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Kinetics of the Formation of Intermetallic Phases in HP-Type Heat-Resistant Alloys at Long-Term High-Temperature Exposure

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Abstract

The kinetics of formation and morphology of the intermetallic phases in the structure of heat-resistant as-cast HP40NbTi alloys in the course of long high-temperature exposure have been studied with the help of light and electron microscopy, electron microprobe, and X-ray diffraction. During exposure of 2 to 1000 hours at 1423 K (1150 °C), intermetallic phase with conditional formula Cr7Ni5Si3N3FeNb is formed in the alloy. The analysis of the kinetics of intermetallic phase’s growth for an impact assessment of certain metal substitutional elements (niobium, chromium, silicon) on the size of the formed particles was performed. Formation and growth of the intermetallic phases with high silicon content in the alloy structure on the boundaries between niobium and chromium carbides (NbC and M23C6) and matrix γ-phase provide a diffusion barrier for oxygen in oxidizing environment. This may create partial protection against oxidation of hardening carbide phases in the structure and promote increasing of the serviceability of the HP series alloys under operating conditions in the petrochemical industry.

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Acknowledgments

Authors thank sincerely Julia and Melvin Mawhin for editing the English version of our manuscript.

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Authors and Affiliations

  1. Peter the Great St. Petersburg Polytechnic University, Polytechnicheskaya street 29, St. Petersburg, Russian Federation, 195251

    Sergey Yu. Kondrat’ev (Full Professor of Technology and Research of Materials Chair) & Grigoriy P. Anastasiadi (Full Professor of Technology and Research of Materials Chair)

  2. Central Research Institute of Structural Materials “Prometey”, Shpalernaya Street 49, St. Petersburg, Russian Federation, 191015

    Sergey N. Petrov (Head of the Physical Materials Science Laboratory) & Alina V. Ptashnik (Engineer of the Physical Materials Science Laboratory)

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  1. Sergey Yu. Kondrat’ev
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  2. Grigoriy P. Anastasiadi
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  3. Sergey N. Petrov
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  4. Alina V. Ptashnik
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Correspondence to Sergey Yu. Kondrat’ev.

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Manuscript submitted April 24, 2016.

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Kondrat’ev, S.Y., Anastasiadi, G.P., Petrov, S.N. et al. Kinetics of the Formation of Intermetallic Phases in HP-Type Heat-Resistant Alloys at Long-Term High-Temperature Exposure. Metall Mater Trans A 48, 482–492 (2017). https://doi.org/10.1007/s11661-016-3814-y

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  • DOI: https://doi.org/10.1007/s11661-016-3814-y

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