Abstract
The effects of long duration exposure of laser surface engineered composite boride coating on plain carbon steel in air at high temperatures were investigated in this study. Exposures at 600 °C, 800 °C, and 1000 °C for 10, 30, and 50 hours of composite-TiB2 coated samples were conducted to study oxide scale growth and morphology. Kinetics of oxidation of the coating during elevated temperature exposures were separately studied using the thermogravimetric analysis (TGA) technique. The oxidation rate for all samples was parabolic in nature and the oxidation kinetic rate constant, K, increased with increasing temperature of exposure. Activation energy, Q for composite TiB2 coating was found to be 205 kJ/mol. A thick (>35 µm) oxide layer formed for all duration of exposure at temperatures ≥800 °C. In case of 1000 °C exposure, a very thick (>150 µm) oxide layer was formed, which was separated from the substrate. X-ray diffractometry analysis revealed the complex nonstoichiometric nature of the oxides of type Ti a O b , Fe m O n , and Fe x Ti y O z . Profilometric measurements indicated an increase in the surface roughness of the oxide layer with an increase in temperature of exposure. These physical observations indicated that the nature and morphology of the oxides formed at various temperatures and duration of exposure are complex.
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R.A. Cutler: Engineering Materials Handbook: Ceramic and Glasses, ASM INTERNATIONAL, Materials Park, Ott, 1991, vol. 4, pp. 787–803.
A. Agarwal and N.B. Dahotre: in Elevated Temperature Coatings: Science and Technology III, J.M. Hampikian and N.B. Dahotre, eds., TMS, Warrendale, PA, 1999, Annual TMS Meeting, San Diego, CA, 1999, pp. 273–84.
A. Agarwal and N.B. Dahotre: Mater. Characterization, 1999, vol. 42 (1), pp. 31–44.
A. Agarwal and N.B. Dahotre: Lasers Eng., 1999, in press.
A. Munster: Z. Electrochem., 1959, vol. 63, p. 807.
M.G. Barandika, J.J. Echeberria, J.M. Sanchez, and F. Castro: J. Mater. Chem., 1998, vol. 8 (8), pp. 1851–57.
R.J. Irving and I.G. Worsley: J. Less-Common Met. 1968, vol. 16, pp. 103–2.
V.B. Voitovich, V.A. Lavrenko, and V.M. Adejev: Oxid. Met., 1994, vol. 42 (1–2), pp. 145–61.
A.N. Pilyankevich, S.V. Papyan, and E.S. Lugovskaya: Poroshkovaya Metallurgiya, 1982, vol. 7 (235), pp. 59–63.
K.L. Choy and B. Derby: J. Mater. Sci., 1994, vol. 29, pp. 3774–80.
K. Billehaug and H. Oye: Aluminum Verlag, 1980, vol. 56 (100), pp. 642–51.
A. Agarwal and N.B. Dahotre: Surf. Coating & Technol., 1998, vol. 106, pp. 242–50.
A. Agarwal, N.B. Dahotre, and T.S. Sudarshan: Surf. Eng., 1999, vol. 15 (1), pp. 27–32.
N.B. Dahotre and A. Agarwal: JOM, 1999, vol. 51 (4), pp. 19–21.
J. Mazumder: in Metallurgical and Ceramic Protective Coatings, Kurt H. Stern, ed., Chapman and Hall, London, 1996, pp. 74–111.
K. Komvopoulos and K. Nagarathnam: J. Eng. Mater. Technol., 1990, vol. 112, pp. 131–43.
A. Agarwal and N.B. Dahotre: Int. J. Refract. Mater. Hard Met., 1999, vol. 17 (4), pp. 283–93.
A. Agarwal, N.B. Dahotre, and L.F. Allard: Pract. Metallogr., 1999, vol. 36 (3), pp. 250–63.
J.T.M. De Hosson and M. Van Den Burg: Mater. Manufacturing Processes, 1995, vol. 10 (6), pp. 1285–94.
A. Munster and G. Schlamp: Z. Phys. Chem., 1960, vol. 25, p. 116.
T. Moeller: Inorganic Chemistry, John Wiley & Sons, New York, NY, 1972, pp. 752–63.
M.G. Fontana: Corrosion Engineering, McGraw-Hill, Inc., New York, NY, 1986, pp. 505–41.
N. Birks and G.H. Meier: Introduction to High Temperature Oxidation of Metals, Edward Arnold Ltd., London, 1983, pp. 91–130.
A. Agarwal: Ph.D. Dissertation University of Tennessee, Knoxville, November 1999.
G.V. Samsonov: The Oxide Handbook, Plenum Press, New York, NY, 1973, pp. 348–60.
F. Gesmundo: Mater. Sci. Forum, 1997, vols. 251–254, pp. 3–18.
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Agarwal, A., Katipelli, L.R. & Dahotre, N.B. Elevated temperature oxidation of laser surface engineered composite boride coating on steel. Metall Mater Trans A 31, 461–473 (2000). https://doi.org/10.1007/s11661-000-0282-0
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DOI: https://doi.org/10.1007/s11661-000-0282-0