Abstract
The effects of Si and Mn interactions on the spheroidization and coarsening behavior of cementite during annealing in severe cold-drawn pearlitic steel were studied. Spheroidization of cementite particles annealed at 873 K (600 °C) in heavily cold-drawn pearlitic steel was obviously retarded by higher Si contents. The coarsening kinetics of cementite particles in heavily cold-drawn and annealed pearlite obeyed a power-law relationship. The values of ECD increase steadily according to a temporal dependence of n S87B (0.21 ± 0.02) for S87B and n S87BM (0.23 ± 0.06) for S87BM. The n values lie between 0.20 and 0.25, indicating that cementite particles coarsening occurs through a combination of dislocation diffusion (n = 0.20) controlled and grain boundary diffusion (n = 0.25) controlled coarsening mechanisms. Higher Si content in S87BM led to more pronounced partitioning of Mn than that in S87B, resulting in more significant suppression of alloying elements and lower coarsening rate constant K on the cementite particles coarsening behavior.
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G. Langford, Metallurgical Transactions a-Physical Metallurgy and Materials Science 1977, vol. 8, pp. 861-875.
YJ Li, P Choi, S Goto, C Borchers, D Raabe and R Kirchheim, Acta Materialia 2012, vol. 60, pp. 4005-4016.
YJ Li, P Choi, C Borchers, S Westerkamp, S Goto, D Raabe and R Kirchheim, Acta Materialia 2011, vol. 59, pp. 3965-3977.
VN Gridnev, VG Gavrilyuk, I Ya Dekhtyar, Yu Meshkov, PS Nizin and VG Prokopenko, physica status solidi (a) 1972, vol. 14, pp. 689-694.
F Danoix, D Julien, X Sauvage and J Copreaux, Materials Science and Engineering: A 1998, vol. 250, pp. 8-13.
X Sauvage, J Copreaux, F Danoix and D Blavette, Philosophical Magazine A 2000, vol. 80, pp. 781-796.
MH Hong, WT Reynolds, T Tarui and K Hono, Metallurgical and Materials Transactions A 1999, vol. 30, pp. 717-727.
J Languillaume, G Kapelski and B Baudelet, Acta Materialia 1997, vol. 45, pp. 1201-1212.
YJ Li, P Choi, S Goto, C Borchers, D Raabe and R Kirchheim, Ultramicroscopy 2013, vol. 132, pp. 233-238.
DB Park, JW Lee, YS Lee, KT Park and WJ Nam, Metals and Materials International 2008, vol. 14, pp. 59-64.
T Tarui, N Maruyama, J Takahashi, S Nishida and H Tashiro, Shinnittetsu Giho 2004, vol. 380, pp. 51–56.
S Björklund, LF Donaghey and M Hillert, Acta Metallurgica 1972, vol. 20, pp. 867-874.
G Miyamoto, JC Oh, K Hono, T Furuhara and T Maki, Acta materialia 2007, vol. 55, pp. 5027-5038.
G. H. Zhang, J. Y. Chae, K. H. Kim and D. W. Suh, Materials Characterization 2013, vol. 81, pp. 56-67.
Z. Q. Lv, S. H. Sun, Z. H. Wang, M. G. Qv, P. Jiang and W. T. Fu, Materials Science and Engineering: A 2008, vol. 489, pp. 107-112.
Wantang Fu, Tadashi Furuhara and Tadashi Maki, ISIJ international 2004, vol. 44, pp. 171-178.
G. Miyamoto, H. Usuki, Z. D. Li and T. Furuhara, Acta Materialia 2010, vol. 58, pp. 4492-4502.
T. Sakuma, N. Watanabe and T. Nishizawa, Transactions of the Japan Institute of Metals 1980, vol. 21, pp. 159-168.
Wan-Hua Yu, Shao-Hui Chen, Yong-Hai Kuang and Kai-Chao Cao, Applied Thermal Engineering 2009, vol. 29, pp. 2949-2953.
Feng Fang, Yufei Zhao, Peipei Liu, Lichu Zhou, Xian-jun Hu, Xuefeng Zhou and Zong-han Xie, Materials Science and Engineering: A 2014, vol. 608, pp. 11-15.
Y. Y. Tu, Z. G. Mao, Q. Zhang, X. F. Zhou, F. Fang and J. Q. Jiang, Mater. Lett. 2014, vol. 134, pp. 84-86.
Alan J. Ardell, Materials Science & Engineering A 1997, vol. A238, pp. 108-120.
A. Lindsley and A. R. Marder, Acta Materialia 1998, vol. 46, pp. 341-351.
W. J. Nam and C. M. Bae, Scripta Materialia 1999, vol. 41, pp. 313-318.
A. J. Ardell, Acta Metallurgica 1972, vol. 20, pp. 601-&.
F. Fang, L. C. Zhou, X. J. Hu, X. F. Zhou, Y. Y. Tu, Z. H. Xie and J. Q. Jiang, Mater. Des. 2015, vol. 79, pp. 60-67.
K. Han, G. D. W. Smith and D. V. Edmonds, Metall. Mater. Trans. A-Phys. Metall. Mater. Sci. 1995, vol. 26, pp. 1617-1631.
K. Hono, M. Ohnuma, M. Murayama, S. Nishida, A. Yoshie and T. Takahashi, Scripta Materialia 2001, vol. 44, pp. 977-983.
J. Agren, Acta Metallurgica 1982, vol. 30, pp. 841-851.
G. P. Airey, T. A. Hughes and R. F. Mehl, Transactions of the Metallurgical Society of Aime 1968, vol. 242, pp. 1853-&.
S. S. Babu, K. Hono and T. Sakurai, Metall. Mater. Trans. A-Phys. Metall. Mater. Sci. 1994, vol. 25, pp. 499-508.
S. K. Tewari and R. C. Sharma, Metallurgical Transactions a-Physical Metallurgy and Materials Science 1985, vol. 16, pp. 597-603.
C. Capdevila, F. G. Caballero and C. G. de Andres, Acta Materialia 2002, vol. 50, pp. 4629-4641.
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This work was supported by the National Science Foundation of China (Nos. 51201031, 51371050, and 51301038) and the Fundamental Research Funds for the Central Universities.
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Manuscript submitted June 28, 2015.
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Tu, Y., Huang, L., Wang, X. et al. Effect of Si and Mn Interactions on the Spheroidization and Coarsening Behavior of Cementite During Annealing in Severe Cold-Drawn Pearlitic Steel. Metall Mater Trans A 47, 254–259 (2016). https://doi.org/10.1007/s11661-015-3219-3
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DOI: https://doi.org/10.1007/s11661-015-3219-3