metall. Mater. Trans. A, 2018, vol. 49, pp. 3401–394.
K.N. Campo, L. Fanton, M.G.D. Mello, S.C. Moon, R. Dippenaar, and R. Caram: Mater. Charact., 2020, vol. 159, 110013.
W.W. Mullins: J. Appl. Phys., 1957, vol. 195728, pp. 333–39.
E. Rabkin and L. Klinger: Metall. Res. Technol., 2001, vol. 98, pp. 1059–64.
R.L. Fullman: J. Appl. Phys., 1951, vol. 22, pp. 448–55.
Acknowledgments
This work was supported by the National Natural Science Foundation of China (Nos. 52074254, 52174349 and 52204377), the Key Projects of International Cooperation (No. 122111KYSB20200034), the CAS Project for Young Scientists in Basic Research (YSBR-025), and the Project of Key Laboratory of Science and Technology on Particle Materials (No. CXJJ-22S043), Chinese Academy of Sciences. The authors are grateful to R.D.K. Misra for careful reading, review, and editing of the study described here.
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Conflict of Interest
The authors declare that they have no conflict of interests.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Gan, X.M., Li, S.F., Wang, S.X. et al. Ductile Ti–Ni Alloys With an Equiaxed Microstructure Designed by Tuning the Precipitation Pathway of Ti2Ni. Metall Mater Trans A 54, 4208–4214 (2023). https://doi.org/10.1007/s11661-023-07179-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11661-023-07179-6