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Investigation on Corrosion Behavior of Simulated Welding HAZ for 22 pct Cr Lean Duplex Stainless Steel With Different Mn/N Ratio Addition

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Abstract

To improve the corrosion resistance of the welding heat-affected zone (HAZ) of 22 pct Cr lean duplex stainless steel (DSS), the matching of Mn, N compositions, and welding heat inputs were investigated with different Mn/N ratio addition. The average pitting potential of HAZ increased first and then decreased rapidly with increasing Mn/N ratio from 3.28 to 51.14 for different heat inputs, with the maximum value of 17.80 Mn/N ratio, which approaches 2205 DSS at higher heat input due to more reformed austenite formation. The large difference in nitrogen content distribution between the two phases for low and high Mn/N ratio DSS resulted in a much lower pitting resistance equivalent number value of the ferrite phase compared to the austenitic phase, weakening the enhanced effect of nitrogen on pitting corrosion resistance of DSS in HAZ. Meanwhile, corrosion pits occurred in δ-ferrite and were accelerated by the rise in Cr2N number and the enhancement of interphase dislocation at low heat input for a 17.80 Mn/N ratio. With the increase of the Mn/N ratio to 51.14, the stability and compactness of the passive film were considerably impaired by lower oxidized Fe(III) and Cr and NH4+ contents and more porous MnO production. The susceptibility to intergranular corrosion (IGC) of HAZ is comparable to 2205 DSS with a Mn/N ratio of 3.28 to 17.80 under various heat inputs, but which increased at a higher Mn/N ratio of 51.14 due to rapid increase of δ-ferrite fraction and fast growth of Widmanstatten austenite.

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Data Availability

The raw/processed data required to reproduce these findings cannot be shared at this time as the data are also part of an ongoing study. The data will be made available upon request by contact with the corresponding author.

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Acknowledgments

This work was mainly supported by the Fundamental Research Funds for the National Natural Science Foundation of China (NSFC Project No. 51861019)

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  1. School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, 650093, P.R. China

    Yinhui Yang & Ke Ni

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  1. Yinhui Yang
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YY participated in the conceptualization, methodology, writing of the original draft, writing, reviewing, & editing of the manuscript, and supervision. KN participated in the conceptualization, resources, data curation, formal analysis, and validation.

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Yang, Y., Ni, K. Investigation on Corrosion Behavior of Simulated Welding HAZ for 22 pct Cr Lean Duplex Stainless Steel With Different Mn/N Ratio Addition. Metall Mater Trans A 54, 2924–2946 (2023). https://doi.org/10.1007/s11661-023-07068-y

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