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Green Approach to Corrosion Inhibition of Copper by the Extract of Calligonum comosum in Strong Acidic Medium

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Abstract

The corrosion inhibition effect of Calligonum comosum (CC) extract on copper (Cu) in 2 mol L−1 HCl medium has been investigated by potentiodynamic polarization and electrochemical impedance spectroscopy methods. The polarization studies showed that CC extract acts as mixed type protection and maximum inhibition efficiency. 80.06 pct in 2 mol L−1 HCl is obtained at 0.8 g L−1 CC extract. The Nyquist plots showed an increase of the charge-transfer resistance with increasing of the inhibitor concentration and decrease double-layer capacitance. The inhibitory action of the extract was discussed in view of the Langmuir adsorption isotherm.

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Acknowledgments

The authors are grateful to University of Kashan for supporting this work by Grant No. (159194/8).

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Authors and Affiliations

  1. Department of Analytical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Islamic Republic of Iran

    Mehdi Shabani-Nooshabadi (Assistant Professor), Fatemeh Sadat Hoseiny (Master Student) & Yaser Jafari (Ph.D. Student)

Authors
  1. Mehdi Shabani-Nooshabadi
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  2. Fatemeh Sadat Hoseiny
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  3. Yaser Jafari
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Correspondence to Mehdi Shabani-Nooshabadi.

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Manuscript submitted March 26, 2014.

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Shabani-Nooshabadi, M., Hoseiny, F.S. & Jafari, Y. Green Approach to Corrosion Inhibition of Copper by the Extract of Calligonum comosum in Strong Acidic Medium. Metall Mater Trans A 46, 293–299 (2015). https://doi.org/10.1007/s11661-014-2634-1

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