Skip to main content
SpringerLink
Log in

Prediction of Phase Separation of Immiscible Ga-Tl Alloys

  • Published:
Metallurgical and Materials Transactions A Aims and scope Submit manuscript

Abstract

Phase separation temperature of Ga-Tl liquid alloys was investigated using the constrained drop method. With this method, density and surface tension were investigated together. Despite strong repulsive interactions, molar volume showed ideal mixing behavior, whereas surface tension of the alloy was close to that of pure Tl due to preferential adsorption of Tl. Phase separation temperatures and surface tension values obtained with this method were close to the theoretically calculated values using three different thermodynamic models.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

Notes

  1. This assumption was adopted to maintain consistency of the successive works by the corresponding author.

References

  1. 1. C.P. Wang, X.J. Liu, I. Ohnuma, R. Kainuma, and K. Ishida: Science, 2000, vol. 297, pp.990–993.

    Article  Google Scholar 

  2. 2. S. Min, J. Park, and J. Lee: Mater. Lett., 2008, vol. 62, pp.4464-4466.

    Article  Google Scholar 

  3. 3. J.Q. Li, B.Q. Ma, S. Min, J. Lee, Z.F. Yuan, and L.K. Zang: Mater. Lett., 2010, vol. 64, pp.814-816.

    Article  Google Scholar 

  4. 4. T. Nagase, M. Suzuki, and T. Tanaka: J. Alloys Comp., 2015, vol. 619, pp.332-337.

    Article  Google Scholar 

  5. 5. H. Shim, P. Wynblatt, and D. Chatain: Surf. Sci. Lett., 2001, vol. 476, pp.L273–L277.

    Article  Google Scholar 

  6. 6. C. Mekler and G. Kaptay: Mater. Sci. Eng. A, 2008, vol. 495, pp.65-69.

    Article  Google Scholar 

  7. 7. Y.B. Kang and A.D. Pelton: J. Chem. Thermodynamics, 2013, vol. 60, pp.19–24.

    Article  Google Scholar 

  8. 9. T. Tanaka, M. Nakamoto, R. Oguni, J. Lee, and S. Hara: Z. Metallkd., 2004, vol. 95, pp.818-822.

    Article  Google Scholar 

  9. 10. J. Lee, A. Kiyose, S. Nakatsuka, M. Nakamoto, and T. Tanaka: ISIJ Int., 2004, vol. 44, pp.1793-1799.

    Article  Google Scholar 

  10. 8. I. Jimbo and A.W. Cramb: ISIJ Int., 1992, vol. 32, pp.26-35.

    Article  Google Scholar 

  11. T. Iida and R.I.L. Guthrie: The Physical Properties of Liquid Metals, Clarendon Press Oxford, New York, NY, 1988, p. 71.

  12. 12. J. Brillo, I. Egry and T. Matsushita: Int. J. Mater. Res., 2006, vol. 97, pp.1526-1532.

    Article  Google Scholar 

  13. 19. T. Tanaka, M. Nakamoto, R. Oguni, J. Lee, and S. Hara: Z. Metallkd., 2004, vol.95, pp.1-5.

    Article  Google Scholar 

  14. 21. S.C. Hardy: J. Cyrst. Growth, 1985, vol. 71, pp.602-606.

    Article  Google Scholar 

  15. 23. S.P. Yatsenko, V.I. Kononenko, and A.L. Sukhman: High Temp., 1972, vol.10, pp.55-59.

    Google Scholar 

  16. 20. N. Konig and W. Keck: J. Less-Common Met., 1983, vol. 90, pp.299-303.

    Article  Google Scholar 

  17. 22. V.I. Nizhenko and L.I. Floka: Zurn. Fiz. Chim., 1975, vol. 49, pp.431-434.

    Google Scholar 

  18. 24. Kh.I. Ibragimov: Fiz. Khim. Issled. Met. Prot. Sverd., 1980, vol.8, pp.61-66.

    Google Scholar 

  19. 25. M.B. Kokov, B.B. Alchagirov, S.N. Zadumkin, and Kh.B. Khokonov: Inorg. Mater., 1978, vol. 14, pp. 26-29.

    Google Scholar 

  20. 26. J. Bohdansky and H.E.J. Schins: J. Inorg. Nucl. Chem., 1968, vol. 30, pp. 3362-3365.

    Article  Google Scholar 

  21. I. Ansara, unpublished research, 1991, cited in H. Shim, P. Wynbaltt, D. Chatain, Surf. Sci. Lett., 2001, vol. 476, pp. L273—277.

  22. 28. A.T. Dinsdale: Calphad, 1991, vol.15, pp.317–425.

    Article  Google Scholar 

  23. 29. C.W. Bale, E. Bélisle, P. Chartrand, S.A. Decterov, G. Eriksson, K. Hack, I.-H. Jung, Y.-B. Kang, J. Melançon, A.D. Pelton, C. Robelin, and S. Petersen: Calphad, 2009, vol.33, pp.295–311.

    Article  Google Scholar 

  24. 30. B. Predel: Z. Metallkd., 1959, vol. 50, pp.663–667.

    Google Scholar 

  25. 31. S.P. Yatsenko and V.I. Kononenko: Inorg. Mater. USSR, 1967, vol. 3, pp.1367–1373.

    Google Scholar 

  26. 32. W. Klemm, L. Klemm, E. Hohmann, H. Volk, E. Orlameunder, and H.A. Klein; Z. Anorg. Chem., 1948, vol.256, pp.239–252.

    Google Scholar 

  27. 33. H. Spengler: Z. Metallkd., 1955, vol. 46, pp.464–467.

    Google Scholar 

  28. 34. R. Fowler and E. Guggenheim: Statistical Thermodynamics, Cambridge University Press, Cambridge, UK, 1939.

    Google Scholar 

  29. A.D. Pelton and M. Blander: Proceedings of second International Symposium on Metallurgical Slags and Fluxes, TMS-AIME, Warrendale, PA, 1984, pp. 281–94.

  30. 36. A.D. Pelton, S.A. Degterov, G. Eriksson, C. Robelin, and Y. Dessureault: Metall. Mater. Trans. B, 2000, vol.31, pp.651–659.

    Article  Google Scholar 

  31. 37. A.D. Pelton and P. Chartrand: Metall. Mater. Trans. A, 2001, vol. 32, pp.1355–1360.

    Article  Google Scholar 

  32. T. Førland, in: Fused Salts, B.R. Sundheim ed., McGraw Hill, NY, 1964, pp. 86–89.

  33. 39. Y. Dessureault and A.D. Pelton: J. Chim. Phys., 1991, vol.88, pp.1811-1830.

    Google Scholar 

  34. J.A.V. Butler: Proc. Royal Soc. Lond. Ser. A-Containing Papers of a Mathematical and Physical Character, 1932, vol. 135, pp. 348–75.

  35. 41. J. Park and J. Lee: Calphad, 2008, vol. 32, pp.135-141.

    Article  Google Scholar 

  36. 42. J. Lee, W. Shimoda and T. Tanaka: Mater. Trans., 2004, vol. 45, pp.2864-2870.

    Article  Google Scholar 

  37. 13. H. Kobatake, J. Schmitz, and J. Brillo: J. Mater. Sci., 2014, vol. 49, pp.3541-3549.

    Article  Google Scholar 

  38. 14. A. Mizuno, H. Kawauchi, M. Tanno, K. Murai, H. Kobatake, H. Fukuyama, T. Tsukada, and M. Watanabe: ISIJ Int., 2014, vol. 54, pp.2120-2124.

    Article  Google Scholar 

  39. 15. M. Schick, J. Brillo and I. Egry: Int. J. Cast Metals Research, 2009, vol. 22, pp.82-85.

    Article  Google Scholar 

  40. 16. S. Amore, S. Delsante, H. Kobatake, J. Brillo: J. Chem. Phys., 2013, vol. 139, 064504.

    Article  Google Scholar 

  41. 17. S. Amore, J. Horbach and I. Egry: J. Chem. Phys., 2011, vol.134, 044515.

    Article  Google Scholar 

  42. 18. J. Brillo: Thermophysical properties of multicomponent liquid alloys, de Gruyter, Gmbh, Berlin, 2016, pp. 38-69.

    Book  Google Scholar 

Download references

Acknowledgments

This research was supported by the Converging Research Center Program (National Research Foundation of Korea, NRF-2014M3C1A8053738) through the Ministry of Science, ICT & Future Planning. YK was supported by the Korea University Grant.

Author information

Authors and Affiliations

  1. Department of Materials Science and Engineering, Korea University, 5 Anam-dong, Seongbuk-gu, Seoul, 02841, Korea

    Yunkyum Kim, Han Gyeol Kim & Joonho Lee

  2. GIFT, POSTECH, 77 Chengamro, Namgu, Pohang, Kyungbuk, 37673, Korea

    Youn-Bae Kang

  3. Department of Nanotechnology, University of Miskolc, Egyetemvaros, Miskolc, 3515, Hungary

    George Kaptay

  4. Department of Materials Science and Engineering, McMaster University, Hamilton, ON, L8S 4L8, Canada

    Yunkyum Kim

Authors
  1. Yunkyum Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Han Gyeol Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Youn-Bae Kang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. George Kaptay
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Joonho Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Joonho Lee.

Additional information

Manuscript submitted April 6, 2016.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kim, Y., Kim, H.G., Kang, YB. et al. Prediction of Phase Separation of Immiscible Ga-Tl Alloys. Metall Mater Trans A 48, 3130–3136 (2017). https://doi.org/10.1007/s11661-017-4075-0

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11661-017-4075-0

Keywords

Search

Navigation