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Influences of TiO2 Addition on the Crystallization Behavior, Microstructure, and Magnetic Properties of Li2O-MnO2-Fe2O3-CaO-P2O5-SiO2 Glasses

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Abstract

Influences of TiO2 addition on the phase transformation, microstructure, and magnetic properties of Li2O-MnO2-Fe2O3-CaO-P2O5-SiO2 (LMFCPS) glass have been studied using DTA, XRD, SEM, EDS, TEM, SAED, and SQUID. When LMFCPS glass, with and without TiO2 content, is crystallized at 1123 K (850 °C) for 2 hours, the magnetite (FeFe2O4), β-wollastonite (β-CaSiO3), lithium orthophosphate (Li3PO4), and triphylite (Li(Mn0.5Fe0.5)PO4) phases are formed. The β-wollastonite and lithium silicate formed with evident directionality were observed in the LMFCPS glass–ceramics without adding TiO2. However, when the LMFCPS glass with various TiO2 content is crystallized at 1123 K (850 °C) for 16 hours, very small remnant magnetic induction and coercive field hysteresis loops were found showing the ferromagnetic property in a magnetic field smaller than 2000 Oe. Additionally, when LMFCPS glass with various TiO2 contents is crystallized at 1123 K (850 °C) for 16 hours, the glass–ceramics showed super-paramagnetic property in a magnetic field of 60 kOe due to the small grains of the iron-rich phases.

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Acknowledgments

The authors would like to thank Ms. Liang-Chu Wang of National Sun Yat-San University for providing TEM imaging assistance. This work was supported by the National Science Counsel, Taiwan (NSC-97-2221-E-239-001-MY3), and is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Materials Science and Engineering, I-Shou University, 1 Hsueh-Cheng Road, Section 1, Ta-Hsu, Kaohsiung, 84001, Taiwan R.O.C

    Huy-Zu Cheng & Chien-Fa Wang

  2. Department of Materials Science and Engineering, National United University, 1 Lien-Da Road, Kung-Ching Li, Miao Li, 360, Taiwan R.O.C

    Huey-Jiuan Lin & Chi-Shiung Hsi

  3. Department of Fragrance and Cosmetic Science, Kaohsiung Medical University, 100 Shih-Chuan 1st Road, Kaohsiung, 807, Taiwan R.O.C

    Moo-Chin Wang

  4. State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, 122 Luo-shi Road, Hongshan District, Wuhan, 430070, Hubei, P.R. China

    XiuJian Zhao

  5. Special Glass Key Laboratory of Hainan Province, Hainan University, 58 People Road, Haikou City, Hainan, P.R. China

    Hong Jiang & Chang-Jiu Li

  6. Aviation Industry Corporation of China (Hainan) Special Glass Materials Co., Ltd, Sourth 1st Road, Economic Development Zone of Old City, Laocheng, Hainan Province, P.R. China

    Peng Lu

  7. Special Glass Engineering Technology Research Center of Hainan Province, Haikou City, P.R. China

    Peng Lu

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  1. Huy-Zu Cheng
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Correspondence to Moo-Chin Wang.

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Manuscript submitted July 13, 2014.

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Cheng, HZ., Lin, HJ., Wang, MC. et al. Influences of TiO2 Addition on the Crystallization Behavior, Microstructure, and Magnetic Properties of Li2O-MnO2-Fe2O3-CaO-P2O5-SiO2 Glasses. Metall Mater Trans A 46, 2040–2050 (2015). https://doi.org/10.1007/s11661-015-2826-3

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