Abstract
The effects of Al and Mn contents on the size, composition, and three-dimensional morphologies of inclusions formed in Fe-xMn-yAl (x = 10 and 20 mass pct, y = 1, 3, and 6 mass pct) steels were investigated to enhance our understanding of the inclusion formation behavior in high Mn-Al–alloyed steels. By assuming that the alumina is a dominant oxide compound, the volume fraction of inclusions estimated from the chemical analysis, i.e., insoluble Al, in the Fe-Mn-3Al steels was larger than the inclusion volume fractions in the Fe-Mn-1Al and Fe-Mn-6Al steels. A similar tendency was found in the analysis of inclusions from a potentiostatic electrolytic extraction method. This finding could be explained from the terminal velocities of the compounds, which was affected by the thermophysical properties of Fe-Mn-Al steels. The inclusions formed in the Fe-Mn-Al–alloyed steels are classified into seven types according to chemistry and morphology: (1) single Al2O3 particle, (2) single AlN or AlON particle, (3) MnAl2O4 single galaxite spinel particle, (4) Al2O3(-Al(O)N) agglomerate, (5) single Mn(S,Se) particle, (6) oxide core with Mn(S,Se) skin (wrap), and (7) Mn(S,Se) core with Al2O3(-Al(O)N) aggregate (or bump). The Mn(S,Se) compounds were formed by the contamination of the steels by Se from the electrolytic Mn. Therefore, the raw materials (Mn) should be used carefully in the melting and casting processes of Fe-Mn-Al–alloyed steels.
Similar content being viewed by others
References
O. Grässel, L. Krüger, G. Frommeyer, and L.W. Meyer: Int. J. Plast., 2000, vol. 16, pp. 1391–1409.
H. Idrissi, K. Renard, L. Ryelandt, D. Schryvers, and P.J. Jacques: Acta Mater., 2010, vol. 58, pp. 2464–76.
S.W. Hwang, J.H. Ji, and K.T. Park: Mater. Sci. Eng. A, 2011, vol. 528, pp. 7267–75.
AHSS Application Guidelines (version 4.1), IISI, http://www.worldautosteel.org, 2009, pp. 1–14.
G. Frommeyer and U. Brüx: Steel Res. Int., 2006, vol. 77, pp. 627–33.
J.D. Yoo, S.W. Hwang, and K.T. Park: Metall. Mater. Trans. A, 2009, vol. 40A, pp. 1520–23.
Y. Sutou, N. Kamiya, R. Umino, I. Ohnuma, and K. Ishida: ISIJ Int., 2010, vol. 50, pp. 893–99.
A. Dumay, J.P. Chateau, S. Allain, S. Miget, and O. Bouaziz: Mater. Sci. Eng. A, 2008, vols. 483–484, pp. 184–87.
K.T. Park, K.G. Jin, S.H. Han, S.W. Hwang, K. Choi, and C.S. Lee: Mater. Sci. Eng. A, 2010, vol. 527, pp. 3651–61.
A.S. Hamada, L.P. Karjalainen, and M.C. Somani: Mater. Sci. Eng. A, 2007, vol. 467, pp. 114–24.
M. Koyama, T. Sawaguchi, K. Ogawa, T. Kikuchi, and M. Murakami: Mater. Sci. Eng. A, 2008, vol. 497, pp. 353–57.
Y. Kim, N. Kim, Y. Park, I. Choi, G. Kim, S. Kim, and K. Cho: J. Kor. Inst. Metall. Mater., 2008, vol. 46, pp. 780–87.
J.M. Jang, S.J. Kim, N.H. Kang, K.M. Cho, and D.W. Suh: Metall. Mater. Int., 2009, vol. 15, pp. 909–16.
K. Ahn, D. Yoo, M.H. Seo, S.H. Park, and K. Chung: Metall. Mater. Int., 2009, vol. 15, pp. 637–47.
K.G. Jin, C.Y. Kang, S.Y. Shin, S. Hong, S. Lee, H.S. Kim, K.H. Kim, and N.J. Kim: Mater. Sci. Eng. A, 2011, vol. 528, pp. 2922–28.
J. Kim, S.J. Lee, and B.C. De Cooman: Scripta Mater., 2011, vol. 65, pp. 363–66.
I.J. Park, S.T. Kim, I.S. Lee, Y.S. Park, and M.B. Moon: Mater. Trans., 2009, vol. 50, pp. 1440–47.
J. Sojka, V. Vodarek, I. Schindler, C. Ly, M. Jerome, P. Vanova, N. Ruscassier, and A. Wenglorzova: Corros. Sci., 2011, vol. 53, pp. 2575–81.
M. Amirthalingam, M. Hermans, and I. Richardson: Metall. Mater. Trans. A, 2009, vol. 40A, pp. 901–09.
S.E. Kang, A. Tuling, J.R. Banerjee, W.D. Gunawardana, and B. Mintz: Mater. Sci. Tech., 2011, vol. 27, pp. 95–100.
G. Gigacher, W. Krieger, P.R. Scheller, and C. Thomser: Steel Res. Int., 2005, vol. 76, pp. 644–49.
J.H. Park: Mater. Sci. Eng. A, 2008, vol. 472, pp. 43–51.
J.H. Park, S.B. Lee, D.S. Kim, and J.J. Pak: ISIJ Int., 2009, vol. 49, pp. 337–42.
J.H. Park, G.H. Park, D.J. Paik, Y. Huh, and M.H. Hong: Metall. Mater. Trans. A, 2012, vol. 43A, pp. 195–207.
A. Karasev and H. Suito: Metall. Mater. Trans. B, 1999, vol. 30B, pp. 259–70.
H. Ohta and H. Suito: ISIJ Int., 2006, vol. 46, pp. 14–21.
J. Lee, L.T. Hoai, and M. Shin: Metall. Mater. Trans. B, 2011, vol. 42B, pp. 546–49.
K.C. Mills: Recommended Values of Thermophysical Properties for Selected Commercial Alloys, NPL and ASM International, Woodhead Publishing Limited, Cambridge, UK, 2002.
S. Seetharaman: Fundamentals of Metallurgy, IOM and CRC Press, Woodhead Publishing Limited, Cambridge, UK, 2005.
www.factsage.com, 2011.
C.W. Bale, E. Belisle, P. Chartrand, S.A. Decterov, G. Eriksson, K. Hack, I.H. Jung, Y.B. Kang, J. Melancon, A.D. Pelton, C. Robelin, and S. Petersen: CALPHAD, 2009, vol. 33, pp. 295–311.
J.H. Park and Y.B. Kang: Metall. Mater. Trans. B, 2006, vol. 37B, pp. 791–98.
J.H. Park, S.B. Lee, and H.R. Gaye: Metall. Mater. Trans. B, 2008, vol. 39B, pp. 853–61.
J.H. Park and H. Todoroki: ISIJ Int., 2010, vol. 50, pp. 1333–46.
J.H. Park: CALPHAD, 2011, vol. 35, pp. 455–62.
I. Lewis, P. Scaife, and D. Swinkels: J. Appl. Electrochem., 1976, vol. 6, pp. 453–63.
Y. Sun, X. Tian, B.B. He, C. Yang, Z.B. Pi, Y.X. Wang, and S.X. Zhang: Electrochim. Acta, 2011, vol. 56, pp. 8305–10.
Y.K. Lee: Private communication, Yonsei University, Seoul, Korea, May 2011.
R. Dekkers: Ph.D. Dissertation, Katholieke Universiteit Leuven, Leuven, Belgium, 2002.
K.C. Mills: Thermodynamic Data for Inorganic Sulphides, Selenides and Tellurides, Butterworth, London, UK, 1974.
J.M. Mehta, P.G. Riewald, and L.H. Van Vlack: J. Am. Ceram. Soc., 1967, vol. 50, pp. 164–65.
Author information
Authors and Affiliations
Corresponding author
Additional information
Manuscript submitted September 11, 2011.
Rights and permissions
About this article
Cite this article
Park, J.H., Kim, DJ. & Min, D.J. Characterization of Nonmetallic Inclusions in High-Manganese and Aluminum-Alloyed Austenitic Steels. Metall Mater Trans A 43, 2316–2324 (2012). https://doi.org/10.1007/s11661-012-1088-6
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11661-012-1088-6