Abstract
The stabilization of liquid-metal foams by ceramic particles is studied by experimental simulations. The objective is to determine the optimum wetting property for liquid-foam stability. Ceramic particles are mimicked by inert plastic particles. The liquid metal is mimicked by a continuous, surfactant-free ethanol-water solution. The wetting property of the plastic particles in the liquid solution is changed continuously by varying the liquid composition. The experimental simulation shows that the liquid-foam stabilization by the solid particles depends strongly on the wetting property. An optimum wetting-angle range of 75 to 85 deg is determined from the experiments. The foam stability is shown to be unrelated to liquid viscosity, which remains unchanged with the wetting angle. Foams formed in the optimum wetting condition exhibit a slow decay, a stable foam volume that persists for a long time, and a fine cell structure in the micrometer range. The selection of ceramic particles for optimal stabilization of liquid-metal foams and the foam-processing procedures are discussed in the light of these experimental simulation results.
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M.F. Ashby, A. Evans, N.A. Fleck, L.J. Gibson, J.W. Hutchinson, and H.N.G. Wadley: Metal Foams: A Design Guide, Butterworth-Heineman, Boston, MA, 2000.
J. Banhart: J. Met., 2000, vol. 12, p. 22.
A.G. Evans, J.W. Hutchinson, and M.F. Ashby: Curr. Opinion Solid State Mater. Sci., 1998, vol. 3, p. 288.
V. Shapovalov: Mater. Res. Soc. Bull., 1994, vol. 4, p. 24.
D. Weaire and S. Hutzler: The Physics of Foams, Clarendon Press, Oxford, United Kingdom, 1999.
L.J. Gibson and M.F. Ashby: Cellular Solids: Structure and Properties, Cambridge University Press, Cambridge, NY, 1997.
L.J. Gibson: Ann. Rev. Mater. Res., 2000, vol. 30, p. 191.
G.J. Davies and S. Zhen: J. Mater. Sci., 1983, vol. 18, p. 1899.
J. Banhart and J. Baumeister: Proc. Materials Research Society, 1998, vol. 521, p. 121.
L.D. Zardiackas, D.E. Parsell, L.D. Dillon et al.: J. Biomed. Mater. Res., 2001, vol. 58, p. 180.
M. Thomas, D. Kenny, and H. Sang: US Patent Database, Alcan International Limited, Ontario, Canada, 1997, vol. 5622542.
T. Miyoshi: in Metal Foams and Porous Metal Structures, J. Banhart, M.F. Ashby, and N.A. Fleck, eds., MIT Verlag, Bremen, 1999, p. 125.
J.J. Bikerman: Foams, Springer-Verlag, New York, NY, 1973.
F. Sebba: Foams and Biliquid Foams—Aphrons, John Wiley & Sons, Chichester, United Kingdom, 1987.
L. Ma and Z. Song: Scripta Mater., 1998, vol. 39, p. 1523.
G. Johansson and R.J. Pugh: Int. J. Mineral Processing, 1992, vol. 34, p. 1.
G. Kaptay: in Metal Foams and Porous Metal Structures, J. Banhart, M.F. Ashby, and N.A. Fleck, eds., MIT Verlag, Bremen, Germany, 1999, p. 141.
S.W. Ip, Y. Wang, and J.M. Toguri: Can. Metall. Q., 1999, vol. 38, p. 81.
C. Yu, H.H. Eifert, J. Banhart and J. Baumeister: Adv. Mater. Processes, 1998, vol. 11, p. 45.
D.M. Elzey and H.N.G. Wadley: Acta Mater., 2001, vol. 49, p. 849.
V. Shapovalov: in Porous and Cellular Materials for Structural Applications, D.S. Schwartz, ed., MRS, Warrendale, PA, 1998, vol. 521, p. 281.
J.R. Dann: J. Coll. Interface Sci., 1970, vol. 32, p. 302.
G. Vazquez, E. Alvarez, and J.M. Navaza: J. Chem Eng. Data, 1995, vol. 40, p. 611.
F. Tang, Z. Xiao, J. Tang, and L. Jiang: J. Coll. Interface Sci., 1989, vol. 131, p. 498.
C. Monnereau, M. Vignes-Adler, and K. Kronberg: J. Chimie Phys., 1999, vol. 96, p. 958.
O. Prakash, H. Sang, and J.D. Embury: Mater. Sci. Eng., 1995, vol. A199, p. 195.
J.K. Spelt and D. Li: in Applied Surface Thermodynamics, A.W. Neumann and J.K. Spelt, eds., Marcel Dekker, New York, NY, 1996.
V. Laurent, D. Chatain, and N. Eustathopoulos: J. Mater. Sci., 1987, vol. 22, p. 244.
A. Adamson and A.P. Gast: Physical Chemistry of Surfaces, John Wiley & Sons, New York, NY, 1997.
L.E. Scriven and C.V. Sternling: Nature, 1960, vol. 187, p. 186.
H. Kumagai, Y. Torikata, H. Yoshimura, M. Kato, and T. Yano: Agric. Biol. Chem., 1991, vol. 55 (7), p. 1823.
S. Ross and G. Nishioka: Foams, Proc. Symp. Society of Chemical Industry, Academic Press, London, 1976, p. 17.
G.E. Dieter: Mechanical Metallurgy, McGraw-Hill, New York, NY, 1986.
B.P. Binks and O.S. Lumsdon: Langmuir, 2000, vol. 16, p. 8622.
J.V. Naidich: Progr. Surf. Member Sci., 1981, vol. 14, p. 353.
W.D. Kingery, H.K. Bowen, and D.R. Uhlman: Introduction to Ceramics, John Wiley & Sons, New York, NY, 1976.
K. Nakashima, H. Matsumoto, and K. Mori: Acta Mater., 2000, vol. 48, p. 4677.
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Sun, Y.Q., Gao, T. The optimum wetting angle for the stabilization of liquid-metal foams by ceramic particles: Experimental simulations. Metall Mater Trans A 33, 3285–3292 (2002). https://doi.org/10.1007/s11661-002-0315-y
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DOI: https://doi.org/10.1007/s11661-002-0315-y