Abstract
The morphological evolution of Cu pillars capped with Sn-1.8 wt pct Ag solder during high-temperature annealing was investigated. Two intermetallic compounds (Cu6Sn5 + Cu3Sn) formed at the Cu/solder interface which changed the pillar’s morphology. Surface diffusion enhanced the growth of Cu6Sn5 + Cu3Sn around the pillar brim and transformed the pillar top from a plane into a truncated cone. Bulk diffusion dominated after long-term annealing and the pillar top became hemispherical shaped. A mechanism was proposed to explain the unusual morphological evolution.
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This work was supported in part by the Ministry of Science and Technology of Taiwan and in part by the Taiwan Semiconductor Manufacturing Company, Hsinchu, Taiwan.
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Manuscript submitted December 3, 2014.
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Cheng, HK., Lin, YJ., Chang, HC. et al. Unusual Morphological Evolution of the Cu Pillar/Solder Micro-joints During High-Temperature Annealing. Metall Mater Trans A 46, 1834–1837 (2015). https://doi.org/10.1007/s11661-015-2825-4
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DOI: https://doi.org/10.1007/s11661-015-2825-4